The impact of P(NDI2OD-T2) crystalline domains on the open-circuit voltage of bilayer all-polymer solar cells with an inverted configuration
We fabricated P(NDI2OD-T2)/PTB7 bilayer all-polymer solar cells with an inverted configuration, where the annealing temperature was systematically varied. The current density–voltage behavior was investigated and the structural properties of the P(NDI2OD-T2) layers were characterized. Absorption spe...
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Format: | Article |
Language: | English |
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AIP Publishing LLC
2015-12-01
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Series: | APL Materials |
Online Access: | http://dx.doi.org/10.1063/1.4937469 |
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author | Yu Jin Kim Chan Eon Park |
author_facet | Yu Jin Kim Chan Eon Park |
author_sort | Yu Jin Kim |
collection | DOAJ |
description | We fabricated P(NDI2OD-T2)/PTB7 bilayer all-polymer solar cells with an inverted configuration, where the annealing temperature was systematically varied. The current density–voltage behavior was investigated and the structural properties of the P(NDI2OD-T2) layers were characterized. Absorption spectroscopy, surface morphology, and crystallite analysis showed that increasing phase segregation of P(NDI2OD-T2) films occurred as the annealing temperature increased. We found that, as the P(NDI2OD-T2) stacking improved, with larger domains, the open-circuit voltage decreased and the saturation dark current density increased. This work provides a guide for the processing of P(NDI2OD-T2) layers to maximize the power conversion efficiency of all-polymer solar cells. |
first_indexed | 2024-04-12T23:09:56Z |
format | Article |
id | doaj.art-e92b508265b84f8db3bd1964447bad0b |
institution | Directory Open Access Journal |
issn | 2166-532X |
language | English |
last_indexed | 2024-04-12T23:09:56Z |
publishDate | 2015-12-01 |
publisher | AIP Publishing LLC |
record_format | Article |
series | APL Materials |
spelling | doaj.art-e92b508265b84f8db3bd1964447bad0b2022-12-22T03:12:50ZengAIP Publishing LLCAPL Materials2166-532X2015-12-01312126105126105-810.1063/1.4937469007512APMThe impact of P(NDI2OD-T2) crystalline domains on the open-circuit voltage of bilayer all-polymer solar cells with an inverted configurationYu Jin Kim0Chan Eon Park1POSTECH Organic Electronics Laboratory, Department of Chemical Engineering, Pohang University of Science and Technology, Pohang 790-784, South KoreaPOSTECH Organic Electronics Laboratory, Department of Chemical Engineering, Pohang University of Science and Technology, Pohang 790-784, South KoreaWe fabricated P(NDI2OD-T2)/PTB7 bilayer all-polymer solar cells with an inverted configuration, where the annealing temperature was systematically varied. The current density–voltage behavior was investigated and the structural properties of the P(NDI2OD-T2) layers were characterized. Absorption spectroscopy, surface morphology, and crystallite analysis showed that increasing phase segregation of P(NDI2OD-T2) films occurred as the annealing temperature increased. We found that, as the P(NDI2OD-T2) stacking improved, with larger domains, the open-circuit voltage decreased and the saturation dark current density increased. This work provides a guide for the processing of P(NDI2OD-T2) layers to maximize the power conversion efficiency of all-polymer solar cells.http://dx.doi.org/10.1063/1.4937469 |
spellingShingle | Yu Jin Kim Chan Eon Park The impact of P(NDI2OD-T2) crystalline domains on the open-circuit voltage of bilayer all-polymer solar cells with an inverted configuration APL Materials |
title | The impact of P(NDI2OD-T2) crystalline domains on the open-circuit voltage of bilayer all-polymer solar cells with an inverted configuration |
title_full | The impact of P(NDI2OD-T2) crystalline domains on the open-circuit voltage of bilayer all-polymer solar cells with an inverted configuration |
title_fullStr | The impact of P(NDI2OD-T2) crystalline domains on the open-circuit voltage of bilayer all-polymer solar cells with an inverted configuration |
title_full_unstemmed | The impact of P(NDI2OD-T2) crystalline domains on the open-circuit voltage of bilayer all-polymer solar cells with an inverted configuration |
title_short | The impact of P(NDI2OD-T2) crystalline domains on the open-circuit voltage of bilayer all-polymer solar cells with an inverted configuration |
title_sort | impact of p ndi2od t2 crystalline domains on the open circuit voltage of bilayer all polymer solar cells with an inverted configuration |
url | http://dx.doi.org/10.1063/1.4937469 |
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