Bis(6-methoxy-2-{[tris(hydroxymethyl)methyl]iminomethyl}phenolato)copper(II) dihydrate
In the title compound, [Cu(C12H16NO5)2]·2H2O, the CuII ion adopts a trans-CuN2O4 octahedral geometry arising from two N,O,O′-tridentate 6-methoxy-2-{[tris(hydroxymethyl)methyl]iminomethyl}phenolate ligands. The Jahn–Teller distortion of the copper centre is unusally smal...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808043948 |
| _version_ | 1818960248239554560 |
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| author | Bo Hu Bin Li Jianmin Dou Peihai Wei Xiutang Zhang |
| author_facet | Bo Hu Bin Li Jianmin Dou Peihai Wei Xiutang Zhang |
| author_sort | Bo Hu |
| collection | DOAJ |
| description | In the title compound, [Cu(C12H16NO5)2]·2H2O, the CuII ion adopts a trans-CuN2O4 octahedral geometry arising from two N,O,O′-tridentate 6-methoxy-2-{[tris(hydroxymethyl)methyl]iminomethyl}phenolate ligands. The Jahn–Teller distortion of the copper centre is unusally small. In the crystal structure, O—H...O hydrogen bonds, some of which are bifurcated, link the component species. |
| first_indexed | 2024-12-20T11:54:31Z |
| format | Article |
| id | doaj.art-e953fb577e52470fb32caf01683a1510 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:54:31Z |
| publishDate | 2009-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-e953fb577e52470fb32caf01683a15102022-12-21T19:41:41ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-02-01652m151m15210.1107/S1600536808043948Bis(6-methoxy-2-{[tris(hydroxymethyl)methyl]iminomethyl}phenolato)copper(II) dihydrateBo HuBin LiJianmin DouPeihai WeiXiutang ZhangIn the title compound, [Cu(C12H16NO5)2]·2H2O, the CuII ion adopts a trans-CuN2O4 octahedral geometry arising from two N,O,O′-tridentate 6-methoxy-2-{[tris(hydroxymethyl)methyl]iminomethyl}phenolate ligands. The Jahn–Teller distortion of the copper centre is unusally small. In the crystal structure, O—H...O hydrogen bonds, some of which are bifurcated, link the component species.http://scripts.iucr.org/cgi-bin/paper?S1600536808043948 |
| spellingShingle | Bo Hu Bin Li Jianmin Dou Peihai Wei Xiutang Zhang Bis(6-methoxy-2-{[tris(hydroxymethyl)methyl]iminomethyl}phenolato)copper(II) dihydrate Acta Crystallographica Section E |
| title | Bis(6-methoxy-2-{[tris(hydroxymethyl)methyl]iminomethyl}phenolato)copper(II) dihydrate |
| title_full | Bis(6-methoxy-2-{[tris(hydroxymethyl)methyl]iminomethyl}phenolato)copper(II) dihydrate |
| title_fullStr | Bis(6-methoxy-2-{[tris(hydroxymethyl)methyl]iminomethyl}phenolato)copper(II) dihydrate |
| title_full_unstemmed | Bis(6-methoxy-2-{[tris(hydroxymethyl)methyl]iminomethyl}phenolato)copper(II) dihydrate |
| title_short | Bis(6-methoxy-2-{[tris(hydroxymethyl)methyl]iminomethyl}phenolato)copper(II) dihydrate |
| title_sort | bis 6 methoxy 2 tris hydroxymethyl methyl iminomethyl phenolato copper ii dihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808043948 |
| work_keys_str_mv | AT bohu bis6methoxy2trishydroxymethylmethyliminomethylphenolatocopperiidihydrate AT binli bis6methoxy2trishydroxymethylmethyliminomethylphenolatocopperiidihydrate AT jianmindou bis6methoxy2trishydroxymethylmethyliminomethylphenolatocopperiidihydrate AT peihaiwei bis6methoxy2trishydroxymethylmethyliminomethylphenolatocopperiidihydrate AT xiutangzhang bis6methoxy2trishydroxymethylmethyliminomethylphenolatocopperiidihydrate |