2-Hydroxy-N′-(2-hydroxy-4-methoxybenzylidene)-3-methylbenzohydrazide monohydrate

In the title compound, C16H16N2O4·H2O, the dihedral angle between the two benzene rings is 12.4 (2)° and the molecule adopts an E configuration with respect to the C=N bond. There are intramolecular O—H...N and O—H...O hydrogen bond...

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Bibliographic Details
Main Authors: You-Yue Han, Yong-Hong Li, Qiu-Rong Zhao
Format: Article
Language:English
Published: International Union of Crystallography 2010-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810016855
Description
Summary:In the title compound, C16H16N2O4·H2O, the dihedral angle between the two benzene rings is 12.4 (2)° and the molecule adopts an E configuration with respect to the C=N bond. There are intramolecular O—H...N and O—H...O hydrogen bonds in the hydrazone molecule, which both generate S(6) rings. In the crystal structure, molecules are linked by N—H...O and O—H...O hydrogen bonds, forming layers parallel to the ab plane. The crystal studied was a non-merohedral twin with a domain ratio of 0.887 (3):0.113 (3).
ISSN:1600-5368