2-Hydroxy-N′-(2-hydroxy-4-methoxybenzylidene)-3-methylbenzohydrazide monohydrate
In the title compound, C16H16N2O4·H2O, the dihedral angle between the two benzene rings is 12.4 (2)° and the molecule adopts an E configuration with respect to the C=N bond. There are intramolecular O—H...N and O—H...O hydrogen bond...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810016855 |
| _version_ | 1818489115080916992 |
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| author | You-Yue Han Yong-Hong Li Qiu-Rong Zhao |
| author_facet | You-Yue Han Yong-Hong Li Qiu-Rong Zhao |
| author_sort | You-Yue Han |
| collection | DOAJ |
| description | In the title compound, C16H16N2O4·H2O, the dihedral angle between the two benzene rings is 12.4 (2)° and the molecule adopts an E configuration with respect to the C=N bond. There are intramolecular O—H...N and O—H...O hydrogen bonds in the hydrazone molecule, which both generate S(6) rings. In the crystal structure, molecules are linked by N—H...O and O—H...O hydrogen bonds, forming layers parallel to the ab plane. The crystal studied was a non-merohedral twin with a domain ratio of 0.887 (3):0.113 (3). |
| first_indexed | 2024-12-10T16:59:24Z |
| format | Article |
| id | doaj.art-e957e802398644eda015938ba3466c83 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T16:59:24Z |
| publishDate | 2010-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-e957e802398644eda015938ba3466c832022-12-22T01:40:37ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-06-01666o1340o134010.1107/S16005368100168552-Hydroxy-N′-(2-hydroxy-4-methoxybenzylidene)-3-methylbenzohydrazide monohydrateYou-Yue HanYong-Hong LiQiu-Rong ZhaoIn the title compound, C16H16N2O4·H2O, the dihedral angle between the two benzene rings is 12.4 (2)° and the molecule adopts an E configuration with respect to the C=N bond. There are intramolecular O—H...N and O—H...O hydrogen bonds in the hydrazone molecule, which both generate S(6) rings. In the crystal structure, molecules are linked by N—H...O and O—H...O hydrogen bonds, forming layers parallel to the ab plane. The crystal studied was a non-merohedral twin with a domain ratio of 0.887 (3):0.113 (3).http://scripts.iucr.org/cgi-bin/paper?S1600536810016855 |
| spellingShingle | You-Yue Han Yong-Hong Li Qiu-Rong Zhao 2-Hydroxy-N′-(2-hydroxy-4-methoxybenzylidene)-3-methylbenzohydrazide monohydrate Acta Crystallographica Section E |
| title | 2-Hydroxy-N′-(2-hydroxy-4-methoxybenzylidene)-3-methylbenzohydrazide monohydrate |
| title_full | 2-Hydroxy-N′-(2-hydroxy-4-methoxybenzylidene)-3-methylbenzohydrazide monohydrate |
| title_fullStr | 2-Hydroxy-N′-(2-hydroxy-4-methoxybenzylidene)-3-methylbenzohydrazide monohydrate |
| title_full_unstemmed | 2-Hydroxy-N′-(2-hydroxy-4-methoxybenzylidene)-3-methylbenzohydrazide monohydrate |
| title_short | 2-Hydroxy-N′-(2-hydroxy-4-methoxybenzylidene)-3-methylbenzohydrazide monohydrate |
| title_sort | 2 hydroxy n amp 8242 2 hydroxy 4 methoxybenzylidene 3 methylbenzohydrazide monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810016855 |
| work_keys_str_mv | AT youyuehan 2hydroxynamp82422hydroxy4methoxybenzylidene3methylbenzohydrazidemonohydrate AT yonghongli 2hydroxynamp82422hydroxy4methoxybenzylidene3methylbenzohydrazidemonohydrate AT qiurongzhao 2hydroxynamp82422hydroxy4methoxybenzylidene3methylbenzohydrazidemonohydrate |