COMPOSITE POLYMER SUSPENSIONS WITH COMPLEX PARTICLE MORPHOLOGY

The review is dedicated to the synthesis of composite polymer suspensions with complex particle morphology. Authors attempted to summarize effects of polymerization conditions on particle morphology. The significance of further investigations in the field of composite polymer suspensions synthesis w...

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Main Authors: N. I. Prokopov, I. A. Gritskova, A. Yu. Gervald, M. S. Balashov
Format: Article
Language:Russian
Published: MIREA - Russian Technological University 2017-06-01
Series:Российский технологический журнал
Subjects:
Online Access:https://www.rtj-mirea.ru/jour/article/view/64
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author N. I. Prokopov
I. A. Gritskova
A. Yu. Gervald
M. S. Balashov
author_facet N. I. Prokopov
I. A. Gritskova
A. Yu. Gervald
M. S. Balashov
author_sort N. I. Prokopov
collection DOAJ
description The review is dedicated to the synthesis of composite polymer suspensions with complex particle morphology. Authors attempted to summarize effects of polymerization conditions on particle morphology. The significance of further investigations in the field of composite polymer suspensions synthesis was shown. The main aspects of different monomers emulsion homopolymerization, affecting the polymer particle morphology, such as polymerization topochemistry, free energy of particle formation, the kind of monomer and others were discussed. The determination methods of polymer particles phase structure may be shown to be classified as direct and indirect. The most frequently used investigation methods of suspension particles morphology viz electron microscopy, soap titration technique and film forming were described. General techniques of composite polymer particle synthesis, such as emulsion copolymerization and seed polymerization, were given and considered in detail. Advantages and disadvantages of each method were listed. Determination of particle morphology, using thermodynamic approach, was discussed. Obtained composite polymer particles were found to be classified into two large groups: non-uniform composite gradient particles and heterophase particles.
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spelling doaj.art-e969e9b672844a43a862c8ab701760d92025-03-02T10:41:25ZrusMIREA - Russian Technological UniversityРоссийский технологический журнал2782-32102500-316X2017-06-01537410510.32362/2500-316X-2017-5-3-74-10564COMPOSITE POLYMER SUSPENSIONS WITH COMPLEX PARTICLE MORPHOLOGYN. I. Prokopov0I. A. Gritskova1A. Yu. Gervald2M. S. Balashov3Moscow Technological University (Institute of Fine Chemical Technologies)Moscow Technological University (Institute of Fine Chemical Technologies)Moscow Technological University (Institute of Fine Chemical Technologies)Moscow Technological University (Institute of Fine Chemical Technologies)The review is dedicated to the synthesis of composite polymer suspensions with complex particle morphology. Authors attempted to summarize effects of polymerization conditions on particle morphology. The significance of further investigations in the field of composite polymer suspensions synthesis was shown. The main aspects of different monomers emulsion homopolymerization, affecting the polymer particle morphology, such as polymerization topochemistry, free energy of particle formation, the kind of monomer and others were discussed. The determination methods of polymer particles phase structure may be shown to be classified as direct and indirect. The most frequently used investigation methods of suspension particles morphology viz electron microscopy, soap titration technique and film forming were described. General techniques of composite polymer particle synthesis, such as emulsion copolymerization and seed polymerization, were given and considered in detail. Advantages and disadvantages of each method were listed. Determination of particle morphology, using thermodynamic approach, was discussed. Obtained composite polymer particles were found to be classified into two large groups: non-uniform composite gradient particles and heterophase particles.https://www.rtj-mirea.ru/jour/article/view/64composite polymer particlesmulticomponent particlespolymer particle morphologyemulsion polymerizationseed polymerizationinvestigation methods of heterophase particles structure
spellingShingle N. I. Prokopov
I. A. Gritskova
A. Yu. Gervald
M. S. Balashov
COMPOSITE POLYMER SUSPENSIONS WITH COMPLEX PARTICLE MORPHOLOGY
Российский технологический журнал
composite polymer particles
multicomponent particles
polymer particle morphology
emulsion polymerization
seed polymerization
investigation methods of heterophase particles structure
title COMPOSITE POLYMER SUSPENSIONS WITH COMPLEX PARTICLE MORPHOLOGY
title_full COMPOSITE POLYMER SUSPENSIONS WITH COMPLEX PARTICLE MORPHOLOGY
title_fullStr COMPOSITE POLYMER SUSPENSIONS WITH COMPLEX PARTICLE MORPHOLOGY
title_full_unstemmed COMPOSITE POLYMER SUSPENSIONS WITH COMPLEX PARTICLE MORPHOLOGY
title_short COMPOSITE POLYMER SUSPENSIONS WITH COMPLEX PARTICLE MORPHOLOGY
title_sort composite polymer suspensions with complex particle morphology
topic composite polymer particles
multicomponent particles
polymer particle morphology
emulsion polymerization
seed polymerization
investigation methods of heterophase particles structure
url https://www.rtj-mirea.ru/jour/article/view/64
work_keys_str_mv AT niprokopov compositepolymersuspensionswithcomplexparticlemorphology
AT iagritskova compositepolymersuspensionswithcomplexparticlemorphology
AT ayugervald compositepolymersuspensionswithcomplexparticlemorphology
AT msbalashov compositepolymersuspensionswithcomplexparticlemorphology