Fish Bone-Catalyzed Methanolysis of Waste Cooking Oil

The use of cheaper alternative such as waste cooking oil as substitute to vegetable oil can reduce the overall production cost of biodiesel. This research focuses on the investigation of the kinetic of waste cooking oil methanolysis using heterogeneous waste catalyst. Fish bone waste was used as the...

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Main Authors: Sarina Sulaiman, M.H.M. Amin
Format: Article
Language:English
Published: Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) 2016-08-01
Series:Bulletin of Chemical Reaction Engineering & Catalysis
Subjects:
Online Access:https://journal.bcrec.id/index.php/bcrec/article/view/556
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author Sarina Sulaiman
M.H.M. Amin
author_facet Sarina Sulaiman
M.H.M. Amin
author_sort Sarina Sulaiman
collection DOAJ
description The use of cheaper alternative such as waste cooking oil as substitute to vegetable oil can reduce the overall production cost of biodiesel. This research focuses on the investigation of the kinetic of waste cooking oil methanolysis using heterogeneous waste catalyst. Fish bone waste was used as the catalyst for the methanolysis of waste cooking oil. The kinetic data obtained from this study can be used to optimize the process of biodiesel production. The effects of temperature and catalyst amount were varied between 50- 65 °C and 4-10 wt % respectively. The kinetic of transesterification of waste oil, the reaction rate constant (k) and activation energy (EA) at 55, 65 and 65 °C were determined. The highest yield of biodiesel, 86 % were achieved at 6 wt% of catalyst amount, mixing of 300 rpm, methanol to oil ratio of 18:1 and reaction temperature of 65 °C. The activation energy (Ea) was 34.12 kJ/mol. This study also proves that transesterification process is not affected by the internal mass transfer due to the Thiele modulus value between 0-1.69.
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spelling doaj.art-e97e81a32369442cb23e190cda988c122023-09-22T03:50:23ZengMasyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)Bulletin of Chemical Reaction Engineering & Catalysis1978-29932016-08-0111224524910.9767/bcrec.11.2.556.245-249432Fish Bone-Catalyzed Methanolysis of Waste Cooking OilSarina Sulaiman0M.H.M. Amin1Department of Biotechnology Engineering, Faculty of Engineering, International Islamic University of Malaysia, Kuala Lumpur, MalaysiaDepartment of Biotechnology Engineering, Faculty of Engineering, International Islamic University of Malaysia, Kuala Lumpur, MalaysiaThe use of cheaper alternative such as waste cooking oil as substitute to vegetable oil can reduce the overall production cost of biodiesel. This research focuses on the investigation of the kinetic of waste cooking oil methanolysis using heterogeneous waste catalyst. Fish bone waste was used as the catalyst for the methanolysis of waste cooking oil. The kinetic data obtained from this study can be used to optimize the process of biodiesel production. The effects of temperature and catalyst amount were varied between 50- 65 °C and 4-10 wt % respectively. The kinetic of transesterification of waste oil, the reaction rate constant (k) and activation energy (EA) at 55, 65 and 65 °C were determined. The highest yield of biodiesel, 86 % were achieved at 6 wt% of catalyst amount, mixing of 300 rpm, methanol to oil ratio of 18:1 and reaction temperature of 65 °C. The activation energy (Ea) was 34.12 kJ/mol. This study also proves that transesterification process is not affected by the internal mass transfer due to the Thiele modulus value between 0-1.69.https://journal.bcrec.id/index.php/bcrec/article/view/556fish bone catalystbiodieselwaste cooking oilkinetic
spellingShingle Sarina Sulaiman
M.H.M. Amin
Fish Bone-Catalyzed Methanolysis of Waste Cooking Oil
Bulletin of Chemical Reaction Engineering & Catalysis
fish bone catalyst
biodiesel
waste cooking oil
kinetic
title Fish Bone-Catalyzed Methanolysis of Waste Cooking Oil
title_full Fish Bone-Catalyzed Methanolysis of Waste Cooking Oil
title_fullStr Fish Bone-Catalyzed Methanolysis of Waste Cooking Oil
title_full_unstemmed Fish Bone-Catalyzed Methanolysis of Waste Cooking Oil
title_short Fish Bone-Catalyzed Methanolysis of Waste Cooking Oil
title_sort fish bone catalyzed methanolysis of waste cooking oil
topic fish bone catalyst
biodiesel
waste cooking oil
kinetic
url https://journal.bcrec.id/index.php/bcrec/article/view/556
work_keys_str_mv AT sarinasulaiman fishbonecatalyzedmethanolysisofwastecookingoil
AT mhmamin fishbonecatalyzedmethanolysisofwastecookingoil