(1-{(E)-[Phenyl(pyridin-2-yl-κN)methylidene]amino-κN}pyrrolidin-2-one-κO)bis(thiocyanato-κN)copper(II)
The CuII atom in the title compound, [Cu(NCS)2(C16H15N3O)], is bonded to the N atoms of two thiocyanate ions, and is N,N′-chelated by the Schiff base ligand. The four N atoms surround the metal atom to form a distorted square; the square environment is distorted towards a square pyrami...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812039918 |
| _version_ | 1818957915368718336 |
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| author | Roji J. Kunnath M. R. Prathapachandra Kurup Seik Weng Ng |
| author_facet | Roji J. Kunnath M. R. Prathapachandra Kurup Seik Weng Ng |
| author_sort | Roji J. Kunnath |
| collection | DOAJ |
| description | The CuII atom in the title compound, [Cu(NCS)2(C16H15N3O)], is bonded to the N atoms of two thiocyanate ions, and is N,N′-chelated by the Schiff base ligand. The four N atoms surround the metal atom to form a distorted square; the square environment is distorted towards a square pyramid by a long Cu...O interaction. In the crystal, two C atoms of the pyrrolidin-2-one ring are disordered over two positions in a 1:1 ratio. |
| first_indexed | 2024-12-20T11:17:26Z |
| format | Article |
| id | doaj.art-e9a0bd3d5455433196f0dd2cc6080731 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:17:26Z |
| publishDate | 2012-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-e9a0bd3d5455433196f0dd2cc60807312022-12-21T19:42:34ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-10-016810m1302m130210.1107/S1600536812039918(1-{(E)-[Phenyl(pyridin-2-yl-κN)methylidene]amino-κN}pyrrolidin-2-one-κO)bis(thiocyanato-κN)copper(II)Roji J. KunnathM. R. Prathapachandra KurupSeik Weng NgThe CuII atom in the title compound, [Cu(NCS)2(C16H15N3O)], is bonded to the N atoms of two thiocyanate ions, and is N,N′-chelated by the Schiff base ligand. The four N atoms surround the metal atom to form a distorted square; the square environment is distorted towards a square pyramid by a long Cu...O interaction. In the crystal, two C atoms of the pyrrolidin-2-one ring are disordered over two positions in a 1:1 ratio.http://scripts.iucr.org/cgi-bin/paper?S1600536812039918 |
| spellingShingle | Roji J. Kunnath M. R. Prathapachandra Kurup Seik Weng Ng (1-{(E)-[Phenyl(pyridin-2-yl-κN)methylidene]amino-κN}pyrrolidin-2-one-κO)bis(thiocyanato-κN)copper(II) Acta Crystallographica Section E |
| title | (1-{(E)-[Phenyl(pyridin-2-yl-κN)methylidene]amino-κN}pyrrolidin-2-one-κO)bis(thiocyanato-κN)copper(II) |
| title_full | (1-{(E)-[Phenyl(pyridin-2-yl-κN)methylidene]amino-κN}pyrrolidin-2-one-κO)bis(thiocyanato-κN)copper(II) |
| title_fullStr | (1-{(E)-[Phenyl(pyridin-2-yl-κN)methylidene]amino-κN}pyrrolidin-2-one-κO)bis(thiocyanato-κN)copper(II) |
| title_full_unstemmed | (1-{(E)-[Phenyl(pyridin-2-yl-κN)methylidene]amino-κN}pyrrolidin-2-one-κO)bis(thiocyanato-κN)copper(II) |
| title_short | (1-{(E)-[Phenyl(pyridin-2-yl-κN)methylidene]amino-κN}pyrrolidin-2-one-κO)bis(thiocyanato-κN)copper(II) |
| title_sort | 1 e phenyl pyridin 2 yl amp 954 n methylidene amino amp 954 n pyrrolidin 2 one amp 954 o bis thiocyanato amp 954 n copper ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812039918 |
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