Minimizing electrostatic interactions from piezoresponse force microscopy via capacitive excitation

Piezoresponse force microscopy (PFM) has emerged as one of the most powerful techniques to probe ferroelectric materials at the nanoscale, yet it has been increasingly recognized that piezoresponse measured by PFM is often influenced by electrostatic interactions. In this letter, we report a capacit...

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Main Authors: Qingfeng Zhu, Ehsan Nasr Esfahani, Shuhong Xie, Jiangyu Li
Format: Article
Language:English
Published: Elsevier 2020-01-01
Series:Theoretical and Applied Mechanics Letters
Online Access:http://www.sciencedirect.com/science/article/pii/S2095034920300052
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author Qingfeng Zhu
Ehsan Nasr Esfahani
Shuhong Xie
Jiangyu Li
author_facet Qingfeng Zhu
Ehsan Nasr Esfahani
Shuhong Xie
Jiangyu Li
author_sort Qingfeng Zhu
collection DOAJ
description Piezoresponse force microscopy (PFM) has emerged as one of the most powerful techniques to probe ferroelectric materials at the nanoscale, yet it has been increasingly recognized that piezoresponse measured by PFM is often influenced by electrostatic interactions. In this letter, we report a capacitive excitation PFM (ce-PFM) to minimize the electrostatic interactions. The effectiveness of ce-PFM in minimizing electrostatic interactions is demonstrated by comparing the piezoresponse and the effective piezoelectric coefficient measured by ce-PFM and conventional PFM. The effectiveness is further confirmed through the ferroelectric domain pattern imaged via ce-PFM and conventional PFM in vertical modes, with the corresponding domain contrast obtained by ce-PFM is sharper than conventional PFM. These results demonstrate ce-PFM as an effective tool to minimize the interference from electrostatic interactions and to image ferroelectric domain pattern, and it can be easily implemented in conventional atomic force microscope (AFM) setup to probe true piezoelectricity at the nanoscale. Keywords: Piezoresponse force microscopy, Electrostatic interactions, Capacitive excitation
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spelling doaj.art-e9a4411262d447efbe087be3189f33122022-12-22T02:34:31ZengElsevierTheoretical and Applied Mechanics Letters2095-03492020-01-011012326Minimizing electrostatic interactions from piezoresponse force microscopy via capacitive excitationQingfeng Zhu0Ehsan Nasr Esfahani1Shuhong Xie2Jiangyu Li3Shenzhen Key Laboratory of Nanobiomechanics, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China; Hunan Provincial Key Laboratory of Thin Film Materials and Devices, Xiangtan University, Xiangtan 411105, ChinaShenzhen Key Laboratory of Nanobiomechanics, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China; Department of Mechanical Engineering, University of Washington, Seattle 98195, WA, USAKey Laboratory of Low Dimensional Materials and Application Technology of Ministry of Education, and School of Materials Science and Engineering, Xiangtan University, Xiangtan 411105, China; Corresponding authorShenzhen Key Laboratory of Nanobiomechanics, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China; Department of Mechanical Engineering, University of Washington, Seattle 98195, WA, USA; Corresponding authorPiezoresponse force microscopy (PFM) has emerged as one of the most powerful techniques to probe ferroelectric materials at the nanoscale, yet it has been increasingly recognized that piezoresponse measured by PFM is often influenced by electrostatic interactions. In this letter, we report a capacitive excitation PFM (ce-PFM) to minimize the electrostatic interactions. The effectiveness of ce-PFM in minimizing electrostatic interactions is demonstrated by comparing the piezoresponse and the effective piezoelectric coefficient measured by ce-PFM and conventional PFM. The effectiveness is further confirmed through the ferroelectric domain pattern imaged via ce-PFM and conventional PFM in vertical modes, with the corresponding domain contrast obtained by ce-PFM is sharper than conventional PFM. These results demonstrate ce-PFM as an effective tool to minimize the interference from electrostatic interactions and to image ferroelectric domain pattern, and it can be easily implemented in conventional atomic force microscope (AFM) setup to probe true piezoelectricity at the nanoscale. Keywords: Piezoresponse force microscopy, Electrostatic interactions, Capacitive excitationhttp://www.sciencedirect.com/science/article/pii/S2095034920300052
spellingShingle Qingfeng Zhu
Ehsan Nasr Esfahani
Shuhong Xie
Jiangyu Li
Minimizing electrostatic interactions from piezoresponse force microscopy via capacitive excitation
Theoretical and Applied Mechanics Letters
title Minimizing electrostatic interactions from piezoresponse force microscopy via capacitive excitation
title_full Minimizing electrostatic interactions from piezoresponse force microscopy via capacitive excitation
title_fullStr Minimizing electrostatic interactions from piezoresponse force microscopy via capacitive excitation
title_full_unstemmed Minimizing electrostatic interactions from piezoresponse force microscopy via capacitive excitation
title_short Minimizing electrostatic interactions from piezoresponse force microscopy via capacitive excitation
title_sort minimizing electrostatic interactions from piezoresponse force microscopy via capacitive excitation
url http://www.sciencedirect.com/science/article/pii/S2095034920300052
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AT ehsannasresfahani minimizingelectrostaticinteractionsfrompiezoresponseforcemicroscopyviacapacitiveexcitation
AT shuhongxie minimizingelectrostaticinteractionsfrompiezoresponseforcemicroscopyviacapacitiveexcitation
AT jiangyuli minimizingelectrostaticinteractionsfrompiezoresponseforcemicroscopyviacapacitiveexcitation