Synthesis of 5-Metalla-Spiro[4.5]Heterodecenes by [1,4]-Cycloaddition Reaction of Group 13 Diyls with 1,2-Diketones

Synthesis of 5-Metalla-Spiro[4.5]Heterodecenes by [1,4]-Cycloaddition Reaction of Group 13 Diyls with 1,2-Diketones

Monovalent group 13 diyls are versatile reagents in oxidative addition reactions. We report here [1,4]-cycloaddition reactions of β-diketiminate-substituted diyls LM (M = Al, Ga, In, Tl; L = HC[C(Me)NDipp]<sub>2</sub>, Dipp = 2,6-<i><sup>i</sup></i>Pr<sub>2&...

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Bibliographic Details
Main Authors:	Hanns M. Weinert, Christoph Wölper, Stephan Schulz
Format:	Article
Language:	English
Published:	MDPI AG 2023-04-01
Series:	Chemistry
Subjects:	group 13 diyls low-valent metal cycloaddition aldol addition
Online Access:	https://www.mdpi.com/2624-8549/5/2/64

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