Effects of rare earth Ce on TiN inclusion modifications in 20CrMnTi steel under deoxygenation conditions of Si–Ca–Ba alloy

20CrMnTi steel is widely used in the gear manufacturing field of engineering machinery. The addition of Ti element to steel can effectively improve its low-temperature impact toughness and enhance its mechanical properties. However, during the smelting process of 20CrMnTi, large-sized TiN inclusions...

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Main Authors: Shuang Liu, Fan Yang, Lixia Liu, Jian Wang, Jun Peng, Fang Zhang, Shengli An
Format: Article
Language:English
Published: Elsevier 2024-05-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785424005994
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author Shuang Liu
Fan Yang
Lixia Liu
Jian Wang
Jun Peng
Fang Zhang
Shengli An
author_facet Shuang Liu
Fan Yang
Lixia Liu
Jian Wang
Jun Peng
Fang Zhang
Shengli An
author_sort Shuang Liu
collection DOAJ
description 20CrMnTi steel is widely used in the gear manufacturing field of engineering machinery. The addition of Ti element to steel can effectively improve its low-temperature impact toughness and enhance its mechanical properties. However, during the smelting process of 20CrMnTi, large-sized TiN inclusions are inevitably formed in the steel, which affects its service performance improvement. This paper focuses on the directional modification behaviors of TiN inclusions in 20CrMnTi gear steel by rare earth Ce under deoxygenation conditions of Si–Ca–Ba alloy. The results show that under the deoxygenation conditions of Si–Ca–Ba alone, there are composite inclusions in 20CrMnTi steel with CaAl12O19 as the core and TiN wrapped around the periphery, all of which have sizes greater than 2 μm. This type of inclusion is square or diamond shaped, and the addition of Si–Ca–Ba deoxygenation alone has poor TiN modification effect on gear steel 20CrMnTi. Adding Ce element can effectively improve the nucleation core of inclusions. The CeAlO3–TiN and (CaAl12O19–Ba–Ce)–TiN composite inclusions are formed, and the TiN inclusions are modified in terms of morphology and size. The average size of inclusions decreases from 4.1 to 3.0 μm, which prevented the excessive growth of pure TiN inclusions to some extent.
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spelling doaj.art-e9d804842d4a4a6ca04abc9248d4ff0d2024-03-17T07:54:34ZengElsevierJournal of Materials Research and Technology2238-78542024-05-0130223230Effects of rare earth Ce on TiN inclusion modifications in 20CrMnTi steel under deoxygenation conditions of Si–Ca–Ba alloyShuang Liu0Fan Yang1Lixia Liu2Jian Wang3Jun Peng4Fang Zhang5Shengli An6School of Rare Earth Research and Development, Inner Mongolia University of Science and Technology, Baotou, 014010, China; School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou, 014010, China; Inner Mongolia Key Laboratory of Advanced Ceramic Materials and Devices, Inner Mongolia University of Science and Technology, Baotou, 014010, China; Key Laboratory of Green Extraction & Efficient Utilization of Light Rare-Earth Resources, Inner Mongolia University of Science and Technology, Ministry of Education, Baotou, 014010, ChinaSchool of Rare Earth Research and Development, Inner Mongolia University of Science and Technology, Baotou, 014010, China; School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou, 014010, China; Inner Mongolia Key Laboratory of Advanced Ceramic Materials and Devices, Inner Mongolia University of Science and Technology, Baotou, 014010, China; Key Laboratory of Green Extraction & Efficient Utilization of Light Rare-Earth Resources, Inner Mongolia University of Science and Technology, Ministry of Education, Baotou, 014010, ChinaSchool of Rare Earth Research and Development, Inner Mongolia University of Science and Technology, Baotou, 014010, China; School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou, 014010, China; Inner Mongolia Key Laboratory of Advanced Ceramic Materials and Devices, Inner Mongolia University of Science and Technology, Baotou, 014010, China; Key Laboratory of Green Extraction & Efficient Utilization of Light Rare-Earth Resources, Inner Mongolia University of Science and Technology, Ministry of Education, Baotou, 014010, ChinaSchool of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou, 014010, China; Inner Mongolia Key Laboratory of Advanced Ceramic Materials and Devices, Inner Mongolia University of Science and Technology, Baotou, 014010, China; Key Laboratory of Green Extraction & Efficient Utilization of Light Rare-Earth Resources, Inner Mongolia University of Science and Technology, Ministry of Education, Baotou, 014010, ChinaSchool of Rare Earth Research and Development, Inner Mongolia University of Science and Technology, Baotou, 014010, China; School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou, 014010, China; Inner Mongolia Key Laboratory of Advanced Ceramic Materials and Devices, Inner Mongolia University of Science and Technology, Baotou, 014010, China; Key Laboratory of Green Extraction & Efficient Utilization of Light Rare-Earth Resources, Inner Mongolia University of Science and Technology, Ministry of Education, Baotou, 014010, China; Corresponding author. School of Rare Earth Research and Development, Inner Mongolia University of Science and Technology, Baotou, 014010, China.School of Rare Earth Research and Development, Inner Mongolia University of Science and Technology, Baotou, 014010, China; School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou, 014010, China; Inner Mongolia Key Laboratory of Advanced Ceramic Materials and Devices, Inner Mongolia University of Science and Technology, Baotou, 014010, China; Key Laboratory of Green Extraction & Efficient Utilization of Light Rare-Earth Resources, Inner Mongolia University of Science and Technology, Ministry of Education, Baotou, 014010, China; Corresponding author. School of Rare Earth Research and Development, Inner Mongolia University of Science and Technology, Baotou, 014010, China.School of Rare Earth Research and Development, Inner Mongolia University of Science and Technology, Baotou, 014010, China; School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou, 014010, China; Inner Mongolia Key Laboratory of Advanced Ceramic Materials and Devices, Inner Mongolia University of Science and Technology, Baotou, 014010, China; Key Laboratory of Green Extraction & Efficient Utilization of Light Rare-Earth Resources, Inner Mongolia University of Science and Technology, Ministry of Education, Baotou, 014010, China20CrMnTi steel is widely used in the gear manufacturing field of engineering machinery. The addition of Ti element to steel can effectively improve its low-temperature impact toughness and enhance its mechanical properties. However, during the smelting process of 20CrMnTi, large-sized TiN inclusions are inevitably formed in the steel, which affects its service performance improvement. This paper focuses on the directional modification behaviors of TiN inclusions in 20CrMnTi gear steel by rare earth Ce under deoxygenation conditions of Si–Ca–Ba alloy. The results show that under the deoxygenation conditions of Si–Ca–Ba alone, there are composite inclusions in 20CrMnTi steel with CaAl12O19 as the core and TiN wrapped around the periphery, all of which have sizes greater than 2 μm. This type of inclusion is square or diamond shaped, and the addition of Si–Ca–Ba deoxygenation alone has poor TiN modification effect on gear steel 20CrMnTi. Adding Ce element can effectively improve the nucleation core of inclusions. The CeAlO3–TiN and (CaAl12O19–Ba–Ce)–TiN composite inclusions are formed, and the TiN inclusions are modified in terms of morphology and size. The average size of inclusions decreases from 4.1 to 3.0 μm, which prevented the excessive growth of pure TiN inclusions to some extent.http://www.sciencedirect.com/science/article/pii/S223878542400599420CrMnTi gear steelDeoxygenationInclusionsModificationSize
spellingShingle Shuang Liu
Fan Yang
Lixia Liu
Jian Wang
Jun Peng
Fang Zhang
Shengli An
Effects of rare earth Ce on TiN inclusion modifications in 20CrMnTi steel under deoxygenation conditions of Si–Ca–Ba alloy
Journal of Materials Research and Technology
20CrMnTi gear steel
Deoxygenation
Inclusions
Modification
Size
title Effects of rare earth Ce on TiN inclusion modifications in 20CrMnTi steel under deoxygenation conditions of Si–Ca–Ba alloy
title_full Effects of rare earth Ce on TiN inclusion modifications in 20CrMnTi steel under deoxygenation conditions of Si–Ca–Ba alloy
title_fullStr Effects of rare earth Ce on TiN inclusion modifications in 20CrMnTi steel under deoxygenation conditions of Si–Ca–Ba alloy
title_full_unstemmed Effects of rare earth Ce on TiN inclusion modifications in 20CrMnTi steel under deoxygenation conditions of Si–Ca–Ba alloy
title_short Effects of rare earth Ce on TiN inclusion modifications in 20CrMnTi steel under deoxygenation conditions of Si–Ca–Ba alloy
title_sort effects of rare earth ce on tin inclusion modifications in 20crmnti steel under deoxygenation conditions of si ca ba alloy
topic 20CrMnTi gear steel
Deoxygenation
Inclusions
Modification
Size
url http://www.sciencedirect.com/science/article/pii/S2238785424005994
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