Chromium-catalyzed stereodivergent E- and Z-selective alkyne hydrogenation controlled by cyclic (alkyl)(amino)carbene ligands
The stereoselective synthesis of olefins from alkynes is a long-standing challenge in organic synthesis. Here, the authors report the chromium-catalyzed alkyne hydrogenation; E- or Z-olefins are obtained depending on the carbene ligand used.
| Main Authors: | , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2023-02-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-023-36677-9 |
| _version_ | 1797864169364520960 |
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| author | Liang Ling Chenyang Hu Linhong Long Xue Zhang Lixing Zhao Liu Leo Liu Hui Chen Meiming Luo Xiaoming Zeng |
| author_facet | Liang Ling Chenyang Hu Linhong Long Xue Zhang Lixing Zhao Liu Leo Liu Hui Chen Meiming Luo Xiaoming Zeng |
| author_sort | Liang Ling |
| collection | DOAJ |
| description | The stereoselective synthesis of olefins from alkynes is a long-standing challenge in organic synthesis. Here, the authors report the chromium-catalyzed alkyne hydrogenation; E- or Z-olefins are obtained depending on the carbene ligand used. |
| first_indexed | 2024-04-09T22:47:31Z |
| format | Article |
| id | doaj.art-e9e043d12e2f443eb62b55de297a793a |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-04-09T22:47:31Z |
| publishDate | 2023-02-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-e9e043d12e2f443eb62b55de297a793a2023-03-22T11:48:18ZengNature PortfolioNature Communications2041-17232023-02-0114111010.1038/s41467-023-36677-9Chromium-catalyzed stereodivergent E- and Z-selective alkyne hydrogenation controlled by cyclic (alkyl)(amino)carbene ligandsLiang Ling0Chenyang Hu1Linhong Long2Xue Zhang3Lixing Zhao4Liu Leo Liu5Hui Chen6Meiming Luo7Xiaoming Zeng8Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan UniversityShenzhen Grubbs Institute and Department of Chemistry, Southern University of Science and TechnologyBeijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Photochemistry, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of SciencesKey Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan UniversityKey Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan UniversityShenzhen Grubbs Institute and Department of Chemistry, Southern University of Science and TechnologyBeijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Photochemistry, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of SciencesKey Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan UniversityKey Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan UniversityThe stereoselective synthesis of olefins from alkynes is a long-standing challenge in organic synthesis. Here, the authors report the chromium-catalyzed alkyne hydrogenation; E- or Z-olefins are obtained depending on the carbene ligand used.https://doi.org/10.1038/s41467-023-36677-9 |
| spellingShingle | Liang Ling Chenyang Hu Linhong Long Xue Zhang Lixing Zhao Liu Leo Liu Hui Chen Meiming Luo Xiaoming Zeng Chromium-catalyzed stereodivergent E- and Z-selective alkyne hydrogenation controlled by cyclic (alkyl)(amino)carbene ligands Nature Communications |
| title | Chromium-catalyzed stereodivergent E- and Z-selective alkyne hydrogenation controlled by cyclic (alkyl)(amino)carbene ligands |
| title_full | Chromium-catalyzed stereodivergent E- and Z-selective alkyne hydrogenation controlled by cyclic (alkyl)(amino)carbene ligands |
| title_fullStr | Chromium-catalyzed stereodivergent E- and Z-selective alkyne hydrogenation controlled by cyclic (alkyl)(amino)carbene ligands |
| title_full_unstemmed | Chromium-catalyzed stereodivergent E- and Z-selective alkyne hydrogenation controlled by cyclic (alkyl)(amino)carbene ligands |
| title_short | Chromium-catalyzed stereodivergent E- and Z-selective alkyne hydrogenation controlled by cyclic (alkyl)(amino)carbene ligands |
| title_sort | chromium catalyzed stereodivergent e and z selective alkyne hydrogenation controlled by cyclic alkyl amino carbene ligands |
| url | https://doi.org/10.1038/s41467-023-36677-9 |
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