Bis[1-(2-ethoxyphenyl)-3-(4-nitrophenyl)triazenido]mercury(II)

In the title compound, [Hg(C14H13N4O3)2], the central Hg atom (site symmetry 2) is six-coordinated by two tridentate 1-(2-ethoxyphenyl)-3-(4-nitrophenyl)triazenide ligands through two N and one O atoms. The mononuclear complex molecules are connected into two parallel chains by intermolecular C&...

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Bibliographic Details
Main Authors: Mohammad Kazem Rofouei, Ehsan Fereyduni, Jafar Attar Gharamaleki, Giuseppe Bruno, Hadi Amiri Rudbari
Format: Article
Language:English
Published: International Union of Crystallography 2010-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810031326
Description
Summary:In the title compound, [Hg(C14H13N4O3)2], the central Hg atom (site symmetry 2) is six-coordinated by two tridentate 1-(2-ethoxyphenyl)-3-(4-nitrophenyl)triazenide ligands through two N and one O atoms. The mononuclear complex molecules are connected into two parallel chains by intermolecular C—H...O hydrogen-bonding interactions. These chains are connected to each other by face-to-edge C—H...π interactions between the CH of the ethoxy groups and the aromatic rings, resulting in a two-dimensional architecture in the ac plane.
ISSN:1600-5368