cis-(Nitrato-κ2O,O′)(2,5,5,7,9,12,12,14-octamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)cadmium nitrate hemihydrate
The CdII atom in the title complex, [Cd(NO3)(C18H40N4)]NO3·0.5H2O, is coordinated within a cis-N4O2 donor set provided by the tetradentate macrocyclic ligand and two O atoms of a nitrate anion; the coordination geometry is distorted octahedral. The lattice water molecule is located on a...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681201238X |
| _version_ | 1818960579537141760 |
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| author | Tapashi G. Roy Saroj K. S. Hazari Babul Chandra Nath Seik Weng Ng Edward R. T. Tiekink |
| author_facet | Tapashi G. Roy Saroj K. S. Hazari Babul Chandra Nath Seik Weng Ng Edward R. T. Tiekink |
| author_sort | Tapashi G. Roy |
| collection | DOAJ |
| description | The CdII atom in the title complex, [Cd(NO3)(C18H40N4)]NO3·0.5H2O, is coordinated within a cis-N4O2 donor set provided by the tetradentate macrocyclic ligand and two O atoms of a nitrate anion; the coordination geometry is distorted octahedral. The lattice water molecule is located on a twofold rotation axis. N—H...O hydrogen bonds and weak C—H...O interactions link the complex cations into a supramolecular layer in the bc plane. Layers are connected by O—H...O hydrogen bonds between the lattice water molecule and the non-coordinating nitrate anion, as well as by weak C—H...O contacts. |
| first_indexed | 2024-12-20T11:59:47Z |
| format | Article |
| id | doaj.art-ea1d32149c89421fa70a988f54d84ba1 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:59:47Z |
| publishDate | 2012-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-ea1d32149c89421fa70a988f54d84ba12022-12-21T19:41:34ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-04-01684m494m49510.1107/S160053681201238Xcis-(Nitrato-κ2O,O′)(2,5,5,7,9,12,12,14-octamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)cadmium nitrate hemihydrateTapashi G. RoySaroj K. S. HazariBabul Chandra NathSeik Weng NgEdward R. T. TiekinkThe CdII atom in the title complex, [Cd(NO3)(C18H40N4)]NO3·0.5H2O, is coordinated within a cis-N4O2 donor set provided by the tetradentate macrocyclic ligand and two O atoms of a nitrate anion; the coordination geometry is distorted octahedral. The lattice water molecule is located on a twofold rotation axis. N—H...O hydrogen bonds and weak C—H...O interactions link the complex cations into a supramolecular layer in the bc plane. Layers are connected by O—H...O hydrogen bonds between the lattice water molecule and the non-coordinating nitrate anion, as well as by weak C—H...O contacts.http://scripts.iucr.org/cgi-bin/paper?S160053681201238X |
| spellingShingle | Tapashi G. Roy Saroj K. S. Hazari Babul Chandra Nath Seik Weng Ng Edward R. T. Tiekink cis-(Nitrato-κ2O,O′)(2,5,5,7,9,12,12,14-octamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)cadmium nitrate hemihydrate Acta Crystallographica Section E |
| title | cis-(Nitrato-κ2O,O′)(2,5,5,7,9,12,12,14-octamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)cadmium nitrate hemihydrate |
| title_full | cis-(Nitrato-κ2O,O′)(2,5,5,7,9,12,12,14-octamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)cadmium nitrate hemihydrate |
| title_fullStr | cis-(Nitrato-κ2O,O′)(2,5,5,7,9,12,12,14-octamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)cadmium nitrate hemihydrate |
| title_full_unstemmed | cis-(Nitrato-κ2O,O′)(2,5,5,7,9,12,12,14-octamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)cadmium nitrate hemihydrate |
| title_short | cis-(Nitrato-κ2O,O′)(2,5,5,7,9,12,12,14-octamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)cadmium nitrate hemihydrate |
| title_sort | cis nitrato amp 954 2o o amp 8242 2 5 5 7 9 12 12 14 octamethyl 1 4 8 11 tetraazacyclotetradecane amp 954 4n n amp 8242 n amp 8242 amp 8242 n amp 8242 amp 8242 amp 8242 cadmium nitrate hemihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053681201238X |
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