Thermodynamic re-optimization of the Cu-Mg-Sn system at the Cu-Mg side

Thermodynamic description of the ternary Cu-Mg-Sn system at its Cu-Mg side is presented. The thermodynamic parameters of the binary sub-systems, Cu-Mg, Cu-Sn and Mg-Sn, are taken from the earlier SGTE-based assessments (modifying the Mg-Sn description slightly) and those of the Cu-Mg-Si system ar...

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Main Authors: Miettinen J., Vassilev G.
Format: Article
Language:English
Published: Technical Faculty, Bor 2012-01-01
Series:Journal of Mining and Metallurgy. Section B: Metallurgy
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/1450-5339/2012/1450-53391200008M.pdf
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author Miettinen J.
Vassilev G.
author_facet Miettinen J.
Vassilev G.
author_sort Miettinen J.
collection DOAJ
description Thermodynamic description of the ternary Cu-Mg-Sn system at its Cu-Mg side is presented. The thermodynamic parameters of the binary sub-systems, Cu-Mg, Cu-Sn and Mg-Sn, are taken from the earlier SGTE-based assessments (modifying the Mg-Sn description slightly) and those of the Cu-Mg-Si system are optimized in this study using the experimental thermodynamic and phase equilibrium data. The solution phases of the systems are described with the substitutional solution model and the intermetallic Cu2Mg compound (Laves C15), treated as simple semi-stoichiometric phases of the (A,B)pCq type, is described with the twosublattice model. The present ternary description is valid for tin contents up to 45 wt% (xSn≈0.30).
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spelling doaj.art-ea4e6e6f58b04d12b1292ce49f02ece22022-12-22T03:22:47ZengTechnical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392012-01-01481536210.2298/JMMB110731008MThermodynamic re-optimization of the Cu-Mg-Sn system at the Cu-Mg sideMiettinen J.Vassilev G.Thermodynamic description of the ternary Cu-Mg-Sn system at its Cu-Mg side is presented. The thermodynamic parameters of the binary sub-systems, Cu-Mg, Cu-Sn and Mg-Sn, are taken from the earlier SGTE-based assessments (modifying the Mg-Sn description slightly) and those of the Cu-Mg-Si system are optimized in this study using the experimental thermodynamic and phase equilibrium data. The solution phases of the systems are described with the substitutional solution model and the intermetallic Cu2Mg compound (Laves C15), treated as simple semi-stoichiometric phases of the (A,B)pCq type, is described with the twosublattice model. The present ternary description is valid for tin contents up to 45 wt% (xSn≈0.30).http://www.doiserbia.nb.rs/img/doi/1450-5339/2012/1450-53391200008M.pdfphase diagramsthermodynamic modelingternary systemscopper-magnesium alloys
spellingShingle Miettinen J.
Vassilev G.
Thermodynamic re-optimization of the Cu-Mg-Sn system at the Cu-Mg side
Journal of Mining and Metallurgy. Section B: Metallurgy
phase diagrams
thermodynamic modeling
ternary systems
copper-magnesium alloys
title Thermodynamic re-optimization of the Cu-Mg-Sn system at the Cu-Mg side
title_full Thermodynamic re-optimization of the Cu-Mg-Sn system at the Cu-Mg side
title_fullStr Thermodynamic re-optimization of the Cu-Mg-Sn system at the Cu-Mg side
title_full_unstemmed Thermodynamic re-optimization of the Cu-Mg-Sn system at the Cu-Mg side
title_short Thermodynamic re-optimization of the Cu-Mg-Sn system at the Cu-Mg side
title_sort thermodynamic re optimization of the cu mg sn system at the cu mg side
topic phase diagrams
thermodynamic modeling
ternary systems
copper-magnesium alloys
url http://www.doiserbia.nb.rs/img/doi/1450-5339/2012/1450-53391200008M.pdf
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