Dependence of the Adsorption Capacity and Thermal Stability of Y Zeolites upon Si/Al Ratio

Three series of dealuminated Y zeolites have been prepared by different procedures. The adsorption of n -hexane and water and the thermal stability have been studied with respect to their dependence on the content of framework aluminium. The reduction of their micropore volume can be calculated from...

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Bibliographic Details
Main Authors: U. Lohse, G. Engelhardt, E. Alsdorf, P. Kölsch, M. Feist, V. Patzelová
Format: Article
Language:English
Published: SAGE Publications 1986-09-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1177/026361748600300304
Description
Summary:Three series of dealuminated Y zeolites have been prepared by different procedures. The adsorption of n -hexane and water and the thermal stability have been studied with respect to their dependence on the content of framework aluminium. The reduction of their micropore volume can be calculated from the loss of framework aluminium. The water uptake decreases strongly below an aluminium content of 30 atoms per unit cell. At an aluminium content ≤8 atoms the zeolitic micropore structure is hydrophobic. Two ranges of thermal stability can be distinguished with decreasing aluminium content.
ISSN:0263-6174
2048-4038