Towards the Large-Scale Electrochemical Reduction of Carbon Dioxide

The severe increase in the CO<sub>2</sub> concentration is a causative factor of global warming, which accelerates the destruction of ecosystems. The massive utilization of CO<sub>2</sub> for value-added chemical production is a key to commercialization to guarantee both econ...

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Main Authors: Subin Park, Devina Thasia Wijaya, Jonggeol Na, Chan Woo Lee
Format: Article
Language:English
Published: MDPI AG 2021-02-01
Series:Catalysts
Subjects:
Online Access:https://www.mdpi.com/2073-4344/11/2/253
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author Subin Park
Devina Thasia Wijaya
Jonggeol Na
Chan Woo Lee
author_facet Subin Park
Devina Thasia Wijaya
Jonggeol Na
Chan Woo Lee
author_sort Subin Park
collection DOAJ
description The severe increase in the CO<sub>2</sub> concentration is a causative factor of global warming, which accelerates the destruction of ecosystems. The massive utilization of CO<sub>2</sub> for value-added chemical production is a key to commercialization to guarantee both economic feasibility and negative carbon emission. Although the electrochemical reduction of CO<sub>2</sub> is one of the most promising technologies, there are remaining challenges for large-scale production. Herein, an overview of these limitations is provided in terms of devices, processes, and catalysts. Further, the economic feasibility of the technology is described in terms of individual processes such as reactions and separation. Additionally, for the practical implementation of the electrochemical CO<sub>2</sub> conversion technology, stable electrocatalytic performances need to be addressed in terms of current density, Faradaic efficiency, and overpotential. Hence, the present review also covers the known degradation behaviors and mechanisms of electrocatalysts and electrodes during electrolysis. Furthermore, strategic approaches for overcoming the stability issues are introduced based on recent reports from various research areas involved in the electrocatalytic conversion.
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spelling doaj.art-ea5f5116f0344ae59f56fc88fc53f3422023-12-11T17:00:33ZengMDPI AGCatalysts2073-43442021-02-0111225310.3390/catal11020253Towards the Large-Scale Electrochemical Reduction of Carbon DioxideSubin Park0Devina Thasia Wijaya1Jonggeol Na2Chan Woo Lee3Department of Chemical Engineering and Materials Science, Ewha Womans University, Seoul 03760, KoreaDepartment of Chemistry, Kookmin University, Seoul 02707, KoreaDepartment of Chemical Engineering and Materials Science, Ewha Womans University, Seoul 03760, KoreaDepartment of Chemistry, Kookmin University, Seoul 02707, KoreaThe severe increase in the CO<sub>2</sub> concentration is a causative factor of global warming, which accelerates the destruction of ecosystems. The massive utilization of CO<sub>2</sub> for value-added chemical production is a key to commercialization to guarantee both economic feasibility and negative carbon emission. Although the electrochemical reduction of CO<sub>2</sub> is one of the most promising technologies, there are remaining challenges for large-scale production. Herein, an overview of these limitations is provided in terms of devices, processes, and catalysts. Further, the economic feasibility of the technology is described in terms of individual processes such as reactions and separation. Additionally, for the practical implementation of the electrochemical CO<sub>2</sub> conversion technology, stable electrocatalytic performances need to be addressed in terms of current density, Faradaic efficiency, and overpotential. Hence, the present review also covers the known degradation behaviors and mechanisms of electrocatalysts and electrodes during electrolysis. Furthermore, strategic approaches for overcoming the stability issues are introduced based on recent reports from various research areas involved in the electrocatalytic conversion.https://www.mdpi.com/2073-4344/11/2/253electrochemical reduction of carbon dioxideprocess systemsstabilitytechno-economic analysiscommercializationlarge-scale production
spellingShingle Subin Park
Devina Thasia Wijaya
Jonggeol Na
Chan Woo Lee
Towards the Large-Scale Electrochemical Reduction of Carbon Dioxide
Catalysts
electrochemical reduction of carbon dioxide
process systems
stability
techno-economic analysis
commercialization
large-scale production
title Towards the Large-Scale Electrochemical Reduction of Carbon Dioxide
title_full Towards the Large-Scale Electrochemical Reduction of Carbon Dioxide
title_fullStr Towards the Large-Scale Electrochemical Reduction of Carbon Dioxide
title_full_unstemmed Towards the Large-Scale Electrochemical Reduction of Carbon Dioxide
title_short Towards the Large-Scale Electrochemical Reduction of Carbon Dioxide
title_sort towards the large scale electrochemical reduction of carbon dioxide
topic electrochemical reduction of carbon dioxide
process systems
stability
techno-economic analysis
commercialization
large-scale production
url https://www.mdpi.com/2073-4344/11/2/253
work_keys_str_mv AT subinpark towardsthelargescaleelectrochemicalreductionofcarbondioxide
AT devinathasiawijaya towardsthelargescaleelectrochemicalreductionofcarbondioxide
AT jonggeolna towardsthelargescaleelectrochemicalreductionofcarbondioxide
AT chanwoolee towardsthelargescaleelectrochemicalreductionofcarbondioxide