Design of innovative agrochemical delivery system for sustainable agriculture and to alleviate environmental and health hazards

This article deals with formation of hydrogels encapsulated with agrochemicals for minimizing agrochemical-environmental pollution and health hazards. These copolymers as controlled release formulations (CRF) were designed by grafting reaction onto natural polymers starch-agar-gelatin and poly(2-acr...

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Main Authors: Jasvir Singh, Baljit Singh, Vishavnath
Format: Article
Language:English
Published: Elsevier 2023-12-01
Series:Sustainable Chemistry for the Environment
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2949839223000469
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author Jasvir Singh
Baljit Singh
Vishavnath
author_facet Jasvir Singh
Baljit Singh
Vishavnath
author_sort Jasvir Singh
collection DOAJ
description This article deals with formation of hydrogels encapsulated with agrochemicals for minimizing agrochemical-environmental pollution and health hazards. These copolymers as controlled release formulations (CRF) were designed by grafting reaction onto natural polymers starch-agar-gelatin and poly(2-acrylamido-2-methylpropanesulphonic acid) (AMPS). Copolymers were characterized by SEM, AFM, and XRD along with FTIR and 13C NMR techniques. SEM and AFM confirmed the un-even morphology with surface roughness and XRD indicated the amorphous nature of the polymers after grafting. Controlled diffusion of thiophante methyl fungicide for 72 h occurred with diffusion non-Fickian type. It is useful observation for preventing leaching and evaporation loss of fungicide and to alleviate environmental and health hazards. After degradation CRF may improve micronutrients and soil quality.
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spelling doaj.art-ea887890de404ab8ac621b855b6ecb7b2024-03-29T05:52:31ZengElsevierSustainable Chemistry for the Environment2949-83922023-12-014100046Design of innovative agrochemical delivery system for sustainable agriculture and to alleviate environmental and health hazardsJasvir Singh0Baljit Singh1 Vishavnath2Corresponding author.; Department of Chemistry, Himachal Pradesh University, Shimla 171005, IndiaDepartment of Chemistry, Himachal Pradesh University, Shimla 171005, IndiaDepartment of Chemistry, Himachal Pradesh University, Shimla 171005, IndiaThis article deals with formation of hydrogels encapsulated with agrochemicals for minimizing agrochemical-environmental pollution and health hazards. These copolymers as controlled release formulations (CRF) were designed by grafting reaction onto natural polymers starch-agar-gelatin and poly(2-acrylamido-2-methylpropanesulphonic acid) (AMPS). Copolymers were characterized by SEM, AFM, and XRD along with FTIR and 13C NMR techniques. SEM and AFM confirmed the un-even morphology with surface roughness and XRD indicated the amorphous nature of the polymers after grafting. Controlled diffusion of thiophante methyl fungicide for 72 h occurred with diffusion non-Fickian type. It is useful observation for preventing leaching and evaporation loss of fungicide and to alleviate environmental and health hazards. After degradation CRF may improve micronutrients and soil quality.http://www.sciencedirect.com/science/article/pii/S2949839223000469GraftingHydrogelFungicideControl release
spellingShingle Jasvir Singh
Baljit Singh
Vishavnath
Design of innovative agrochemical delivery system for sustainable agriculture and to alleviate environmental and health hazards
Sustainable Chemistry for the Environment
Grafting
Hydrogel
Fungicide
Control release
title Design of innovative agrochemical delivery system for sustainable agriculture and to alleviate environmental and health hazards
title_full Design of innovative agrochemical delivery system for sustainable agriculture and to alleviate environmental and health hazards
title_fullStr Design of innovative agrochemical delivery system for sustainable agriculture and to alleviate environmental and health hazards
title_full_unstemmed Design of innovative agrochemical delivery system for sustainable agriculture and to alleviate environmental and health hazards
title_short Design of innovative agrochemical delivery system for sustainable agriculture and to alleviate environmental and health hazards
title_sort design of innovative agrochemical delivery system for sustainable agriculture and to alleviate environmental and health hazards
topic Grafting
Hydrogel
Fungicide
Control release
url http://www.sciencedirect.com/science/article/pii/S2949839223000469
work_keys_str_mv AT jasvirsingh designofinnovativeagrochemicaldeliverysystemforsustainableagricultureandtoalleviateenvironmentalandhealthhazards
AT baljitsingh designofinnovativeagrochemicaldeliverysystemforsustainableagricultureandtoalleviateenvironmentalandhealthhazards
AT vishavnath designofinnovativeagrochemicaldeliverysystemforsustainableagricultureandtoalleviateenvironmentalandhealthhazards