A REACTION OF 4, 5-DIPHENYLIMIDAZOLE NITRATION IN THE PRESENCE OF SOME 3D-METALS NITRATES
By interaction of cobalt(II), nickel(II), or zinc(II) nitrate with 4,5- diphenylimidazole in methanol in solvotermal conditions the new derivative of imidazole (4,5-diphenyl-2-nitroimidazole) and three new coordinative compounds [M(4,5-Ph2ImNO2)2(CH3OH)2] have been synthesized and investigated. Met...
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Academy of Sciences of Moldova, Institute of Chemistry
2012-12-01
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Series: | Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry |
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Online Access: | http://www.cjm.asm.md/sites/default/files/article_files/Voda%20124-129.pdf |
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author | I. Voda V. Druta C. Indricean I. Ciumacov C. Turta |
author_facet | I. Voda V. Druta C. Indricean I. Ciumacov C. Turta |
author_sort | I. Voda |
collection | DOAJ |
description | By interaction of cobalt(II), nickel(II), or zinc(II) nitrate with 4,5- diphenylimidazole in methanol in solvotermal conditions the new derivative of
imidazole (4,5-diphenyl-2-nitroimidazole) and three new coordinative compounds [M(4,5-Ph2ImNO2)2(CH3OH)2] have been synthesized and investigated. Metal ions have a distorted octahedral environment with N2O4. Coordination number of metal is six. Ligand is coordinated to metal ion by one oxygen atom of nitrogroup and one nitrogen atom of imidazole. |
first_indexed | 2024-12-19T03:23:26Z |
format | Article |
id | doaj.art-ea9c6f789144406f86a07d355cd9cd2f |
institution | Directory Open Access Journal |
issn | 1857-1727 2345-1688 |
language | English |
last_indexed | 2024-12-19T03:23:26Z |
publishDate | 2012-12-01 |
publisher | Academy of Sciences of Moldova, Institute of Chemistry |
record_format | Article |
series | Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry |
spelling | doaj.art-ea9c6f789144406f86a07d355cd9cd2f2022-12-21T20:37:42ZengAcademy of Sciences of Moldova, Institute of ChemistryChemistry Journal of Moldova: General, Industrial and Ecological Chemistry1857-17272345-16882012-12-0172124129A REACTION OF 4, 5-DIPHENYLIMIDAZOLE NITRATION IN THE PRESENCE OF SOME 3D-METALS NITRATESI. Voda0V. Druta1C. Indricean2 I. Ciumacov3C. Turta4Institute of Chemistry, Academy of Sciences of Moldova, 3, Academiei str., MD-2028, Chisinau, Moldova Institute of Chemistry, Academy of Sciences of Moldova, 3, Academiei str., MD-2028, Chisinau, Moldova Institute of Chemistry, Academy of Sciences of Moldova, 3, Academiei str., MD-2028, Chisinau, Moldova Institute of Applied Physics, Academy of Sciences of Moldova, 5, Academiei str., MD-2028,Chisinau, MoldovaInstitute of Chemistry, Academy of Sciences of Moldova, 3, Academiei str., MD-2028, Chisinau, Moldova By interaction of cobalt(II), nickel(II), or zinc(II) nitrate with 4,5- diphenylimidazole in methanol in solvotermal conditions the new derivative of imidazole (4,5-diphenyl-2-nitroimidazole) and three new coordinative compounds [M(4,5-Ph2ImNO2)2(CH3OH)2] have been synthesized and investigated. Metal ions have a distorted octahedral environment with N2O4. Coordination number of metal is six. Ligand is coordinated to metal ion by one oxygen atom of nitrogroup and one nitrogen atom of imidazole.http://www.cjm.asm.md/sites/default/files/article_files/Voda%20124-129.pdfNickel(II)Zinc(II) complexes; 4physico- chemical propertiessolvothermal synthesisphysicochemical properties |
spellingShingle | I. Voda V. Druta C. Indricean I. Ciumacov C. Turta A REACTION OF 4, 5-DIPHENYLIMIDAZOLE NITRATION IN THE PRESENCE OF SOME 3D-METALS NITRATES Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry Nickel(II) Zinc(II) complexes; 4 physico- chemical properties solvothermal synthesis physicochemical properties |
title | A REACTION OF 4, 5-DIPHENYLIMIDAZOLE NITRATION IN THE PRESENCE OF SOME 3D-METALS NITRATES |
title_full | A REACTION OF 4, 5-DIPHENYLIMIDAZOLE NITRATION IN THE PRESENCE OF SOME 3D-METALS NITRATES |
title_fullStr | A REACTION OF 4, 5-DIPHENYLIMIDAZOLE NITRATION IN THE PRESENCE OF SOME 3D-METALS NITRATES |
title_full_unstemmed | A REACTION OF 4, 5-DIPHENYLIMIDAZOLE NITRATION IN THE PRESENCE OF SOME 3D-METALS NITRATES |
title_short | A REACTION OF 4, 5-DIPHENYLIMIDAZOLE NITRATION IN THE PRESENCE OF SOME 3D-METALS NITRATES |
title_sort | reaction of 4 5 diphenylimidazole nitration in the presence of some 3d metals nitrates |
topic | Nickel(II) Zinc(II) complexes; 4 physico- chemical properties solvothermal synthesis physicochemical properties |
url | http://www.cjm.asm.md/sites/default/files/article_files/Voda%20124-129.pdf |
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