A REACTION OF 4, 5-DIPHENYLIMIDAZOLE NITRATION IN THE PRESENCE OF SOME 3D-METALS NITRATES

By interaction of cobalt(II), nickel(II), or zinc(II) nitrate with 4,5- diphenylimidazole in methanol in solvotermal conditions the new derivative of imidazole (4,5-diphenyl-2-nitroimidazole) and three new coordinative compounds [M(4,5-Ph2ImNO2)2(CH3OH)2] have been synthesized and investigated. Met...

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Main Authors: I. Voda, V. Druta, C. Indricean, I. Ciumacov, C. Turta
Format: Article
Language:English
Published: Academy of Sciences of Moldova, Institute of Chemistry 2012-12-01
Series:Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry
Subjects:
Online Access:http://www.cjm.asm.md/sites/default/files/article_files/Voda%20124-129.pdf
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author I. Voda
V. Druta
C. Indricean
I. Ciumacov
C. Turta
author_facet I. Voda
V. Druta
C. Indricean
I. Ciumacov
C. Turta
author_sort I. Voda
collection DOAJ
description By interaction of cobalt(II), nickel(II), or zinc(II) nitrate with 4,5- diphenylimidazole in methanol in solvotermal conditions the new derivative of imidazole (4,5-diphenyl-2-nitroimidazole) and three new coordinative compounds [M(4,5-Ph2ImNO2)2(CH3OH)2] have been synthesized and investigated. Metal ions have a distorted octahedral environment with N2O4. Coordination number of metal is six. Ligand is coordinated to metal ion by one oxygen atom of nitrogroup and one nitrogen atom of imidazole.
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spelling doaj.art-ea9c6f789144406f86a07d355cd9cd2f2022-12-21T20:37:42ZengAcademy of Sciences of Moldova, Institute of ChemistryChemistry Journal of Moldova: General, Industrial and Ecological Chemistry1857-17272345-16882012-12-0172124129A REACTION OF 4, 5-DIPHENYLIMIDAZOLE NITRATION IN THE PRESENCE OF SOME 3D-METALS NITRATESI. Voda0V. Druta1C. Indricean2 I. Ciumacov3C. Turta4Institute of Chemistry, Academy of Sciences of Moldova, 3, Academiei str., MD-2028, Chisinau, Moldova Institute of Chemistry, Academy of Sciences of Moldova, 3, Academiei str., MD-2028, Chisinau, Moldova Institute of Chemistry, Academy of Sciences of Moldova, 3, Academiei str., MD-2028, Chisinau, Moldova Institute of Applied Physics, Academy of Sciences of Moldova, 5, Academiei str., MD-2028,Chisinau, MoldovaInstitute of Chemistry, Academy of Sciences of Moldova, 3, Academiei str., MD-2028, Chisinau, Moldova By interaction of cobalt(II), nickel(II), or zinc(II) nitrate with 4,5- diphenylimidazole in methanol in solvotermal conditions the new derivative of imidazole (4,5-diphenyl-2-nitroimidazole) and three new coordinative compounds [M(4,5-Ph2ImNO2)2(CH3OH)2] have been synthesized and investigated. Metal ions have a distorted octahedral environment with N2O4. Coordination number of metal is six. Ligand is coordinated to metal ion by one oxygen atom of nitrogroup and one nitrogen atom of imidazole.http://www.cjm.asm.md/sites/default/files/article_files/Voda%20124-129.pdfNickel(II)Zinc(II) complexes; 4physico- chemical propertiessolvothermal synthesisphysicochemical properties
spellingShingle I. Voda
V. Druta
C. Indricean
I. Ciumacov
C. Turta
A REACTION OF 4, 5-DIPHENYLIMIDAZOLE NITRATION IN THE PRESENCE OF SOME 3D-METALS NITRATES
Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry
Nickel(II)
Zinc(II) complexes; 4
physico- chemical properties
solvothermal synthesis
physicochemical properties
title A REACTION OF 4, 5-DIPHENYLIMIDAZOLE NITRATION IN THE PRESENCE OF SOME 3D-METALS NITRATES
title_full A REACTION OF 4, 5-DIPHENYLIMIDAZOLE NITRATION IN THE PRESENCE OF SOME 3D-METALS NITRATES
title_fullStr A REACTION OF 4, 5-DIPHENYLIMIDAZOLE NITRATION IN THE PRESENCE OF SOME 3D-METALS NITRATES
title_full_unstemmed A REACTION OF 4, 5-DIPHENYLIMIDAZOLE NITRATION IN THE PRESENCE OF SOME 3D-METALS NITRATES
title_short A REACTION OF 4, 5-DIPHENYLIMIDAZOLE NITRATION IN THE PRESENCE OF SOME 3D-METALS NITRATES
title_sort reaction of 4 5 diphenylimidazole nitration in the presence of some 3d metals nitrates
topic Nickel(II)
Zinc(II) complexes; 4
physico- chemical properties
solvothermal synthesis
physicochemical properties
url http://www.cjm.asm.md/sites/default/files/article_files/Voda%20124-129.pdf
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