A novel Schiff-based palladium-complex as a capable nanocatalyst for the green synthesis of hexahydroquinolines and benzochromenes
A novel Schiff-based Pd complex (Fe3O4@SiO2@CPTES@MEL@SAL@Pd) was synthesized by modification of Fe3O4 NPs with tetraethyl orthosilicate (TEOS), 3-chloropropyltriethoxysilane (CPTES), melamine (MEL) and salicylaldehyde (SAL) and further complexation with Pd(II) and characterized by various technique...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2023-08-01
|
| Series: | Catalysis Communications |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S1566736723001231 |
| _version_ | 1797754062746157056 |
|---|---|
| author | Shiva Ghorbani Davood Habibi Somayyeh Heydari Hakimeh Ebrahimi Asl |
| author_facet | Shiva Ghorbani Davood Habibi Somayyeh Heydari Hakimeh Ebrahimi Asl |
| author_sort | Shiva Ghorbani |
| collection | DOAJ |
| description | A novel Schiff-based Pd complex (Fe3O4@SiO2@CPTES@MEL@SAL@Pd) was synthesized by modification of Fe3O4 NPs with tetraethyl orthosilicate (TEOS), 3-chloropropyltriethoxysilane (CPTES), melamine (MEL) and salicylaldehyde (SAL) and further complexation with Pd(II) and characterized by various techniques.Then, the catalytic activity of the Fe3O4-supported Schiff-based Pd complex was studied in the green one-pot multicomponent condensation reactions of: i) the aldehyde, dimedone, ethyl acetoacetate and ammonium acetate (synthesis of hexahydroquinolines) and ii) the aldehyde, malononitrile and 2-hydroxynaphthalene-1,4-dione (synthesis of benzochromenes). |
| first_indexed | 2024-03-12T17:27:02Z |
| format | Article |
| id | doaj.art-ea9d553513c4454ab08729fcba9e7ca1 |
| institution | Directory Open Access Journal |
| issn | 1873-3905 |
| language | English |
| last_indexed | 2024-03-12T17:27:02Z |
| publishDate | 2023-08-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Catalysis Communications |
| spelling | doaj.art-ea9d553513c4454ab08729fcba9e7ca12023-08-05T05:15:41ZengElsevierCatalysis Communications1873-39052023-08-01181106721A novel Schiff-based palladium-complex as a capable nanocatalyst for the green synthesis of hexahydroquinolines and benzochromenesShiva Ghorbani0Davood Habibi1Somayyeh Heydari2Hakimeh Ebrahimi Asl3Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan 6517838683, IranDepartment of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan 6517838683, Iran; Corresponding author.Saveh University of Medical Sciences, Saveh, IranDepartment of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan 6517838683, IranA novel Schiff-based Pd complex (Fe3O4@SiO2@CPTES@MEL@SAL@Pd) was synthesized by modification of Fe3O4 NPs with tetraethyl orthosilicate (TEOS), 3-chloropropyltriethoxysilane (CPTES), melamine (MEL) and salicylaldehyde (SAL) and further complexation with Pd(II) and characterized by various techniques.Then, the catalytic activity of the Fe3O4-supported Schiff-based Pd complex was studied in the green one-pot multicomponent condensation reactions of: i) the aldehyde, dimedone, ethyl acetoacetate and ammonium acetate (synthesis of hexahydroquinolines) and ii) the aldehyde, malononitrile and 2-hydroxynaphthalene-1,4-dione (synthesis of benzochromenes).http://www.sciencedirect.com/science/article/pii/S1566736723001231The Schiff-based Pd-complexNano-catalystMulti-component reactionsHexahydroquinolineBenzochromenes |
| spellingShingle | Shiva Ghorbani Davood Habibi Somayyeh Heydari Hakimeh Ebrahimi Asl A novel Schiff-based palladium-complex as a capable nanocatalyst for the green synthesis of hexahydroquinolines and benzochromenes Catalysis Communications The Schiff-based Pd-complex Nano-catalyst Multi-component reactions Hexahydroquinoline Benzochromenes |
| title | A novel Schiff-based palladium-complex as a capable nanocatalyst for the green synthesis of hexahydroquinolines and benzochromenes |
| title_full | A novel Schiff-based palladium-complex as a capable nanocatalyst for the green synthesis of hexahydroquinolines and benzochromenes |
| title_fullStr | A novel Schiff-based palladium-complex as a capable nanocatalyst for the green synthesis of hexahydroquinolines and benzochromenes |
| title_full_unstemmed | A novel Schiff-based palladium-complex as a capable nanocatalyst for the green synthesis of hexahydroquinolines and benzochromenes |
| title_short | A novel Schiff-based palladium-complex as a capable nanocatalyst for the green synthesis of hexahydroquinolines and benzochromenes |
| title_sort | novel schiff based palladium complex as a capable nanocatalyst for the green synthesis of hexahydroquinolines and benzochromenes |
| topic | The Schiff-based Pd-complex Nano-catalyst Multi-component reactions Hexahydroquinoline Benzochromenes |
| url | http://www.sciencedirect.com/science/article/pii/S1566736723001231 |
| work_keys_str_mv | AT shivaghorbani anovelschiffbasedpalladiumcomplexasacapablenanocatalystforthegreensynthesisofhexahydroquinolinesandbenzochromenes AT davoodhabibi anovelschiffbasedpalladiumcomplexasacapablenanocatalystforthegreensynthesisofhexahydroquinolinesandbenzochromenes AT somayyehheydari anovelschiffbasedpalladiumcomplexasacapablenanocatalystforthegreensynthesisofhexahydroquinolinesandbenzochromenes AT hakimehebrahimiasl anovelschiffbasedpalladiumcomplexasacapablenanocatalystforthegreensynthesisofhexahydroquinolinesandbenzochromenes AT shivaghorbani novelschiffbasedpalladiumcomplexasacapablenanocatalystforthegreensynthesisofhexahydroquinolinesandbenzochromenes AT davoodhabibi novelschiffbasedpalladiumcomplexasacapablenanocatalystforthegreensynthesisofhexahydroquinolinesandbenzochromenes AT somayyehheydari novelschiffbasedpalladiumcomplexasacapablenanocatalystforthegreensynthesisofhexahydroquinolinesandbenzochromenes AT hakimehebrahimiasl novelschiffbasedpalladiumcomplexasacapablenanocatalystforthegreensynthesisofhexahydroquinolinesandbenzochromenes |