Numerical simulation of quantum dots as a buffer layer in CIGS solar cells: a comparative study

Abstract Quantum bandgap buffer layers can improve sunlight absorption in the short wavelength region, hence improving the performance of CIGS solar cells. In this study, we use numerical modelling to determine the impact of various buffer layers' electrical characteristics on the performance o...

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Main Authors: Zuhair R. Abdulghani, Asmaa Soheil Najm, Araa Mebdir Holi, Asla Abdullah Al-Zahrani, Khaled S. Al-Zahrani, Hazim Moria
Format: Article
Language:English
Published: Nature Portfolio 2022-05-01
Series:Scientific Reports
Online Access:https://doi.org/10.1038/s41598-022-12234-0
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author Zuhair R. Abdulghani
Asmaa Soheil Najm
Araa Mebdir Holi
Asla Abdullah Al-Zahrani
Khaled S. Al-Zahrani
Hazim Moria
author_facet Zuhair R. Abdulghani
Asmaa Soheil Najm
Araa Mebdir Holi
Asla Abdullah Al-Zahrani
Khaled S. Al-Zahrani
Hazim Moria
author_sort Zuhair R. Abdulghani
collection DOAJ
description Abstract Quantum bandgap buffer layers can improve sunlight absorption in the short wavelength region, hence improving the performance of CIGS solar cells. In this study, we use numerical modelling to determine the impact of various buffer layers' electrical characteristics on the performance of CIGS thin film photovoltaic devices, particularly, carrier concentration and the quantum effect. As well Ag2S buffer layer has been experimentally examined to fulfilment its effect in term of bulk and quantum bandgap. Experimental results depicted that, Ag2S QDs has polycrystalline nature of films, with smooth surface roughness, and average diameter 4 nm. Meanwhile, a simulation revealed that the Fermi level of the (n-buffer layer) material shifts closer to the conduction band with an increase in carrier concentration. The findings indicate that, a buffer layer with a wider bandgap and carrier concentration is an essential demand for achieving a device with a higher conversion efficiency and a broader bandgap-CBO window. It was attributed to beneficial synergistic effects of high carrier concentration and narrower depletion region, which enable carriers to overcome high CBO barrier. Most importantly, modelling results indicate that the optic-electrical characteristics of the buffer layer are critical in determining the progress of a CIGS solar cell.
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spelling doaj.art-eaa7b725c9f84e99b1f77924cc03414f2022-12-22T02:34:22ZengNature PortfolioScientific Reports2045-23222022-05-0112111610.1038/s41598-022-12234-0Numerical simulation of quantum dots as a buffer layer in CIGS solar cells: a comparative studyZuhair R. Abdulghani0Asmaa Soheil Najm1Araa Mebdir Holi2Asla Abdullah Al-Zahrani3Khaled S. Al-Zahrani4Hazim Moria5Department of Mechanical Engineering Technology, Yanbu Industrial CollegeDepartment of Electrical Electronic and Systems Engineering, Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia (UKM)Department of Physics, College of Education, University of Al-QadisiyahImam Abdulrahman Bin Faisal University, Eastern RegionDepartment of Mechanical Engineering Technology, Yanbu Industrial CollegeDepartment of Mechanical Engineering Technology, Yanbu Industrial CollegeAbstract Quantum bandgap buffer layers can improve sunlight absorption in the short wavelength region, hence improving the performance of CIGS solar cells. In this study, we use numerical modelling to determine the impact of various buffer layers' electrical characteristics on the performance of CIGS thin film photovoltaic devices, particularly, carrier concentration and the quantum effect. As well Ag2S buffer layer has been experimentally examined to fulfilment its effect in term of bulk and quantum bandgap. Experimental results depicted that, Ag2S QDs has polycrystalline nature of films, with smooth surface roughness, and average diameter 4 nm. Meanwhile, a simulation revealed that the Fermi level of the (n-buffer layer) material shifts closer to the conduction band with an increase in carrier concentration. The findings indicate that, a buffer layer with a wider bandgap and carrier concentration is an essential demand for achieving a device with a higher conversion efficiency and a broader bandgap-CBO window. It was attributed to beneficial synergistic effects of high carrier concentration and narrower depletion region, which enable carriers to overcome high CBO barrier. Most importantly, modelling results indicate that the optic-electrical characteristics of the buffer layer are critical in determining the progress of a CIGS solar cell.https://doi.org/10.1038/s41598-022-12234-0
spellingShingle Zuhair R. Abdulghani
Asmaa Soheil Najm
Araa Mebdir Holi
Asla Abdullah Al-Zahrani
Khaled S. Al-Zahrani
Hazim Moria
Numerical simulation of quantum dots as a buffer layer in CIGS solar cells: a comparative study
Scientific Reports
title Numerical simulation of quantum dots as a buffer layer in CIGS solar cells: a comparative study
title_full Numerical simulation of quantum dots as a buffer layer in CIGS solar cells: a comparative study
title_fullStr Numerical simulation of quantum dots as a buffer layer in CIGS solar cells: a comparative study
title_full_unstemmed Numerical simulation of quantum dots as a buffer layer in CIGS solar cells: a comparative study
title_short Numerical simulation of quantum dots as a buffer layer in CIGS solar cells: a comparative study
title_sort numerical simulation of quantum dots as a buffer layer in cigs solar cells a comparative study
url https://doi.org/10.1038/s41598-022-12234-0
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