Biodiesel Production from Waste Coconut Oil in Coconut Milk Manufacturing
The purpose of this research was to develop a 3 step biodiesel production from waste coconut oil taken from a wastewater pond in a coconut milk manufacturing plant. Special attention was paid to optimizing the first step, acid catalyzed hydrolysis, to convert the waste coconut oil into high free fat...
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Format: | Article |
Language: | English |
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Walailak University
2013-12-01
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Series: | Walailak Journal of Science and Technology |
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Online Access: | http://wjst.wu.ac.th/index.php/wjst/article/view/687 |
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author | Sujinna KARNNASUTA Vittaya PUNSUVON Rayakorn NOKKAEW |
author_facet | Sujinna KARNNASUTA Vittaya PUNSUVON Rayakorn NOKKAEW |
author_sort | Sujinna KARNNASUTA |
collection | DOAJ |
description | The purpose of this research was to develop a 3 step biodiesel production from waste coconut oil taken from a wastewater pond in a coconut milk manufacturing plant. Special attention was paid to optimizing the first step, acid catalyzed hydrolysis, to convert the waste coconut oil into high free fatty acid oil, 83.32 wt%. The first step was the acid hydrolysis, in order to produce high free fatty acid oil. The optimum condition in acid hydrolysis was 5 % by mass of hydrochloric acid, in order to produce high free fatty acid oil that could be used as raw material for biodiesel production. The second step was the acid esterification, in order to reduce the FFA and convert FFA to methyl ester. The reduction of the FFA from 83.32 % in high free fatty acid oil to less than 2 % required 3 % by mass of hydrochloric acid, a molar ratio of methanol to oil of 10: 1, and a reaction time of 60 min. The alkaline transesterification in the third step was used triglyceride at 1.0wt% of KOH for catalysis, a molar ratio of methanol to oil of 6:1, and a reaction time of 60 min. The waste coconut oil biodiesel was further evaluated by determining its fuel quality, and most of the properties were well within ASTM and EN standards.
doi:10.14456/WJST.2015.24 |
first_indexed | 2024-12-12T11:30:13Z |
format | Article |
id | doaj.art-eac531004f75475b836082d9bab3b827 |
institution | Directory Open Access Journal |
issn | 1686-3933 2228-835X |
language | English |
last_indexed | 2024-12-12T11:30:13Z |
publishDate | 2013-12-01 |
publisher | Walailak University |
record_format | Article |
series | Walailak Journal of Science and Technology |
spelling | doaj.art-eac531004f75475b836082d9bab3b8272022-12-22T00:25:48ZengWalailak UniversityWalailak Journal of Science and Technology1686-39332228-835X2013-12-0112310.2004/wjst.v12i2.687407Biodiesel Production from Waste Coconut Oil in Coconut Milk ManufacturingSujinna KARNNASUTA0Vittaya PUNSUVON1Rayakorn NOKKAEW2Department of Environmental Science, Faculty of Environment, Kasetsart University, Bangkok 10900Department of Chemistry, Faculty of Science, Kasetsart University, Bangkok 10900Center of Excellence-Oil Palm, Kasetsart University, Bangkok 10900The purpose of this research was to develop a 3 step biodiesel production from waste coconut oil taken from a wastewater pond in a coconut milk manufacturing plant. Special attention was paid to optimizing the first step, acid catalyzed hydrolysis, to convert the waste coconut oil into high free fatty acid oil, 83.32 wt%. The first step was the acid hydrolysis, in order to produce high free fatty acid oil. The optimum condition in acid hydrolysis was 5 % by mass of hydrochloric acid, in order to produce high free fatty acid oil that could be used as raw material for biodiesel production. The second step was the acid esterification, in order to reduce the FFA and convert FFA to methyl ester. The reduction of the FFA from 83.32 % in high free fatty acid oil to less than 2 % required 3 % by mass of hydrochloric acid, a molar ratio of methanol to oil of 10: 1, and a reaction time of 60 min. The alkaline transesterification in the third step was used triglyceride at 1.0wt% of KOH for catalysis, a molar ratio of methanol to oil of 6:1, and a reaction time of 60 min. The waste coconut oil biodiesel was further evaluated by determining its fuel quality, and most of the properties were well within ASTM and EN standards. doi:10.14456/WJST.2015.24http://wjst.wu.ac.th/index.php/wjst/article/view/687Waste coconut oilbiodieselhydrolysisesterificationtransesterification |
spellingShingle | Sujinna KARNNASUTA Vittaya PUNSUVON Rayakorn NOKKAEW Biodiesel Production from Waste Coconut Oil in Coconut Milk Manufacturing Walailak Journal of Science and Technology Waste coconut oil biodiesel hydrolysis esterification transesterification |
title | Biodiesel Production from Waste Coconut Oil in Coconut Milk Manufacturing |
title_full | Biodiesel Production from Waste Coconut Oil in Coconut Milk Manufacturing |
title_fullStr | Biodiesel Production from Waste Coconut Oil in Coconut Milk Manufacturing |
title_full_unstemmed | Biodiesel Production from Waste Coconut Oil in Coconut Milk Manufacturing |
title_short | Biodiesel Production from Waste Coconut Oil in Coconut Milk Manufacturing |
title_sort | biodiesel production from waste coconut oil in coconut milk manufacturing |
topic | Waste coconut oil biodiesel hydrolysis esterification transesterification |
url | http://wjst.wu.ac.th/index.php/wjst/article/view/687 |
work_keys_str_mv | AT sujinnakarnnasuta biodieselproductionfromwastecoconutoilincoconutmilkmanufacturing AT vittayapunsuvon biodieselproductionfromwastecoconutoilincoconutmilkmanufacturing AT rayakornnokkaew biodieselproductionfromwastecoconutoilincoconutmilkmanufacturing |