Study on corrosion, hydrogen permeation, and stress corrosion cracking behaviours of AISI 4135 steel in the tidal zone

Abstract High-strength steels are widely used in marine engineering; however, they suffer from the risks of corrosion, hydrogen permeation, and stress corrosion cracking (SCC) in wet–dry cyclic marine environments. In this study, the corrosion, hydrogen permeation, and SCC behaviours of AISI 4135 st...

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Main Authors: Yong Xu, Yanliang Huang, Fanfan Cai, Dongzhu Lu, Zhengquan Wang, Xiutong Wang
Format: Article
Language:English
Published: Nature Portfolio 2022-12-01
Series:npj Materials Degradation
Online Access:https://doi.org/10.1038/s41529-022-00309-2
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author Yong Xu
Yanliang Huang
Fanfan Cai
Dongzhu Lu
Zhengquan Wang
Xiutong Wang
author_facet Yong Xu
Yanliang Huang
Fanfan Cai
Dongzhu Lu
Zhengquan Wang
Xiutong Wang
author_sort Yong Xu
collection DOAJ
description Abstract High-strength steels are widely used in marine engineering; however, they suffer from the risks of corrosion, hydrogen permeation, and stress corrosion cracking (SCC) in wet–dry cyclic marine environments. In this study, the corrosion, hydrogen permeation, and SCC behaviours of AISI 4135 steel in the tidal zone were investigated using electrochemical corrosion, electrochemical hydrogen permeation, and slow strain rate tests, respectively, via field exposure. The results showed that the AISI 4135 steel sample placed at the high tide level had high SCC susceptibility because of severe pitting corrosion and hydrogen permeation, whereas the steel samples placed at the middle and low tide levels had low SCC susceptibilities. The dry/wet time ratio was crucial in determining the SCC behaviour and mechanism of the steel in the tidal zone. With increasing time ratio, the SCC mechanism changed from micro-void coalescence control to localised anodic dissolution and hydrogen embrittlement in tandem.
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spelling doaj.art-eacc7da6829240b09f612e14fcc41a4e2022-12-22T04:40:06ZengNature Portfolionpj Materials Degradation2397-21062022-12-016111810.1038/s41529-022-00309-2Study on corrosion, hydrogen permeation, and stress corrosion cracking behaviours of AISI 4135 steel in the tidal zoneYong Xu0Yanliang Huang1Fanfan Cai2Dongzhu Lu3Zhengquan Wang4Xiutong Wang5CAS Key Laboratory of Marine Environmental Corrosion and Bio-fouling, Institute of Oceanology, Chinese Academy of SciencesCAS Key Laboratory of Marine Environmental Corrosion and Bio-fouling, Institute of Oceanology, Chinese Academy of SciencesCAS Key Laboratory of Marine Environmental Corrosion and Bio-fouling, Institute of Oceanology, Chinese Academy of SciencesCAS Key Laboratory of Marine Environmental Corrosion and Bio-fouling, Institute of Oceanology, Chinese Academy of SciencesCAS Key Laboratory of Marine Environmental Corrosion and Bio-fouling, Institute of Oceanology, Chinese Academy of SciencesCAS Key Laboratory of Marine Environmental Corrosion and Bio-fouling, Institute of Oceanology, Chinese Academy of SciencesAbstract High-strength steels are widely used in marine engineering; however, they suffer from the risks of corrosion, hydrogen permeation, and stress corrosion cracking (SCC) in wet–dry cyclic marine environments. In this study, the corrosion, hydrogen permeation, and SCC behaviours of AISI 4135 steel in the tidal zone were investigated using electrochemical corrosion, electrochemical hydrogen permeation, and slow strain rate tests, respectively, via field exposure. The results showed that the AISI 4135 steel sample placed at the high tide level had high SCC susceptibility because of severe pitting corrosion and hydrogen permeation, whereas the steel samples placed at the middle and low tide levels had low SCC susceptibilities. The dry/wet time ratio was crucial in determining the SCC behaviour and mechanism of the steel in the tidal zone. With increasing time ratio, the SCC mechanism changed from micro-void coalescence control to localised anodic dissolution and hydrogen embrittlement in tandem.https://doi.org/10.1038/s41529-022-00309-2
spellingShingle Yong Xu
Yanliang Huang
Fanfan Cai
Dongzhu Lu
Zhengquan Wang
Xiutong Wang
Study on corrosion, hydrogen permeation, and stress corrosion cracking behaviours of AISI 4135 steel in the tidal zone
npj Materials Degradation
title Study on corrosion, hydrogen permeation, and stress corrosion cracking behaviours of AISI 4135 steel in the tidal zone
title_full Study on corrosion, hydrogen permeation, and stress corrosion cracking behaviours of AISI 4135 steel in the tidal zone
title_fullStr Study on corrosion, hydrogen permeation, and stress corrosion cracking behaviours of AISI 4135 steel in the tidal zone
title_full_unstemmed Study on corrosion, hydrogen permeation, and stress corrosion cracking behaviours of AISI 4135 steel in the tidal zone
title_short Study on corrosion, hydrogen permeation, and stress corrosion cracking behaviours of AISI 4135 steel in the tidal zone
title_sort study on corrosion hydrogen permeation and stress corrosion cracking behaviours of aisi 4135 steel in the tidal zone
url https://doi.org/10.1038/s41529-022-00309-2
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