[μ-N,N,N′,N′-Tetrakis(2-pyridylmethyl)butane-1,4-diamine]bis[diacetatocadmium(II)] nonahydrate
The title dinuclear complex, [Cd2(CH3CO2)4(C28H32N6)]·9H2O, is located on a crystallographic inversion center. The unique CdII ion displays a 5 + 2 coordination. A distorted square-pyramidal geometry is formed by the dipicolylamine unit of the ligand via the N...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-10-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810034550 |
| _version_ | 1818286246119604224 |
|---|---|
| author | Jon Zubieta Hoi Cheung Mark Bartholomä |
| author_facet | Jon Zubieta Hoi Cheung Mark Bartholomä |
| author_sort | Jon Zubieta |
| collection | DOAJ |
| description | The title dinuclear complex, [Cd2(CH3CO2)4(C28H32N6)]·9H2O, is located on a crystallographic inversion center. The unique CdII ion displays a 5 + 2 coordination. A distorted square-pyramidal geometry is formed by the dipicolylamine unit of the ligand via the N atoms in a meridional fashion and two O atoms of the acetate ligands with short Cd—O distances. The coordination is completed by two loosely bound O atoms of the acetate ligands. The Cd—N distances involving the pyridine N atoms differ slightly from each other and the Cd—N distance involving the tertiary N atom is the longest. In the crystal structure, complex molecules and solvent water molecules are connected into a three-dimensional network via intermolecular O—H...O hydrogen bonds. One of the water molecules lies on a twofold rotation axis. |
| first_indexed | 2024-12-13T01:21:32Z |
| format | Article |
| id | doaj.art-eacd2e02b84a4ed3bd0f24f830346bdf |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T01:21:32Z |
| publishDate | 2010-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-eacd2e02b84a4ed3bd0f24f830346bdf2022-12-22T00:04:14ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-10-016610m1195m119610.1107/S1600536810034550[μ-N,N,N′,N′-Tetrakis(2-pyridylmethyl)butane-1,4-diamine]bis[diacetatocadmium(II)] nonahydrateJon ZubietaHoi CheungMark BartholomäThe title dinuclear complex, [Cd2(CH3CO2)4(C28H32N6)]·9H2O, is located on a crystallographic inversion center. The unique CdII ion displays a 5 + 2 coordination. A distorted square-pyramidal geometry is formed by the dipicolylamine unit of the ligand via the N atoms in a meridional fashion and two O atoms of the acetate ligands with short Cd—O distances. The coordination is completed by two loosely bound O atoms of the acetate ligands. The Cd—N distances involving the pyridine N atoms differ slightly from each other and the Cd—N distance involving the tertiary N atom is the longest. In the crystal structure, complex molecules and solvent water molecules are connected into a three-dimensional network via intermolecular O—H...O hydrogen bonds. One of the water molecules lies on a twofold rotation axis.http://scripts.iucr.org/cgi-bin/paper?S1600536810034550 |
| spellingShingle | Jon Zubieta Hoi Cheung Mark Bartholomä [μ-N,N,N′,N′-Tetrakis(2-pyridylmethyl)butane-1,4-diamine]bis[diacetatocadmium(II)] nonahydrate Acta Crystallographica Section E |
| title | [μ-N,N,N′,N′-Tetrakis(2-pyridylmethyl)butane-1,4-diamine]bis[diacetatocadmium(II)] nonahydrate |
| title_full | [μ-N,N,N′,N′-Tetrakis(2-pyridylmethyl)butane-1,4-diamine]bis[diacetatocadmium(II)] nonahydrate |
| title_fullStr | [μ-N,N,N′,N′-Tetrakis(2-pyridylmethyl)butane-1,4-diamine]bis[diacetatocadmium(II)] nonahydrate |
| title_full_unstemmed | [μ-N,N,N′,N′-Tetrakis(2-pyridylmethyl)butane-1,4-diamine]bis[diacetatocadmium(II)] nonahydrate |
| title_short | [μ-N,N,N′,N′-Tetrakis(2-pyridylmethyl)butane-1,4-diamine]bis[diacetatocadmium(II)] nonahydrate |
| title_sort | amp 956 n n n amp 8242 n amp 8242 tetrakis 2 pyridylmethyl butane 1 4 diamine bis diacetatocadmium ii nonahydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810034550 |
| work_keys_str_mv | AT jonzubieta amp956nnnamp8242namp8242tetrakis2pyridylmethylbutane14diaminebisdiacetatocadmiumiinonahydrate AT hoicheung amp956nnnamp8242namp8242tetrakis2pyridylmethylbutane14diaminebisdiacetatocadmiumiinonahydrate AT markbartholomamp228 amp956nnnamp8242namp8242tetrakis2pyridylmethylbutane14diaminebisdiacetatocadmiumiinonahydrate |