Investigation of Electrochemical Assisted Deposition of Sol-Gel Silica Films for Long-Lasting Superhydrophobicity
Current methods for the protection of metal surfaces utilize harsh chemical processes, such as organic paint or electro-plating, which are not environment-friendly and require extensive waste treatments. In this study, a two-step approach consisting of electrochemical assisted deposition (EAD) of an...
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2023-02-01
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author | Baoming Zhou Yongling Wu Hongyu Zheng |
author_facet | Baoming Zhou Yongling Wu Hongyu Zheng |
author_sort | Baoming Zhou |
collection | DOAJ |
description | Current methods for the protection of metal surfaces utilize harsh chemical processes, such as organic paint or electro-plating, which are not environment-friendly and require extensive waste treatments. In this study, a two-step approach consisting of electrochemical assisted deposition (EAD) of an aqueous silane solution and a dip coating of a low surface energy silane for obtaining a superhydrophobic self-cleaning surface for the enhanced protection of copper substrate is presented. A porous and hierarchical micro-nanostructured silica basecoat (sol-gel) was first formed by EAD of a methyltriethoxysilane (MTES) precursor solution on a copper substrate. Then, a superhydrophobic top-coat (E-MTES/PFOTS) was prepared with 1H,1H,2H,2H-Perfluorooctyltriethoxysilane (PFOTS) for low surface energy. The superhydrophobic coating exhibited anti-stain properties against milk, cola, and oil, with contact angles of 151°, 151.5°, and 129°, respectively. The EAD deposition potential and duration were effective in controlling the microscopic morphology, surface roughness, and coating thickness. The E-MTES/PFOTS coatings exhibited chemical stability against acids, bases, and abrasion resistance by sandpaper. The proposed 2-layer coating system exhibited strong chemical bonding at the two interfaces and provided a brush-like surface morphology with long-lasting superhydrophobicity. The developed method would provide an environment-friendly and expedient process for uniform protective coatings on complex surfaces. |
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issn | 1996-1944 |
language | English |
last_indexed | 2024-03-11T08:30:57Z |
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spelling | doaj.art-eaceb069ecb24db2a87c2c283d8c36372023-11-16T21:49:34ZengMDPI AGMaterials1996-19442023-02-01164141710.3390/ma16041417Investigation of Electrochemical Assisted Deposition of Sol-Gel Silica Films for Long-Lasting SuperhydrophobicityBaoming Zhou0Yongling Wu1Hongyu Zheng2Centre for Advanced Laser Manufacturing (CALM), School of Mechanical Engineering, Shandong University of Technology, Zibo 255000, ChinaCentre for Advanced Laser Manufacturing (CALM), School of Mechanical Engineering, Shandong University of Technology, Zibo 255000, ChinaCentre for Advanced Laser Manufacturing (CALM), School of Mechanical Engineering, Shandong University of Technology, Zibo 255000, ChinaCurrent methods for the protection of metal surfaces utilize harsh chemical processes, such as organic paint or electro-plating, which are not environment-friendly and require extensive waste treatments. In this study, a two-step approach consisting of electrochemical assisted deposition (EAD) of an aqueous silane solution and a dip coating of a low surface energy silane for obtaining a superhydrophobic self-cleaning surface for the enhanced protection of copper substrate is presented. A porous and hierarchical micro-nanostructured silica basecoat (sol-gel) was first formed by EAD of a methyltriethoxysilane (MTES) precursor solution on a copper substrate. Then, a superhydrophobic top-coat (E-MTES/PFOTS) was prepared with 1H,1H,2H,2H-Perfluorooctyltriethoxysilane (PFOTS) for low surface energy. The superhydrophobic coating exhibited anti-stain properties against milk, cola, and oil, with contact angles of 151°, 151.5°, and 129°, respectively. The EAD deposition potential and duration were effective in controlling the microscopic morphology, surface roughness, and coating thickness. The E-MTES/PFOTS coatings exhibited chemical stability against acids, bases, and abrasion resistance by sandpaper. The proposed 2-layer coating system exhibited strong chemical bonding at the two interfaces and provided a brush-like surface morphology with long-lasting superhydrophobicity. The developed method would provide an environment-friendly and expedient process for uniform protective coatings on complex surfaces.https://www.mdpi.com/1996-1944/16/4/1417sol-gelelectrochemical assisted depositionsuperhydrophobicityself-cleaningcontact angle |
spellingShingle | Baoming Zhou Yongling Wu Hongyu Zheng Investigation of Electrochemical Assisted Deposition of Sol-Gel Silica Films for Long-Lasting Superhydrophobicity Materials sol-gel electrochemical assisted deposition superhydrophobicity self-cleaning contact angle |
title | Investigation of Electrochemical Assisted Deposition of Sol-Gel Silica Films for Long-Lasting Superhydrophobicity |
title_full | Investigation of Electrochemical Assisted Deposition of Sol-Gel Silica Films for Long-Lasting Superhydrophobicity |
title_fullStr | Investigation of Electrochemical Assisted Deposition of Sol-Gel Silica Films for Long-Lasting Superhydrophobicity |
title_full_unstemmed | Investigation of Electrochemical Assisted Deposition of Sol-Gel Silica Films for Long-Lasting Superhydrophobicity |
title_short | Investigation of Electrochemical Assisted Deposition of Sol-Gel Silica Films for Long-Lasting Superhydrophobicity |
title_sort | investigation of electrochemical assisted deposition of sol gel silica films for long lasting superhydrophobicity |
topic | sol-gel electrochemical assisted deposition superhydrophobicity self-cleaning contact angle |
url | https://www.mdpi.com/1996-1944/16/4/1417 |
work_keys_str_mv | AT baomingzhou investigationofelectrochemicalassisteddepositionofsolgelsilicafilmsforlonglastingsuperhydrophobicity AT yonglingwu investigationofelectrochemicalassisteddepositionofsolgelsilicafilmsforlonglastingsuperhydrophobicity AT hongyuzheng investigationofelectrochemicalassisteddepositionofsolgelsilicafilmsforlonglastingsuperhydrophobicity |