1,4-Bis(4-methoxyphenyl)naphthalene
The title naphthalene derivative, C24H20O2, features 4-methyoxy-substituted benzene rings in the 1 and 4 positions of the naphthalene ring system. There are two crystallographically independent molecules (A and B) in asymmetric unit. The independent molecules have very similar conformations in which...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2020-02-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314620002126 |
| _version_ | 1818280359807156224 |
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| author | R. Manickam G. Jagadeesan J. Karunakaran G. Srinivasan |
| author_facet | R. Manickam G. Jagadeesan J. Karunakaran G. Srinivasan |
| author_sort | R. Manickam |
| collection | DOAJ |
| description | The title naphthalene derivative, C24H20O2, features 4-methyoxy-substituted benzene rings in the 1 and 4 positions of the naphthalene ring system. There are two crystallographically independent molecules (A and B) in asymmetric unit. The independent molecules have very similar conformations in which the naphthalene ring systems are only slightly bent, exhibiting dihedral angles between the constituent benzene rings of 3.76 (15) and 3.39 (15)° for A and B, respectively. The pendent 4-methyoxybenzene rings are splayed out of the plane through the naphthalene ring system to which they are connected [range of dihedral angles = 59.63 (13) to 67.09 (13)°]. In the crystal, the molecular packing is consolidated by intermolecular C—H...π interactions, leading to supramolecular chains along the b axis. The chains assemble without directional interactions between them. |
| first_indexed | 2024-12-12T23:47:59Z |
| format | Article |
| id | doaj.art-eaf73711fce1496d9a58cd3082e16ded |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-12T23:47:59Z |
| publishDate | 2020-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-eaf73711fce1496d9a58cd3082e16ded2022-12-22T00:06:48ZengInternational Union of CrystallographyIUCrData2414-31462020-02-0152x20021210.1107/S2414314620002126tk40611,4-Bis(4-methoxyphenyl)naphthaleneR. Manickam0G. Jagadeesan1J. Karunakaran2G. Srinivasan3PG and Research Department of Physics, Government Arts College for Men (Autonomous), Nandanam, Chennai - 600 035, IndiaDepartment of Physics, Jeppiar Engineering College, Jeppiar Nagar, OMR, Chennai - 600 119, IndiaDepartment of Organic Chemistry, University of Madras, Guindy Campus, Chennai - 600 025, IndiaPG and Research Department of Physics, Government Arts College for Men (Autonomous), Nandanam, Chennai - 600 035, IndiaThe title naphthalene derivative, C24H20O2, features 4-methyoxy-substituted benzene rings in the 1 and 4 positions of the naphthalene ring system. There are two crystallographically independent molecules (A and B) in asymmetric unit. The independent molecules have very similar conformations in which the naphthalene ring systems are only slightly bent, exhibiting dihedral angles between the constituent benzene rings of 3.76 (15) and 3.39 (15)° for A and B, respectively. The pendent 4-methyoxybenzene rings are splayed out of the plane through the naphthalene ring system to which they are connected [range of dihedral angles = 59.63 (13) to 67.09 (13)°]. In the crystal, the molecular packing is consolidated by intermolecular C—H...π interactions, leading to supramolecular chains along the b axis. The chains assemble without directional interactions between them.http://scripts.iucr.org/cgi-bin/paper?S2414314620002126crystal structurenaphthalene derivativec—h...π interactions |
| spellingShingle | R. Manickam G. Jagadeesan J. Karunakaran G. Srinivasan 1,4-Bis(4-methoxyphenyl)naphthalene IUCrData crystal structure naphthalene derivative c—h...π interactions |
| title | 1,4-Bis(4-methoxyphenyl)naphthalene |
| title_full | 1,4-Bis(4-methoxyphenyl)naphthalene |
| title_fullStr | 1,4-Bis(4-methoxyphenyl)naphthalene |
| title_full_unstemmed | 1,4-Bis(4-methoxyphenyl)naphthalene |
| title_short | 1,4-Bis(4-methoxyphenyl)naphthalene |
| title_sort | 1 4 bis 4 methoxyphenyl naphthalene |
| topic | crystal structure naphthalene derivative c—h...π interactions |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314620002126 |
| work_keys_str_mv | AT rmanickam 14bis4methoxyphenylnaphthalene AT gjagadeesan 14bis4methoxyphenylnaphthalene AT jkarunakaran 14bis4methoxyphenylnaphthalene AT gsrinivasan 14bis4methoxyphenylnaphthalene |