Synthesis, crystal structure and antimicrobial activity of a hetero trinuclear manganese(III)-iron(II) complex derived from N,N’-bis(5-methylsalicylidene)-1,2-diaminoethane
A new hetero trinuclear manganese(III)-iron(II) complex, [Mn(salen)(H2O)]2[Fe(CN)6], in which salen is the dianionic form of N,N’-bis(5-methylsalicylidene)-1,2-diaminoethane, has been prepared and characterized by elemental analyses, IR, and single crystal X-ray crystallographic determination. The c...
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| Format: | Article |
| Language: | English |
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Chemical Society of Ethiopia
2015-10-01
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| Series: | Bulletin of the Chemical Society of Ethiopia |
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| Online Access: | http://www.ajol.info/index.php/bcse/article/view/122951 |
| _version_ | 1818152414395498496 |
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| author | X-M Hu L-W Xue G-Q Zhao W-C Yang |
| author_facet | X-M Hu L-W Xue G-Q Zhao W-C Yang |
| author_sort | X-M Hu |
| collection | DOAJ |
| description | A new hetero trinuclear manganese(III)-iron(II) complex, [Mn(salen)(H2O)]2[Fe(CN)6], in which salen is the dianionic form of N,N’-bis(5-methylsalicylidene)-1,2-diaminoethane, has been prepared and characterized by elemental analyses, IR, and single crystal X-ray crystallographic determination. The crystal of the complex is monoclinic: space group P21/c, a = 10.768(2), b = 14.248(3), c = 15.222(3) Å, β = 95.394(2)º, V = 2325.0(8) Å3, Z = 2, R1 = 0.0754, wR2 = 0.2366. The bis-Schiff base ligand coordinates to the Mn atom through phenolate O and imine N atoms. Each Mn atom in the complex is in octahedral coordination, with the equatorial donor atoms come from the Schiff base ligand, and with the axial donor atoms come from a water O atom and a cyanide N atom. The effects of the complex on the antimicrobial activity against Staphylococcus aureus, Escherichia coli, and Candida albicans were studied. DOI: http://dx.doi.org/10.4314/bcse.v29i3.8 |
| first_indexed | 2024-12-11T13:54:20Z |
| format | Article |
| id | doaj.art-eb382329a446403690c68e7747acbdc8 |
| institution | Directory Open Access Journal |
| issn | 1011-3924 1726-801X |
| language | English |
| last_indexed | 2024-12-11T13:54:20Z |
| publishDate | 2015-10-01 |
| publisher | Chemical Society of Ethiopia |
| record_format | Article |
| series | Bulletin of the Chemical Society of Ethiopia |
| spelling | doaj.art-eb382329a446403690c68e7747acbdc82022-12-22T01:04:07ZengChemical Society of EthiopiaBulletin of the Chemical Society of Ethiopia1011-39241726-801X2015-10-01293407413http://dx.doi.org/10.4314/bcse.v29i3.8Synthesis, crystal structure and antimicrobial activity of a hetero trinuclear manganese(III)-iron(II) complex derived from N,N’-bis(5-methylsalicylidene)-1,2-diaminoethaneX-M HuL-W XueG-Q ZhaoW-C YangA new hetero trinuclear manganese(III)-iron(II) complex, [Mn(salen)(H2O)]2[Fe(CN)6], in which salen is the dianionic form of N,N’-bis(5-methylsalicylidene)-1,2-diaminoethane, has been prepared and characterized by elemental analyses, IR, and single crystal X-ray crystallographic determination. The crystal of the complex is monoclinic: space group P21/c, a = 10.768(2), b = 14.248(3), c = 15.222(3) Å, β = 95.394(2)º, V = 2325.0(8) Å3, Z = 2, R1 = 0.0754, wR2 = 0.2366. The bis-Schiff base ligand coordinates to the Mn atom through phenolate O and imine N atoms. Each Mn atom in the complex is in octahedral coordination, with the equatorial donor atoms come from the Schiff base ligand, and with the axial donor atoms come from a water O atom and a cyanide N atom. The effects of the complex on the antimicrobial activity against Staphylococcus aureus, Escherichia coli, and Candida albicans were studied. DOI: http://dx.doi.org/10.4314/bcse.v29i3.8http://www.ajol.info/index.php/bcse/article/view/122951Schiff baseManganese(III) complexIron(II) complexHeteronuclearCrystal structure |
| spellingShingle | X-M Hu L-W Xue G-Q Zhao W-C Yang Synthesis, crystal structure and antimicrobial activity of a hetero trinuclear manganese(III)-iron(II) complex derived from N,N’-bis(5-methylsalicylidene)-1,2-diaminoethane Bulletin of the Chemical Society of Ethiopia Schiff base Manganese(III) complex Iron(II) complex Heteronuclear Crystal structure |
| title | Synthesis, crystal structure and antimicrobial activity of a hetero trinuclear manganese(III)-iron(II) complex derived from N,N’-bis(5-methylsalicylidene)-1,2-diaminoethane |
| title_full | Synthesis, crystal structure and antimicrobial activity of a hetero trinuclear manganese(III)-iron(II) complex derived from N,N’-bis(5-methylsalicylidene)-1,2-diaminoethane |
| title_fullStr | Synthesis, crystal structure and antimicrobial activity of a hetero trinuclear manganese(III)-iron(II) complex derived from N,N’-bis(5-methylsalicylidene)-1,2-diaminoethane |
| title_full_unstemmed | Synthesis, crystal structure and antimicrobial activity of a hetero trinuclear manganese(III)-iron(II) complex derived from N,N’-bis(5-methylsalicylidene)-1,2-diaminoethane |
| title_short | Synthesis, crystal structure and antimicrobial activity of a hetero trinuclear manganese(III)-iron(II) complex derived from N,N’-bis(5-methylsalicylidene)-1,2-diaminoethane |
| title_sort | synthesis crystal structure and antimicrobial activity of a hetero trinuclear manganese iii iron ii complex derived from n n bis 5 methylsalicylidene 1 2 diaminoethane |
| topic | Schiff base Manganese(III) complex Iron(II) complex Heteronuclear Crystal structure |
| url | http://www.ajol.info/index.php/bcse/article/view/122951 |
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