The Aluminum-Ion Battery: A Sustainable and Seminal Concept?

The expansion of renewable energy and the growing number of electric vehicles and mobile devices are demanding improved and low-cost electrochemical energy storage. In order to meet the future needs for energy storage, novel material systems with high energy densities, readily available raw material...

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Main Authors: Tilmann Leisegang, Falk Meutzner, Matthias Zschornak, Wolfram Münchgesang, Robert Schmid, Tina Nestler, Roman A. Eremin, Artem A. Kabanov, Vladislav A. Blatov, Dirk C. Meyer
Format: Article
Language:English
Published: Frontiers Media S.A. 2019-05-01
Series:Frontiers in Chemistry
Subjects:
Online Access:https://www.frontiersin.org/article/10.3389/fchem.2019.00268/full
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author Tilmann Leisegang
Tilmann Leisegang
Falk Meutzner
Falk Meutzner
Matthias Zschornak
Matthias Zschornak
Wolfram Münchgesang
Robert Schmid
Tina Nestler
Roman A. Eremin
Roman A. Eremin
Artem A. Kabanov
Artem A. Kabanov
Vladislav A. Blatov
Vladislav A. Blatov
Dirk C. Meyer
author_facet Tilmann Leisegang
Tilmann Leisegang
Falk Meutzner
Falk Meutzner
Matthias Zschornak
Matthias Zschornak
Wolfram Münchgesang
Robert Schmid
Tina Nestler
Roman A. Eremin
Roman A. Eremin
Artem A. Kabanov
Artem A. Kabanov
Vladislav A. Blatov
Vladislav A. Blatov
Dirk C. Meyer
author_sort Tilmann Leisegang
collection DOAJ
description The expansion of renewable energy and the growing number of electric vehicles and mobile devices are demanding improved and low-cost electrochemical energy storage. In order to meet the future needs for energy storage, novel material systems with high energy densities, readily available raw materials, and safety are required. Currently, lithium and lead mainly dominate the battery market, but apart from cobalt and phosphorous, lithium may show substantial supply challenges prospectively, as well. Therefore, the search for new chemistries will become increasingly important in the future, to diversify battery technologies. But which materials seem promising? Using a selection algorithm for the evaluation of suitable materials, the concept of a rechargeable, high-valent all-solid-state aluminum-ion battery appears promising, in which metallic aluminum is used as the negative electrode. On the one hand, this offers the advantage of a volumetric capacity four times higher (theoretically) compared to lithium analog. On the other hand, aluminum is the most abundant metal in the earth's crust. There is a mature industry and recycling infrastructure, making aluminum very cost efficient. This would make the aluminum-ion battery an important contribution to the energy transition process, which has already started globally. So far, it has not been possible to exploit this technological potential, as suitable positive electrodes and electrolyte materials are still lacking. The discovery of inorganic materials with high aluminum-ion mobility—usable as solid electrolytes or intercalation electrodes—is an innovative and required leap forward in the field of rechargeable high-valent ion batteries. In this review article, the constraints for a sustainable and seminal battery chemistry are described, and we present an assessment of the chemical elements in terms of negative electrodes, comprehensively motivate utilizing aluminum, categorize the aluminum battery field, critically review the existing positive electrodes and solid electrolytes, present a promising path for the accelerated development of novel materials and address problems of scientific communication in this field.
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spelling doaj.art-eb40aa7c5579414ba4393df763c48c092022-12-21T17:31:50ZengFrontiers Media S.A.Frontiers in Chemistry2296-26462019-05-01710.3389/fchem.2019.00268441201The Aluminum-Ion Battery: A Sustainable and Seminal Concept?Tilmann Leisegang0Tilmann Leisegang1Falk Meutzner2Falk Meutzner3Matthias Zschornak4Matthias Zschornak5Wolfram Münchgesang6Robert Schmid7Tina Nestler8Roman A. Eremin9Roman A. Eremin10Artem A. Kabanov11Artem A. Kabanov12Vladislav A. Blatov13Vladislav A. Blatov14Dirk C. Meyer15Institute of Experimental Physics, TU Bergakademie Freiberg, Freiberg, GermanySamara Center for Theoretical Materials Science, Samara State Technical University, Samara, RussiaInstitute of Experimental Physics, TU Bergakademie Freiberg, Freiberg, GermanySamara Center for Theoretical Materials Science, Samara State Technical University, Samara, RussiaInstitute of Experimental Physics, TU Bergakademie Freiberg, Freiberg, GermanyHelmholtz-Zentrum Dresden Rossendorf, Institute of Ion Beam Physics and Materials Research, Dresden, GermanyInstitute of Experimental Physics, TU Bergakademie Freiberg, Freiberg, GermanyInstitute of Experimental Physics, TU Bergakademie Freiberg, Freiberg, GermanyInstitute of Experimental Physics, TU Bergakademie Freiberg, Freiberg, GermanySamara Center for Theoretical Materials Science, Samara State Technical University, Samara, RussiaSamara Center for Theoretical Materials Science, Samara University, Samara, RussiaSamara Center for Theoretical Materials Science, Samara State Technical University, Samara, RussiaSamara Center for Theoretical Materials Science, Samara University, Samara, RussiaSamara Center for Theoretical Materials Science, Samara State Technical University, Samara, RussiaSamara Center for Theoretical Materials Science, Samara University, Samara, RussiaInstitute of Experimental Physics, TU Bergakademie Freiberg, Freiberg, GermanyThe expansion of renewable energy and the growing number of electric vehicles and mobile devices are demanding improved and low-cost electrochemical energy storage. In order to meet the future needs for energy storage, novel material systems with high energy densities, readily available raw materials, and safety are required. Currently, lithium and lead mainly dominate the battery market, but apart from cobalt and phosphorous, lithium may show substantial supply challenges prospectively, as well. Therefore, the search for new chemistries will become increasingly important in the future, to diversify battery technologies. But which materials seem promising? Using a selection algorithm for the evaluation of suitable materials, the concept of a rechargeable, high-valent all-solid-state aluminum-ion battery appears promising, in which metallic aluminum is used as the negative electrode. On the one hand, this offers the advantage of a volumetric capacity four times higher (theoretically) compared to lithium analog. On the other hand, aluminum is the most abundant metal in the earth's crust. There is a mature industry and recycling infrastructure, making aluminum very cost efficient. This would make the aluminum-ion battery an important contribution to the energy transition process, which has already started globally. So far, it has not been possible to exploit this technological potential, as suitable positive electrodes and electrolyte materials are still lacking. The discovery of inorganic materials with high aluminum-ion mobility—usable as solid electrolytes or intercalation electrodes—is an innovative and required leap forward in the field of rechargeable high-valent ion batteries. In this review article, the constraints for a sustainable and seminal battery chemistry are described, and we present an assessment of the chemical elements in terms of negative electrodes, comprehensively motivate utilizing aluminum, categorize the aluminum battery field, critically review the existing positive electrodes and solid electrolytes, present a promising path for the accelerated development of novel materials and address problems of scientific communication in this field.https://www.frontiersin.org/article/10.3389/fchem.2019.00268/fullaluminum-ion batterycathodepost-lithiumelectrolyteresources
spellingShingle Tilmann Leisegang
Tilmann Leisegang
Falk Meutzner
Falk Meutzner
Matthias Zschornak
Matthias Zschornak
Wolfram Münchgesang
Robert Schmid
Tina Nestler
Roman A. Eremin
Roman A. Eremin
Artem A. Kabanov
Artem A. Kabanov
Vladislav A. Blatov
Vladislav A. Blatov
Dirk C. Meyer
The Aluminum-Ion Battery: A Sustainable and Seminal Concept?
Frontiers in Chemistry
aluminum-ion battery
cathode
post-lithium
electrolyte
resources
title The Aluminum-Ion Battery: A Sustainable and Seminal Concept?
title_full The Aluminum-Ion Battery: A Sustainable and Seminal Concept?
title_fullStr The Aluminum-Ion Battery: A Sustainable and Seminal Concept?
title_full_unstemmed The Aluminum-Ion Battery: A Sustainable and Seminal Concept?
title_short The Aluminum-Ion Battery: A Sustainable and Seminal Concept?
title_sort aluminum ion battery a sustainable and seminal concept
topic aluminum-ion battery
cathode
post-lithium
electrolyte
resources
url https://www.frontiersin.org/article/10.3389/fchem.2019.00268/full
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