Galvanic Replacement of Electrochemically Restructured Copper Electrodes with Gold and Its Electrocatalytic Activity for Nitrate Ion Reduction
The electrochemical formation of nanostructured materials is a cost effective route to creating substrates that can be employed in a variety of applications. In this work the surface of a copper electrode was electrochemically restructured in an alkaline solution containing ethanol as an additive to...
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| Format: | Article |
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MDPI AG
2018-09-01
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| Series: | Nanomaterials |
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| Online Access: | http://www.mdpi.com/2079-4991/8/10/756 |
| _version_ | 1819263009230422016 |
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| author | Ali Balkis Jessica Crawford Anthony P. O’Mullane |
| author_facet | Ali Balkis Jessica Crawford Anthony P. O’Mullane |
| author_sort | Ali Balkis |
| collection | DOAJ |
| description | The electrochemical formation of nanostructured materials is a cost effective route to creating substrates that can be employed in a variety of applications. In this work the surface of a copper electrode was electrochemically restructured in an alkaline solution containing ethanol as an additive to modify the surface morphology, and generate a Cu/Cu2O surface, which is known to be active for the electrocatalytic reduction of environmentally harmful nitrate ions. To increase the activity of the nanostructured surface it was decorated with gold prisms through a facile galvanic replacement approach to create an active Cu/Cu2O/Au layer. The surface was characterized by scanning electron microscopy, energy dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, as well as electrochemical techniques. It was found that the presence of recalcitrant oxides, and Au was beneficial for the increased activity compared to unmodified copper and undecorated restructured copper and was consistent with the incipient hydrous oxide adatom mediator model of electrocatalysis. This approach to generating nanostructured metal/metal oxide surfaces that can be galvanically replaced to create these types of composites may have other applications in the area of electrocatalysis. |
| first_indexed | 2024-12-23T20:06:46Z |
| format | Article |
| id | doaj.art-eb7a2301afe94e648eccf8fae7fffb4b |
| institution | Directory Open Access Journal |
| issn | 2079-4991 |
| language | English |
| last_indexed | 2024-12-23T20:06:46Z |
| publishDate | 2018-09-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Nanomaterials |
| spelling | doaj.art-eb7a2301afe94e648eccf8fae7fffb4b2022-12-21T17:32:56ZengMDPI AGNanomaterials2079-49912018-09-0181075610.3390/nano8100756nano8100756Galvanic Replacement of Electrochemically Restructured Copper Electrodes with Gold and Its Electrocatalytic Activity for Nitrate Ion ReductionAli Balkis0Jessica Crawford1Anthony P. O’Mullane2School of Science, RMIT University, Melbourne, VIC 3001, AustraliaSchool of Chemistry, Physics and Mechanical Engineering, Queensland University of Technology (QUT), Brisbane, QLD 4001, AustraliaSchool of Chemistry, Physics and Mechanical Engineering, Queensland University of Technology (QUT), Brisbane, QLD 4001, AustraliaThe electrochemical formation of nanostructured materials is a cost effective route to creating substrates that can be employed in a variety of applications. In this work the surface of a copper electrode was electrochemically restructured in an alkaline solution containing ethanol as an additive to modify the surface morphology, and generate a Cu/Cu2O surface, which is known to be active for the electrocatalytic reduction of environmentally harmful nitrate ions. To increase the activity of the nanostructured surface it was decorated with gold prisms through a facile galvanic replacement approach to create an active Cu/Cu2O/Au layer. The surface was characterized by scanning electron microscopy, energy dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, as well as electrochemical techniques. It was found that the presence of recalcitrant oxides, and Au was beneficial for the increased activity compared to unmodified copper and undecorated restructured copper and was consistent with the incipient hydrous oxide adatom mediator model of electrocatalysis. This approach to generating nanostructured metal/metal oxide surfaces that can be galvanically replaced to create these types of composites may have other applications in the area of electrocatalysis.http://www.mdpi.com/2079-4991/8/10/756galvanic replacementelectrocatalysisnitrate reductionnanostructuresactive siteshydrous oxides |
| spellingShingle | Ali Balkis Jessica Crawford Anthony P. O’Mullane Galvanic Replacement of Electrochemically Restructured Copper Electrodes with Gold and Its Electrocatalytic Activity for Nitrate Ion Reduction Nanomaterials galvanic replacement electrocatalysis nitrate reduction nanostructures active sites hydrous oxides |
| title | Galvanic Replacement of Electrochemically Restructured Copper Electrodes with Gold and Its Electrocatalytic Activity for Nitrate Ion Reduction |
| title_full | Galvanic Replacement of Electrochemically Restructured Copper Electrodes with Gold and Its Electrocatalytic Activity for Nitrate Ion Reduction |
| title_fullStr | Galvanic Replacement of Electrochemically Restructured Copper Electrodes with Gold and Its Electrocatalytic Activity for Nitrate Ion Reduction |
| title_full_unstemmed | Galvanic Replacement of Electrochemically Restructured Copper Electrodes with Gold and Its Electrocatalytic Activity for Nitrate Ion Reduction |
| title_short | Galvanic Replacement of Electrochemically Restructured Copper Electrodes with Gold and Its Electrocatalytic Activity for Nitrate Ion Reduction |
| title_sort | galvanic replacement of electrochemically restructured copper electrodes with gold and its electrocatalytic activity for nitrate ion reduction |
| topic | galvanic replacement electrocatalysis nitrate reduction nanostructures active sites hydrous oxides |
| url | http://www.mdpi.com/2079-4991/8/10/756 |
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