RADICAL MECHANISM OF FORMATION OF Cu-Re AND Pb-Re COMPOSITES IN GASEOUS PHASE BY THERMAL DECOMPOSITION OF TRANS-TETRACHLORODI-μ-PROPIONATO DIRHENIUM(III)
Reactions of individual trans-tetrachloro-di-μ-propionato dirhenium(III) thermal decomposition in dynamic inert atmosphere were investigated. Using a radical reaction of transportation in gaseous phase, Cu-Re and Pb-Re composites were obtained on a ceramic surface. Free radicals C2H5• were detected...
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| Format: | Article |
| Language: | English |
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Odessa I. I. Mechnikov National University
2018-02-01
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| Series: | Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ |
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| Online Access: | http://heraldchem.onu.edu.ua/article/view/124552 |
| _version_ | 1811281872475389952 |
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| author | M. S. Iziumskyi A. V. Shtemenko |
| author_facet | M. S. Iziumskyi A. V. Shtemenko |
| author_sort | M. S. Iziumskyi |
| collection | DOAJ |
| description | Reactions of individual trans-tetrachloro-di-μ-propionato dirhenium(III) thermal decomposition in dynamic inert atmosphere were investigated. Using a radical reaction of transportation in gaseous phase, Cu-Re and Pb-Re composites were obtained on a ceramic surface. Free radicals C2H5• were detected by reaction with metal Cu and Pb mirrors. Cu-Re and Pb-Re composites were studied by XRD, micro-X-ray spectral and SEM analysis. Cu-Re composites contain nanodendrites of Cu which «grow» from a Re base and most likely have a nanotube structure. Dimensions of the nanotubes can vary from 100 nm to 1 μm. |
| first_indexed | 2024-04-13T01:41:26Z |
| format | Article |
| id | doaj.art-eb83257690214878a3ff57cc974bfd34 |
| institution | Directory Open Access Journal |
| issn | 2304-0947 2414-5963 |
| language | English |
| last_indexed | 2024-04-13T01:41:26Z |
| publishDate | 2018-02-01 |
| publisher | Odessa I. I. Mechnikov National University |
| record_format | Article |
| series | Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ |
| spelling | doaj.art-eb83257690214878a3ff57cc974bfd342022-12-22T03:08:11ZengOdessa I. I. Mechnikov National UniversityVìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ2304-09472414-59632018-02-01231(65)12313210.18524/2304-0947.2018.1(65).124552124552RADICAL MECHANISM OF FORMATION OF Cu-Re AND Pb-Re COMPOSITES IN GASEOUS PHASE BY THERMAL DECOMPOSITION OF TRANS-TETRACHLORODI-μ-PROPIONATO DIRHENIUM(III)M. S. Iziumskyi0A. V. Shtemenko1ДВУЗ «Український державний хіміко-технологічний університет», кафедра неорганічної хіміїДВУЗ «Український державний хіміко-технологічний університет», кафедра неорганічної хіміїReactions of individual trans-tetrachloro-di-μ-propionato dirhenium(III) thermal decomposition in dynamic inert atmosphere were investigated. Using a radical reaction of transportation in gaseous phase, Cu-Re and Pb-Re composites were obtained on a ceramic surface. Free radicals C2H5• were detected by reaction with metal Cu and Pb mirrors. Cu-Re and Pb-Re composites were studied by XRD, micro-X-ray spectral and SEM analysis. Cu-Re composites contain nanodendrites of Cu which «grow» from a Re base and most likely have a nanotube structure. Dimensions of the nanotubes can vary from 100 nm to 1 μm.http://heraldchem.onu.edu.ua/article/view/124552ренійвільний радикалкарбоксилаткомпозитмеханізмрозклад |
| spellingShingle | M. S. Iziumskyi A. V. Shtemenko RADICAL MECHANISM OF FORMATION OF Cu-Re AND Pb-Re COMPOSITES IN GASEOUS PHASE BY THERMAL DECOMPOSITION OF TRANS-TETRACHLORODI-μ-PROPIONATO DIRHENIUM(III) Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ реній вільний радикал карбоксилат композит механізм розклад |
| title | RADICAL MECHANISM OF FORMATION OF Cu-Re AND Pb-Re COMPOSITES IN GASEOUS PHASE BY THERMAL DECOMPOSITION OF TRANS-TETRACHLORODI-μ-PROPIONATO DIRHENIUM(III) |
| title_full | RADICAL MECHANISM OF FORMATION OF Cu-Re AND Pb-Re COMPOSITES IN GASEOUS PHASE BY THERMAL DECOMPOSITION OF TRANS-TETRACHLORODI-μ-PROPIONATO DIRHENIUM(III) |
| title_fullStr | RADICAL MECHANISM OF FORMATION OF Cu-Re AND Pb-Re COMPOSITES IN GASEOUS PHASE BY THERMAL DECOMPOSITION OF TRANS-TETRACHLORODI-μ-PROPIONATO DIRHENIUM(III) |
| title_full_unstemmed | RADICAL MECHANISM OF FORMATION OF Cu-Re AND Pb-Re COMPOSITES IN GASEOUS PHASE BY THERMAL DECOMPOSITION OF TRANS-TETRACHLORODI-μ-PROPIONATO DIRHENIUM(III) |
| title_short | RADICAL MECHANISM OF FORMATION OF Cu-Re AND Pb-Re COMPOSITES IN GASEOUS PHASE BY THERMAL DECOMPOSITION OF TRANS-TETRACHLORODI-μ-PROPIONATO DIRHENIUM(III) |
| title_sort | radical mechanism of formation of cu re and pb re composites in gaseous phase by thermal decomposition of trans tetrachlorodi μ propionato dirhenium iii |
| topic | реній вільний радикал карбоксилат композит механізм розклад |
| url | http://heraldchem.onu.edu.ua/article/view/124552 |
| work_keys_str_mv | AT msiziumskyi radicalmechanismofformationofcureandpbrecompositesingaseousphasebythermaldecompositionoftranstetrachlorodimpropionatodirheniumiii AT avshtemenko radicalmechanismofformationofcureandpbrecompositesingaseousphasebythermaldecompositionoftranstetrachlorodimpropionatodirheniumiii |