Comportamiento acústico y volumétrico de las mezclas binarias de valeronitrilo + propanoato de propilo y valeronitrilo + propanoato de butilo entre 278,15 y 318,15K
Densities and speeds of sound of the binary mixtures valeronitrile/propyl propanoate and valeronitrile/butyl propanoate were determined at atmospheric pressure and at a temperature range which goes from 278.15 to 318.15K every 5K. With the experimental data, we calculated the following physicochemic...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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Universidad de Los Andes
2013-05-01
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| Series: | Avances en Química |
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| Online Access: | http://www.saber.ula.ve/bitstream/123456789/37138/1/articulo3.pdf |
| _version_ | 1818855890300698624 |
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| author | Alejandra Mariano Lelia Mussari Alberto Camacho Salvador Canzonieri |
| author_facet | Alejandra Mariano Lelia Mussari Alberto Camacho Salvador Canzonieri |
| author_sort | Alejandra Mariano |
| collection | DOAJ |
| description | Densities and speeds of sound of the binary mixtures valeronitrile/propyl propanoate and valeronitrile/butyl propanoate were determined at atmospheric pressure and at a temperature range which goes from 278.15 to 318.15K every 5K. With the experimental data, we calculated the following physicochemical properties: VE,, E, u, S y SE; these results were fitted with the polynomial equation of Redlich-Kister. The studied binary mixtures showed negative values of VE, E, u y SE in the whole range of composition and at all temperatures. The prediction of the speed of sound was performed with the models proposed by Nomoto, Ernst and Van Dael. |
| first_indexed | 2024-12-19T08:15:47Z |
| format | Article |
| id | doaj.art-ebb8c27ee719492096bb2351cfdc33cc |
| institution | Directory Open Access Journal |
| issn | 1856-5301 |
| language | English |
| last_indexed | 2024-12-19T08:15:47Z |
| publishDate | 2013-05-01 |
| publisher | Universidad de Los Andes |
| record_format | Article |
| series | Avances en Química |
| spelling | doaj.art-ebb8c27ee719492096bb2351cfdc33cc2022-12-21T20:29:30ZengUniversidad de Los AndesAvances en Química1856-53012013-05-01811727Comportamiento acústico y volumétrico de las mezclas binarias de valeronitrilo + propanoato de propilo y valeronitrilo + propanoato de butilo entre 278,15 y 318,15KAlejandra Mariano0Lelia Mussari1Alberto Camacho2Salvador Canzonieri3Universidad Nacional del Comahue. Departamento de Química–Argentina y Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET)-ArgentinaUniversidad Nacional del Comahue. Departamento de Química – ArgentinaUniversidad Nacional del Comahue. Departamento de Física - Argentina.Universidad Nacional del Comahue. Departamento de Química – ArgentinaDensities and speeds of sound of the binary mixtures valeronitrile/propyl propanoate and valeronitrile/butyl propanoate were determined at atmospheric pressure and at a temperature range which goes from 278.15 to 318.15K every 5K. With the experimental data, we calculated the following physicochemical properties: VE,, E, u, S y SE; these results were fitted with the polynomial equation of Redlich-Kister. The studied binary mixtures showed negative values of VE, E, u y SE in the whole range of composition and at all temperatures. The prediction of the speed of sound was performed with the models proposed by Nomoto, Ernst and Van Dael.http://www.saber.ula.ve/bitstream/123456789/37138/1/articulo3.pdfExcess molar volumeSpeed of sound deviationIsobaric thermal expansion coefficientExcess isentropic compressibilityModels for the speed of sound |
| spellingShingle | Alejandra Mariano Lelia Mussari Alberto Camacho Salvador Canzonieri Comportamiento acústico y volumétrico de las mezclas binarias de valeronitrilo + propanoato de propilo y valeronitrilo + propanoato de butilo entre 278,15 y 318,15K Avances en Química Excess molar volume Speed of sound deviation Isobaric thermal expansion coefficient Excess isentropic compressibility Models for the speed of sound |
| title | Comportamiento acústico y volumétrico de las mezclas binarias de valeronitrilo + propanoato de propilo y valeronitrilo + propanoato de butilo entre 278,15 y 318,15K |
| title_full | Comportamiento acústico y volumétrico de las mezclas binarias de valeronitrilo + propanoato de propilo y valeronitrilo + propanoato de butilo entre 278,15 y 318,15K |
| title_fullStr | Comportamiento acústico y volumétrico de las mezclas binarias de valeronitrilo + propanoato de propilo y valeronitrilo + propanoato de butilo entre 278,15 y 318,15K |
| title_full_unstemmed | Comportamiento acústico y volumétrico de las mezclas binarias de valeronitrilo + propanoato de propilo y valeronitrilo + propanoato de butilo entre 278,15 y 318,15K |
| title_short | Comportamiento acústico y volumétrico de las mezclas binarias de valeronitrilo + propanoato de propilo y valeronitrilo + propanoato de butilo entre 278,15 y 318,15K |
| title_sort | comportamiento acustico y volumetrico de las mezclas binarias de valeronitrilo propanoato de propilo y valeronitrilo propanoato de butilo entre 278 15 y 318 15k |
| topic | Excess molar volume Speed of sound deviation Isobaric thermal expansion coefficient Excess isentropic compressibility Models for the speed of sound |
| url | http://www.saber.ula.ve/bitstream/123456789/37138/1/articulo3.pdf |
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