5-[(4-Methylphenyl)sulfonyl]-1-phenylthiopyrano[4,3-b]indole-3(5H)-thione dichloromethane monosolvate
Rhodium-catalyzed [2+2+2] cycloaddition of carbon disulfide to o,N-dialkynyltosylanilines gives two isomeric indolothiopyranthiones, a violet and a red isomer. This is the first crystal structure of a red isomer, which crystallizes with one solvent molecule of dichloromethane in the asymmetric unit,...
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| Language: | English |
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International Union of Crystallography
2023-05-01
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314623003541 |
| _version_ | 1797692294388776960 |
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| author | Benjamin Dassonneville Dieter Schollmeyer Heiner Detert |
| author_facet | Benjamin Dassonneville Dieter Schollmeyer Heiner Detert |
| author_sort | Benjamin Dassonneville |
| collection | DOAJ |
| description | Rhodium-catalyzed [2+2+2] cycloaddition of carbon disulfide to o,N-dialkynyltosylanilines gives two isomeric indolothiopyranthiones, a violet and a red isomer. This is the first crystal structure of a red isomer, which crystallizes with one solvent molecule of dichloromethane in the asymmetric unit, C24H17NO2S3·CH2Cl2. In the extended structure, centrosymmetric pairs of the planar annulated system are arranged in strands and solvent molecules fill the space between the strands. |
| first_indexed | 2024-03-12T02:26:30Z |
| format | Article |
| id | doaj.art-ebbb79c082614d9abdd1c32f42ef2894 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-03-12T02:26:30Z |
| publishDate | 2023-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-ebbb79c082614d9abdd1c32f42ef28942023-09-05T13:04:45ZengInternational Union of CrystallographyIUCrData2414-31462023-05-0185x23035410.1107/S2414314623003541bt41375-[(4-Methylphenyl)sulfonyl]-1-phenylthiopyrano[4,3-b]indole-3(5H)-thione dichloromethane monosolvateBenjamin Dassonneville0Dieter Schollmeyer1Heiner Detert2University of Mainz, Department of Chemistry, Duesbergweg 10-14, 55099 Mainz, GermanyUniversity of Mainz, Department of Chemistry, Duesbergweg 10-14, 55099 Mainz, GermanyUniversity of Mainz, Department of Chemistry, Duesbergweg 10-14, 55099 Mainz, GermanyRhodium-catalyzed [2+2+2] cycloaddition of carbon disulfide to o,N-dialkynyltosylanilines gives two isomeric indolothiopyranthiones, a violet and a red isomer. This is the first crystal structure of a red isomer, which crystallizes with one solvent molecule of dichloromethane in the asymmetric unit, C24H17NO2S3·CH2Cl2. In the extended structure, centrosymmetric pairs of the planar annulated system are arranged in strands and solvent molecules fill the space between the strands.http://scripts.iucr.org/cgi-bin/paper?S2414314623003541crystal structuresulfurannulated heterocycles |
| spellingShingle | Benjamin Dassonneville Dieter Schollmeyer Heiner Detert 5-[(4-Methylphenyl)sulfonyl]-1-phenylthiopyrano[4,3-b]indole-3(5H)-thione dichloromethane monosolvate IUCrData crystal structure sulfur annulated heterocycles |
| title | 5-[(4-Methylphenyl)sulfonyl]-1-phenylthiopyrano[4,3-b]indole-3(5H)-thione dichloromethane monosolvate |
| title_full | 5-[(4-Methylphenyl)sulfonyl]-1-phenylthiopyrano[4,3-b]indole-3(5H)-thione dichloromethane monosolvate |
| title_fullStr | 5-[(4-Methylphenyl)sulfonyl]-1-phenylthiopyrano[4,3-b]indole-3(5H)-thione dichloromethane monosolvate |
| title_full_unstemmed | 5-[(4-Methylphenyl)sulfonyl]-1-phenylthiopyrano[4,3-b]indole-3(5H)-thione dichloromethane monosolvate |
| title_short | 5-[(4-Methylphenyl)sulfonyl]-1-phenylthiopyrano[4,3-b]indole-3(5H)-thione dichloromethane monosolvate |
| title_sort | 5 4 methylphenyl sulfonyl 1 phenylthiopyrano 4 3 b indole 3 5h thione dichloromethane monosolvate |
| topic | crystal structure sulfur annulated heterocycles |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314623003541 |
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