Hardness and degree of conversion of dental restorative composites based on an organic-inorganic hybrid

This paper presents a factorial design (mixture design) used to analyze the hardness and degree of monomer conversion into composites containing conventional monomers and an organic-inorganic hybrid polymer-based methacryloyloxypropyl trimethoxysilane (MEMO). For this purpose, resins (composites wit...

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Main Authors: Sandro Aurélio de Souza Venter, Silvia Luciana Fávaro, Eduardo Radovanovic, Emerson Marcelo Girotto
Format: Article
Language:English
Published: Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol) 2013-01-01
Series:Materials Research
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392013005000089
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author Sandro Aurélio de Souza Venter
Silvia Luciana Fávaro
Eduardo Radovanovic
Emerson Marcelo Girotto
author_facet Sandro Aurélio de Souza Venter
Silvia Luciana Fávaro
Eduardo Radovanovic
Emerson Marcelo Girotto
author_sort Sandro Aurélio de Souza Venter
collection DOAJ
description This paper presents a factorial design (mixture design) used to analyze the hardness and degree of monomer conversion into composites containing conventional monomers and an organic-inorganic hybrid polymer-based methacryloyloxypropyl trimethoxysilane (MEMO). For this purpose, resins (composites with SiO2) were formulated with the hybrid polymer (polycondensed, pMEMO), and two conventional monomers used in dentistry, bisphenol-A dimethacrylate (Bis-GMA) and triethyleneglycol dimethacrylate (TEGDMA). The resins were characterized through the degree of monomer conversion and Vickers hardness, and the pMEMO by means of FTIR and ¹H NMR. The results showed an increase in hardness for resins containing the hybrid material relative to the resins containing only conventional monomers. The mathematical model adjusted to the experimental data yielded an optimized formulation, which presented a higher hardness value (48.88 HV).
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publishDate 2013-01-01
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spelling doaj.art-ebe2f4e426dd41cd9cd28a9fdf8722602022-12-21T19:04:15ZengAssociação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)Materials Research1516-14392013-01-01ahead0Hardness and degree of conversion of dental restorative composites based on an organic-inorganic hybridSandro Aurélio de Souza VenterSilvia Luciana FávaroEduardo RadovanovicEmerson Marcelo GirottoThis paper presents a factorial design (mixture design) used to analyze the hardness and degree of monomer conversion into composites containing conventional monomers and an organic-inorganic hybrid polymer-based methacryloyloxypropyl trimethoxysilane (MEMO). For this purpose, resins (composites with SiO2) were formulated with the hybrid polymer (polycondensed, pMEMO), and two conventional monomers used in dentistry, bisphenol-A dimethacrylate (Bis-GMA) and triethyleneglycol dimethacrylate (TEGDMA). The resins were characterized through the degree of monomer conversion and Vickers hardness, and the pMEMO by means of FTIR and ¹H NMR. The results showed an increase in hardness for resins containing the hybrid material relative to the resins containing only conventional monomers. The mathematical model adjusted to the experimental data yielded an optimized formulation, which presented a higher hardness value (48.88 HV).http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392013005000089
spellingShingle Sandro Aurélio de Souza Venter
Silvia Luciana Fávaro
Eduardo Radovanovic
Emerson Marcelo Girotto
Hardness and degree of conversion of dental restorative composites based on an organic-inorganic hybrid
Materials Research
title Hardness and degree of conversion of dental restorative composites based on an organic-inorganic hybrid
title_full Hardness and degree of conversion of dental restorative composites based on an organic-inorganic hybrid
title_fullStr Hardness and degree of conversion of dental restorative composites based on an organic-inorganic hybrid
title_full_unstemmed Hardness and degree of conversion of dental restorative composites based on an organic-inorganic hybrid
title_short Hardness and degree of conversion of dental restorative composites based on an organic-inorganic hybrid
title_sort hardness and degree of conversion of dental restorative composites based on an organic inorganic hybrid
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392013005000089
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AT eduardoradovanovic hardnessanddegreeofconversionofdentalrestorativecompositesbasedonanorganicinorganichybrid
AT emersonmarcelogirotto hardnessanddegreeofconversionofdentalrestorativecompositesbasedonanorganicinorganichybrid