Hardness and degree of conversion of dental restorative composites based on an organic-inorganic hybrid
This paper presents a factorial design (mixture design) used to analyze the hardness and degree of monomer conversion into composites containing conventional monomers and an organic-inorganic hybrid polymer-based methacryloyloxypropyl trimethoxysilane (MEMO). For this purpose, resins (composites wit...
Main Authors: | , , , |
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Format: | Article |
Language: | English |
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Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)
2013-01-01
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Series: | Materials Research |
Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392013005000089 |
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author | Sandro Aurélio de Souza Venter Silvia Luciana Fávaro Eduardo Radovanovic Emerson Marcelo Girotto |
author_facet | Sandro Aurélio de Souza Venter Silvia Luciana Fávaro Eduardo Radovanovic Emerson Marcelo Girotto |
author_sort | Sandro Aurélio de Souza Venter |
collection | DOAJ |
description | This paper presents a factorial design (mixture design) used to analyze the hardness and degree of monomer conversion into composites containing conventional monomers and an organic-inorganic hybrid polymer-based methacryloyloxypropyl trimethoxysilane (MEMO). For this purpose, resins (composites with SiO2) were formulated with the hybrid polymer (polycondensed, pMEMO), and two conventional monomers used in dentistry, bisphenol-A dimethacrylate (Bis-GMA) and triethyleneglycol dimethacrylate (TEGDMA). The resins were characterized through the degree of monomer conversion and Vickers hardness, and the pMEMO by means of FTIR and ¹H NMR. The results showed an increase in hardness for resins containing the hybrid material relative to the resins containing only conventional monomers. The mathematical model adjusted to the experimental data yielded an optimized formulation, which presented a higher hardness value (48.88 HV). |
first_indexed | 2024-12-21T12:22:59Z |
format | Article |
id | doaj.art-ebe2f4e426dd41cd9cd28a9fdf872260 |
institution | Directory Open Access Journal |
issn | 1516-1439 |
language | English |
last_indexed | 2024-12-21T12:22:59Z |
publishDate | 2013-01-01 |
publisher | Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol) |
record_format | Article |
series | Materials Research |
spelling | doaj.art-ebe2f4e426dd41cd9cd28a9fdf8722602022-12-21T19:04:15ZengAssociação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)Materials Research1516-14392013-01-01ahead0Hardness and degree of conversion of dental restorative composites based on an organic-inorganic hybridSandro Aurélio de Souza VenterSilvia Luciana FávaroEduardo RadovanovicEmerson Marcelo GirottoThis paper presents a factorial design (mixture design) used to analyze the hardness and degree of monomer conversion into composites containing conventional monomers and an organic-inorganic hybrid polymer-based methacryloyloxypropyl trimethoxysilane (MEMO). For this purpose, resins (composites with SiO2) were formulated with the hybrid polymer (polycondensed, pMEMO), and two conventional monomers used in dentistry, bisphenol-A dimethacrylate (Bis-GMA) and triethyleneglycol dimethacrylate (TEGDMA). The resins were characterized through the degree of monomer conversion and Vickers hardness, and the pMEMO by means of FTIR and ¹H NMR. The results showed an increase in hardness for resins containing the hybrid material relative to the resins containing only conventional monomers. The mathematical model adjusted to the experimental data yielded an optimized formulation, which presented a higher hardness value (48.88 HV).http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392013005000089 |
spellingShingle | Sandro Aurélio de Souza Venter Silvia Luciana Fávaro Eduardo Radovanovic Emerson Marcelo Girotto Hardness and degree of conversion of dental restorative composites based on an organic-inorganic hybrid Materials Research |
title | Hardness and degree of conversion of dental restorative composites based on an organic-inorganic hybrid |
title_full | Hardness and degree of conversion of dental restorative composites based on an organic-inorganic hybrid |
title_fullStr | Hardness and degree of conversion of dental restorative composites based on an organic-inorganic hybrid |
title_full_unstemmed | Hardness and degree of conversion of dental restorative composites based on an organic-inorganic hybrid |
title_short | Hardness and degree of conversion of dental restorative composites based on an organic-inorganic hybrid |
title_sort | hardness and degree of conversion of dental restorative composites based on an organic inorganic hybrid |
url | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392013005000089 |
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