A Window into the Workings of <i>anti</i>-B<sub>18</sub>H<sub>22</sub> Luminescence—Blue-Fluorescent Isomeric Pair 3,3′-Cl<sub>2</sub>-B<sub>18</sub>H<sub>20</sub> and 3,4′-Cl<sub>2</sub>-B<sub>18</sub>H<sub>20</sub> (and Others)

A Window into the Workings of <i>anti</i>-B<sub>18</sub>H<sub>22</sub> Luminescence—Blue-Fluorescent Isomeric Pair 3,3′-Cl<sub>2</sub>-B<sub>18</sub>H<sub>20</sub> and 3,4′-Cl<sub>2</sub>-B<sub>18</sub>H<sub>20</sub> (and Others)

The action of AlCl<sub>3</sub> on room-temperature tetrachloromethane solutions of <i>anti</i>-B<sub>18</sub>H<sub>22</sub> (<b>1</b>) results in a mixture of fluorescent isomers, 3,3′-Cl<sub>2</sub>-B<sub>18</sub>H&...

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Bibliographic Details
Main Authors: Marcel Ehn, Dmytro Bavol, Jonathan Bould, Vojtěch Strnad, Miroslava Litecká, Kamil Lang, Kaplan Kirakci, William Clegg, Paul G. Waddell, Michael G. S. Londesborough
Format: Article
Language:English
Published: MDPI AG 2023-06-01
Series:Molecules
Subjects:
<i>anti</i>-B<sub>18</sub>H<sub>22</sub>
luminescence
fluorescence
cluster boron hydrides
chlorination
halogenation
Online Access:https://www.mdpi.com/1420-3049/28/11/4505

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