Long-term trend of CO<sub>2</sub> and ocean acidification in the surface water of the Ulleung Basin, the East/Japan Sea inferred from the underway observational data

Anthropogenic carbon is responsible for both global warming and ocean acidification. Efforts are underway to understand the role of ocean in a high CO<sub>2</sub> world on a global context. However, marginal seas received little attention despite their significant contribution to biogeoc...

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Bibliographic Details
Main Authors: J.-Y. Kim, D.-J. Kang, T. Lee, K.-R. Kim
Format: Article
Language:English
Published: Copernicus Publications 2014-05-01
Series:Biogeosciences
Online Access:http://www.biogeosciences.net/11/2443/2014/bg-11-2443-2014.pdf
Description
Summary:Anthropogenic carbon is responsible for both global warming and ocean acidification. Efforts are underway to understand the role of ocean in a high CO<sub>2</sub> world on a global context. However, marginal seas received little attention despite their significant contribution to biogeochemical cycles. Here we report the CO<sub>2</sub> increase and ocean acidification in the surface waters of the Ulleung Basin (UB) of the East/Japan Sea, and possible causes are discussed. Fourteen observations of surface <i>f</i>CO<sub>2</sub> were made in the period from 1995 to 2009. The contribution of temperature variation to the seasonality of <i>f</i>CO<sub>2</sub> was almost equivalent to the non-thermal effect in the UB. However, the difference of relative contribution with the season makes two seasonal peaks of <i>f</i>CO<sub>2</sub> in the surface water of the UB. Non-thermal effect contributed to the surface <i>f</i>CO<sub>2</sub> drawdown in summer, whereas the surface <i>f</i>CO<sub>2</sub> elevation in winter. The decadal trend of <i>f</i>CO<sub>2</sub> increment was estimated by harmonic analysis. The estimated rates of increase of <i>f</i>CO<sub>2</sub> were 1.8 ± 0.4 μatm yr<sup>−1</sup> for the atmosphere and 2.7 ± 1.1 μatm yr<sup>−1</sup> for the surface water. The ocean acidification trend, calculated from total alkalinity and <i>f</i>CO<sub>2</sub>, was estimated to be −0.03 ± 0.02 pH units decade<sup>−1</sup>. These rates seem to be higher than observations at most other ocean time-series sites during the same period of time. Sustained observations are required to understand more accurate trend in this area.
ISSN:1726-4170
1726-4189