Water and Aqueous Mixtures as Convenient Alternative Media for Organoselenium Chemistry
Even if water is the natural environment for bioorganic reactions, its use in organic chemistry is often severely limited by the high insolubility of the organic derivatives. In this review, we introduce some examples of the use of water to perform organoselenium chemistry. We mainly discuss the adv...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2016-11-01
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| Series: | Molecules |
| Subjects: | |
| Online Access: | http://www.mdpi.com/1420-3049/21/11/1482 |
| _version_ | 1818921095845117952 |
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| author | Claudio Santi Raquel G. Jacob Bonifacio Monti Luana Bagnoli Luca Sancineto Eder J. Lenardão |
| author_facet | Claudio Santi Raquel G. Jacob Bonifacio Monti Luana Bagnoli Luca Sancineto Eder J. Lenardão |
| author_sort | Claudio Santi |
| collection | DOAJ |
| description | Even if water is the natural environment for bioorganic reactions, its use in organic chemistry is often severely limited by the high insolubility of the organic derivatives. In this review, we introduce some examples of the use of water to perform organoselenium chemistry. We mainly discuss the advantages of this medium when the recyclability is demonstrated and when the water can control the selectivity of a reaction or enhance the reaction rate. |
| first_indexed | 2024-12-20T01:32:12Z |
| format | Article |
| id | doaj.art-ec15e457863b402894df887baf100966 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-20T01:32:12Z |
| publishDate | 2016-11-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-ec15e457863b402894df887baf1009662022-12-21T19:58:06ZengMDPI AGMolecules1420-30492016-11-012111148210.3390/molecules21111482molecules21111482Water and Aqueous Mixtures as Convenient Alternative Media for Organoselenium ChemistryClaudio Santi0Raquel G. Jacob1Bonifacio Monti2Luana Bagnoli3Luca Sancineto4Eder J. Lenardão5Department of Pharmaceutical Sciences, Group of Catalysis and Organic Green Chemistry, University of Perugia, Via del Liceo 1, Perugia 06100, ItalyLaboratório de Síntese Orgânica Limpa-LASOL-CCQFA-Universidade Federal de Pelotas-UFPel, P.O. Box 354, Pelotas 96010-900, RS, BrazilDepartment of Pharmaceutical Sciences, Group of Catalysis and Organic Green Chemistry, University of Perugia, Via del Liceo 1, Perugia 06100, ItalyDepartment of Pharmaceutical Sciences, Group of Catalysis and Organic Green Chemistry, University of Perugia, Via del Liceo 1, Perugia 06100, ItalyDepartment of Pharmaceutical Sciences, Group of Catalysis and Organic Green Chemistry, University of Perugia, Via del Liceo 1, Perugia 06100, ItalyLaboratório de Síntese Orgânica Limpa-LASOL-CCQFA-Universidade Federal de Pelotas-UFPel, P.O. Box 354, Pelotas 96010-900, RS, BrazilEven if water is the natural environment for bioorganic reactions, its use in organic chemistry is often severely limited by the high insolubility of the organic derivatives. In this review, we introduce some examples of the use of water to perform organoselenium chemistry. We mainly discuss the advantages of this medium when the recyclability is demonstrated and when the water can control the selectivity of a reaction or enhance the reaction rate.http://www.mdpi.com/1420-3049/21/11/1482on-water reactionswaterseleniumepoxidezincmichael additioncouplingcatalysisoxidation |
| spellingShingle | Claudio Santi Raquel G. Jacob Bonifacio Monti Luana Bagnoli Luca Sancineto Eder J. Lenardão Water and Aqueous Mixtures as Convenient Alternative Media for Organoselenium Chemistry Molecules on-water reactions water selenium epoxide zinc michael addition coupling catalysis oxidation |
| title | Water and Aqueous Mixtures as Convenient Alternative Media for Organoselenium Chemistry |
| title_full | Water and Aqueous Mixtures as Convenient Alternative Media for Organoselenium Chemistry |
| title_fullStr | Water and Aqueous Mixtures as Convenient Alternative Media for Organoselenium Chemistry |
| title_full_unstemmed | Water and Aqueous Mixtures as Convenient Alternative Media for Organoselenium Chemistry |
| title_short | Water and Aqueous Mixtures as Convenient Alternative Media for Organoselenium Chemistry |
| title_sort | water and aqueous mixtures as convenient alternative media for organoselenium chemistry |
| topic | on-water reactions water selenium epoxide zinc michael addition coupling catalysis oxidation |
| url | http://www.mdpi.com/1420-3049/21/11/1482 |
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