Spontaneous demixing of chiral active mixtures in motility-induced phase separation

The demixing and sorting strategies for chiral active mixtures are crucial to the biochemical and pharmaceutical industries. However, it remains uncertain whether chiral mixed particles can spontaneously demix without the aid of specific strategies. In this paper, we investigate the demixing behavio...

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Main Authors: Bao-Quan Ai, Shan Quan, Feng-guo Li
Format: Article
Language:English
Published: IOP Publishing 2023-01-01
Series:New Journal of Physics
Subjects:
Online Access:https://doi.org/10.1088/1367-2630/acdf79
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author Bao-Quan Ai
Shan Quan
Feng-guo Li
author_facet Bao-Quan Ai
Shan Quan
Feng-guo Li
author_sort Bao-Quan Ai
collection DOAJ
description The demixing and sorting strategies for chiral active mixtures are crucial to the biochemical and pharmaceutical industries. However, it remains uncertain whether chiral mixed particles can spontaneously demix without the aid of specific strategies. In this paper, we investigate the demixing behaviors of binary mixtures in a model of chiral active particles to understand the demixing mechanism of chiral active mixtures. We demonstrate that chiral mixed particles can spontaneously demix in motility-induced phase separation (MIPS). The hidden velocity alignment in MIPS allows particles of different types to accumulate in different clusters, thereby facilitating separation. There exists an optimal angular velocity or packing fraction at which this separation is optimal. Noise (translational or rotational diffusion) can promote mixture separation in certain cases, rather than always being detrimental to the process. Since the order caused by the hidden velocity alignment in this process is not global, the separation behavior is strongly dependent on the system size. Furthermore, we also discovered that the mixture separation caused by MIPS is different from that resulting from explicit velocity alignment. Our findings are crucial for understanding the demixing mechanism of chiral active mixtures and can be applied to experiments attempting to separate various active mixtures in the future.
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spelling doaj.art-ec1fa91541c24372857fde7e2b6a65712023-08-09T14:13:25ZengIOP PublishingNew Journal of Physics1367-26302023-01-0125606302510.1088/1367-2630/acdf79Spontaneous demixing of chiral active mixtures in motility-induced phase separationBao-Quan Ai0https://orcid.org/0000-0002-3033-8630Shan Quan1Feng-guo Li2Guangdong Provincial Key Laboratory of Quantum Engineering and Quantum Materials, School of Physics, South China Normal University , Guangzhou 510006, People’s Republic of China; Guangdong-Hong Kong Joint Laboratory of Quantum Matter, Frontier Research Institute for Physics, South China Normal University , Guangzhou 510006, People’s Republic of ChinaGuangdong Provincial Key Laboratory of Quantum Engineering and Quantum Materials, School of Physics, South China Normal University , Guangzhou 510006, People’s Republic of China; Guangdong-Hong Kong Joint Laboratory of Quantum Matter, Frontier Research Institute for Physics, South China Normal University , Guangzhou 510006, People’s Republic of ChinaGuangdong Provincial Key Laboratory of Quantum Engineering and Quantum Materials, School of Physics, South China Normal University , Guangzhou 510006, People’s Republic of China; Guangdong-Hong Kong Joint Laboratory of Quantum Matter, Frontier Research Institute for Physics, South China Normal University , Guangzhou 510006, People’s Republic of ChinaThe demixing and sorting strategies for chiral active mixtures are crucial to the biochemical and pharmaceutical industries. However, it remains uncertain whether chiral mixed particles can spontaneously demix without the aid of specific strategies. In this paper, we investigate the demixing behaviors of binary mixtures in a model of chiral active particles to understand the demixing mechanism of chiral active mixtures. We demonstrate that chiral mixed particles can spontaneously demix in motility-induced phase separation (MIPS). The hidden velocity alignment in MIPS allows particles of different types to accumulate in different clusters, thereby facilitating separation. There exists an optimal angular velocity or packing fraction at which this separation is optimal. Noise (translational or rotational diffusion) can promote mixture separation in certain cases, rather than always being detrimental to the process. Since the order caused by the hidden velocity alignment in this process is not global, the separation behavior is strongly dependent on the system size. Furthermore, we also discovered that the mixture separation caused by MIPS is different from that resulting from explicit velocity alignment. Our findings are crucial for understanding the demixing mechanism of chiral active mixtures and can be applied to experiments attempting to separate various active mixtures in the future.https://doi.org/10.1088/1367-2630/acdf79spontaneous demixingchiral active mixturesmotility-induced phase separation
spellingShingle Bao-Quan Ai
Shan Quan
Feng-guo Li
Spontaneous demixing of chiral active mixtures in motility-induced phase separation
New Journal of Physics
spontaneous demixing
chiral active mixtures
motility-induced phase separation
title Spontaneous demixing of chiral active mixtures in motility-induced phase separation
title_full Spontaneous demixing of chiral active mixtures in motility-induced phase separation
title_fullStr Spontaneous demixing of chiral active mixtures in motility-induced phase separation
title_full_unstemmed Spontaneous demixing of chiral active mixtures in motility-induced phase separation
title_short Spontaneous demixing of chiral active mixtures in motility-induced phase separation
title_sort spontaneous demixing of chiral active mixtures in motility induced phase separation
topic spontaneous demixing
chiral active mixtures
motility-induced phase separation
url https://doi.org/10.1088/1367-2630/acdf79
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AT shanquan spontaneousdemixingofchiralactivemixturesinmotilityinducedphaseseparation
AT fengguoli spontaneousdemixingofchiralactivemixturesinmotilityinducedphaseseparation