Development of Graphene-Based Polymeric Nanocomposites: A Brief Overview

Graphene (G) and its derivatives, such as graphene oxide (GO) and reduced GO (rGO), have outstanding electrical, mechanical, thermal, optical, and electrochemical properties, owed to their 2D structure and large specific surface area. Further, their combination with polymers leads to novel nanocompo...

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Main Author: Ana M. Díez-Pascual
Format: Article
Language:English
Published: MDPI AG 2021-09-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/13/17/2978
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author Ana M. Díez-Pascual
author_facet Ana M. Díez-Pascual
author_sort Ana M. Díez-Pascual
collection DOAJ
description Graphene (G) and its derivatives, such as graphene oxide (GO) and reduced GO (rGO), have outstanding electrical, mechanical, thermal, optical, and electrochemical properties, owed to their 2D structure and large specific surface area. Further, their combination with polymers leads to novel nanocomposites with enhanced structural and functional properties due to synergistic effects. Such nanocomposites are becoming increasingly useful in a wide variety of fields ranging from biomedicine to the electronics and energy storage applications. In this review, a brief introduction on the aforementioned G derivatives is presented, and different strategies to develop polymeric nanocomposites are described. Several functionalization methods including covalent and non-covalent approaches to increase their interaction with polymers are summarized, and selected examples are provided. Further, applications of this type of nanocomposites in the field of energy are discussed, including lithium-ion batteries, supercapacitors, transparent conductive electrodes, counter electrodes of dye-sensitized solar cells, and active layers of organic solar cells. Finally, the challenges and future outlook for G-based polymeric nanocomposites are discussed.
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spelling doaj.art-ec43073e92374d69bbf5f0af3f0870312023-11-22T11:06:13ZengMDPI AGPolymers2073-43602021-09-011317297810.3390/polym13172978Development of Graphene-Based Polymeric Nanocomposites: A Brief OverviewAna M. Díez-Pascual0Universidad de Alcalá, Facultad de Ciencias, Departamento de Química Analítica, Química Física e Ingeniería Química, Ctra. Madrid-Barcelona, Km. 33.6, 28805 Alcalá de Henares, Madrid, SpainGraphene (G) and its derivatives, such as graphene oxide (GO) and reduced GO (rGO), have outstanding electrical, mechanical, thermal, optical, and electrochemical properties, owed to their 2D structure and large specific surface area. Further, their combination with polymers leads to novel nanocomposites with enhanced structural and functional properties due to synergistic effects. Such nanocomposites are becoming increasingly useful in a wide variety of fields ranging from biomedicine to the electronics and energy storage applications. In this review, a brief introduction on the aforementioned G derivatives is presented, and different strategies to develop polymeric nanocomposites are described. Several functionalization methods including covalent and non-covalent approaches to increase their interaction with polymers are summarized, and selected examples are provided. Further, applications of this type of nanocomposites in the field of energy are discussed, including lithium-ion batteries, supercapacitors, transparent conductive electrodes, counter electrodes of dye-sensitized solar cells, and active layers of organic solar cells. Finally, the challenges and future outlook for G-based polymeric nanocomposites are discussed.https://www.mdpi.com/2073-4360/13/17/2978polymer nanocompositesgraphenegraphene oxidefunctionalizationsynergistic effectsenergy storage
spellingShingle Ana M. Díez-Pascual
Development of Graphene-Based Polymeric Nanocomposites: A Brief Overview
Polymers
polymer nanocomposites
graphene
graphene oxide
functionalization
synergistic effects
energy storage
title Development of Graphene-Based Polymeric Nanocomposites: A Brief Overview
title_full Development of Graphene-Based Polymeric Nanocomposites: A Brief Overview
title_fullStr Development of Graphene-Based Polymeric Nanocomposites: A Brief Overview
title_full_unstemmed Development of Graphene-Based Polymeric Nanocomposites: A Brief Overview
title_short Development of Graphene-Based Polymeric Nanocomposites: A Brief Overview
title_sort development of graphene based polymeric nanocomposites a brief overview
topic polymer nanocomposites
graphene
graphene oxide
functionalization
synergistic effects
energy storage
url https://www.mdpi.com/2073-4360/13/17/2978
work_keys_str_mv AT anamdiezpascual developmentofgraphenebasedpolymericnanocompositesabriefoverview