Realizing the potential of metallic iron for the mitigation of toxics: flee or adapt?

Abstract Metallic iron (Fe0) has been increasingly used to remove toxics from water over the past three decades. However, the idea that metallic iron (Fe0) is not an environmental reducing agent has been vigorously refuted. Researchers presenting their findings in a scientific journal have to accept...

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Main Authors: Bernard Konadu-Amoah, Rui Hu, Viet Cao, Ran Tao, Huichen Yang, Arnaud Igor Ndé-Tchoupé, Willis Gwenzi, Hans Ruppert, Chicgoua Noubactep
Format: Article
Language:English
Published: SpringerOpen 2022-08-01
Series:Applied Water Science
Subjects:
Online Access:https://doi.org/10.1007/s13201-022-01738-9
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author Bernard Konadu-Amoah
Rui Hu
Viet Cao
Ran Tao
Huichen Yang
Arnaud Igor Ndé-Tchoupé
Willis Gwenzi
Hans Ruppert
Chicgoua Noubactep
author_facet Bernard Konadu-Amoah
Rui Hu
Viet Cao
Ran Tao
Huichen Yang
Arnaud Igor Ndé-Tchoupé
Willis Gwenzi
Hans Ruppert
Chicgoua Noubactep
author_sort Bernard Konadu-Amoah
collection DOAJ
description Abstract Metallic iron (Fe0) has been increasingly used to remove toxics from water over the past three decades. However, the idea that metallic iron (Fe0) is not an environmental reducing agent has been vigorously refuted. Researchers presenting their findings in a scientific journal have to accept the burden of proving that their argument has any validity. This 30-year-lasting discussion within the Fe0 remediation community is alien to electro-chemists, as it is a century-old knowledge. Nevertheless, the peer-reviewed literature on “remediation using Fe0” seems to be dominated by evaluators thinking that Fe0 is a reducing agent. This communication challenges the view that Fe0 donates any electron to any dissolved species. The sole goal is to reconcile a proven efficient technology with its scientific roots and enable the design of better Fe0 remediation systems.
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spelling doaj.art-ec5207049b324ff7a116a18cd19b986b2022-12-22T01:32:24ZengSpringerOpenApplied Water Science2190-54872190-54952022-08-0112911110.1007/s13201-022-01738-9Realizing the potential of metallic iron for the mitigation of toxics: flee or adapt?Bernard Konadu-Amoah0Rui Hu1Viet Cao2Ran Tao3Huichen Yang4Arnaud Igor Ndé-Tchoupé5Willis Gwenzi6Hans Ruppert7Chicgoua Noubactep8School of Earth Science and Engineering, Hohai UniversitySchool of Earth Science and Engineering, Hohai UniversityFaculty of Natural Sciences, Hung Vuong UniversityAngewandte Geologie, Universität GöttingenAngewandte Geologie, Universität GöttingenSchool of Earth Science and Engineering, Hohai UniversityBiosystems and Environmental Engineering Research Group, Department of Soil Science and Agricultural Engineering, University of ZimbabweDepartment of Sedimentology and Environmental Geology, University of GöttingenAngewandte Geologie, Universität GöttingenAbstract Metallic iron (Fe0) has been increasingly used to remove toxics from water over the past three decades. However, the idea that metallic iron (Fe0) is not an environmental reducing agent has been vigorously refuted. Researchers presenting their findings in a scientific journal have to accept the burden of proving that their argument has any validity. This 30-year-lasting discussion within the Fe0 remediation community is alien to electro-chemists, as it is a century-old knowledge. Nevertheless, the peer-reviewed literature on “remediation using Fe0” seems to be dominated by evaluators thinking that Fe0 is a reducing agent. This communication challenges the view that Fe0 donates any electron to any dissolved species. The sole goal is to reconcile a proven efficient technology with its scientific roots and enable the design of better Fe0 remediation systems.https://doi.org/10.1007/s13201-022-01738-9Electrochemical dissolution kineticsGroundwater remediationPermeable reactive barrierWater treatmentZero-valent iron
spellingShingle Bernard Konadu-Amoah
Rui Hu
Viet Cao
Ran Tao
Huichen Yang
Arnaud Igor Ndé-Tchoupé
Willis Gwenzi
Hans Ruppert
Chicgoua Noubactep
Realizing the potential of metallic iron for the mitigation of toxics: flee or adapt?
Applied Water Science
Electrochemical dissolution kinetics
Groundwater remediation
Permeable reactive barrier
Water treatment
Zero-valent iron
title Realizing the potential of metallic iron for the mitigation of toxics: flee or adapt?
title_full Realizing the potential of metallic iron for the mitigation of toxics: flee or adapt?
title_fullStr Realizing the potential of metallic iron for the mitigation of toxics: flee or adapt?
title_full_unstemmed Realizing the potential of metallic iron for the mitigation of toxics: flee or adapt?
title_short Realizing the potential of metallic iron for the mitigation of toxics: flee or adapt?
title_sort realizing the potential of metallic iron for the mitigation of toxics flee or adapt
topic Electrochemical dissolution kinetics
Groundwater remediation
Permeable reactive barrier
Water treatment
Zero-valent iron
url https://doi.org/10.1007/s13201-022-01738-9
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