Bis(2-amino-4-methylpyridinium) trans-diaquabis(pyrazine-2,3-dicarboxylato)cuprate(II) hexahydrate
The title compound, (C6H9N2)2[Cu(C6H2N2O4)2(H2O)2]·6H2O, consists of a mononuclear trans-[Cu(pzdc)2(H2O)2]2− dianion (pzdc is pyrazine-2,3-dicarboxylate) and two [ampyH]+ cations (ampy is 2-amino-4-methylpyridine) with six water molecules of solvation. The CuII atom is hex...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-07-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810023081 |
| _version_ | 1819280196788813824 |
|---|---|
| author | Hossein Eshtiagh-Hosseini Fabienne Gschwind Nafiseh Alfi Masoud Mirzaei |
| author_facet | Hossein Eshtiagh-Hosseini Fabienne Gschwind Nafiseh Alfi Masoud Mirzaei |
| author_sort | Hossein Eshtiagh-Hosseini |
| collection | DOAJ |
| description | The title compound, (C6H9N2)2[Cu(C6H2N2O4)2(H2O)2]·6H2O, consists of a mononuclear trans-[Cu(pzdc)2(H2O)2]2− dianion (pzdc is pyrazine-2,3-dicarboxylate) and two [ampyH]+ cations (ampy is 2-amino-4-methylpyridine) with six water molecules of solvation. The CuII atom is hexacoordinated by two pzdc groups and two water molecules. The coordinated water molecules are in trans-diaxial positions and the pzdc dianion acts as a bidentate ligand through an O atom of the carboxylate group and the N atom of the pyrazine ring. There are diverse hydrogen-bonding interactions, such as N—H...O and O—H...O contacts, which lead to the formation of a three-dimensional supramolecular architecture. |
| first_indexed | 2024-12-24T00:39:58Z |
| format | Article |
| id | doaj.art-ec768825593a4c9fb43379afdfc8d6f0 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:39:58Z |
| publishDate | 2010-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-ec768825593a4c9fb43379afdfc8d6f02022-12-21T17:24:00ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-07-01667m826m82710.1107/S1600536810023081Bis(2-amino-4-methylpyridinium) trans-diaquabis(pyrazine-2,3-dicarboxylato)cuprate(II) hexahydrateHossein Eshtiagh-HosseiniFabienne GschwindNafiseh AlfiMasoud MirzaeiThe title compound, (C6H9N2)2[Cu(C6H2N2O4)2(H2O)2]·6H2O, consists of a mononuclear trans-[Cu(pzdc)2(H2O)2]2− dianion (pzdc is pyrazine-2,3-dicarboxylate) and two [ampyH]+ cations (ampy is 2-amino-4-methylpyridine) with six water molecules of solvation. The CuII atom is hexacoordinated by two pzdc groups and two water molecules. The coordinated water molecules are in trans-diaxial positions and the pzdc dianion acts as a bidentate ligand through an O atom of the carboxylate group and the N atom of the pyrazine ring. There are diverse hydrogen-bonding interactions, such as N—H...O and O—H...O contacts, which lead to the formation of a three-dimensional supramolecular architecture.http://scripts.iucr.org/cgi-bin/paper?S1600536810023081 |
| spellingShingle | Hossein Eshtiagh-Hosseini Fabienne Gschwind Nafiseh Alfi Masoud Mirzaei Bis(2-amino-4-methylpyridinium) trans-diaquabis(pyrazine-2,3-dicarboxylato)cuprate(II) hexahydrate Acta Crystallographica Section E |
| title | Bis(2-amino-4-methylpyridinium) trans-diaquabis(pyrazine-2,3-dicarboxylato)cuprate(II) hexahydrate |
| title_full | Bis(2-amino-4-methylpyridinium) trans-diaquabis(pyrazine-2,3-dicarboxylato)cuprate(II) hexahydrate |
| title_fullStr | Bis(2-amino-4-methylpyridinium) trans-diaquabis(pyrazine-2,3-dicarboxylato)cuprate(II) hexahydrate |
| title_full_unstemmed | Bis(2-amino-4-methylpyridinium) trans-diaquabis(pyrazine-2,3-dicarboxylato)cuprate(II) hexahydrate |
| title_short | Bis(2-amino-4-methylpyridinium) trans-diaquabis(pyrazine-2,3-dicarboxylato)cuprate(II) hexahydrate |
| title_sort | bis 2 amino 4 methylpyridinium trans diaquabis pyrazine 2 3 dicarboxylato cuprate ii hexahydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810023081 |
| work_keys_str_mv | AT hosseineshtiaghhosseini bis2amino4methylpyridiniumtransdiaquabispyrazine23dicarboxylatocuprateiihexahydrate AT fabiennegschwind bis2amino4methylpyridiniumtransdiaquabispyrazine23dicarboxylatocuprateiihexahydrate AT nafisehalfi bis2amino4methylpyridiniumtransdiaquabispyrazine23dicarboxylatocuprateiihexahydrate AT masoudmirzaei bis2amino4methylpyridiniumtransdiaquabispyrazine23dicarboxylatocuprateiihexahydrate |