N-(9H-Fluoren-9-ylidene)-4-methylaniline
In the title compound, C20H15N, the fluorene unit is essentially planar [r.m.s. deviation 0.0334 Å] and the benzene ring bound to the imine N atom bears a methyl group which is nearly coplanar [dihedral angle 0.5 (1)°]. The dihedral angle between...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809020765 |
| _version_ | 1818999658810179584 |
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| author | Su-Zhen Bai Xin-Hua Lou Hong-Mei Li Hui Shi |
| author_facet | Su-Zhen Bai Xin-Hua Lou Hong-Mei Li Hui Shi |
| author_sort | Su-Zhen Bai |
| collection | DOAJ |
| description | In the title compound, C20H15N, the fluorene unit is essentially planar [r.m.s. deviation 0.0334 Å] and the benzene ring bound to the imine N atom bears a methyl group which is nearly coplanar [dihedral angle 0.5 (1)°]. The dihedral angle between the substituent benzene ring and the 9H-fluoren-9-imine unit is 71.1 (3)°. Intermolecular π–π interactions between the benzene rings of adjacent fluorene units [centroid–centroid distance 3.8081 (13) Å] are present in the crystal structure, resulting in a one-dimensional supramolecular architecture. |
| first_indexed | 2024-12-20T22:20:56Z |
| format | Article |
| id | doaj.art-ec7a229fdd7d43eba64f39af8aa9ea73 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T22:20:56Z |
| publishDate | 2009-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-ec7a229fdd7d43eba64f39af8aa9ea732022-12-21T19:24:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-07-01657o1545o154510.1107/S1600536809020765N-(9H-Fluoren-9-ylidene)-4-methylanilineSu-Zhen BaiXin-Hua LouHong-Mei LiHui ShiIn the title compound, C20H15N, the fluorene unit is essentially planar [r.m.s. deviation 0.0334 Å] and the benzene ring bound to the imine N atom bears a methyl group which is nearly coplanar [dihedral angle 0.5 (1)°]. The dihedral angle between the substituent benzene ring and the 9H-fluoren-9-imine unit is 71.1 (3)°. Intermolecular π–π interactions between the benzene rings of adjacent fluorene units [centroid–centroid distance 3.8081 (13) Å] are present in the crystal structure, resulting in a one-dimensional supramolecular architecture.http://scripts.iucr.org/cgi-bin/paper?S1600536809020765 |
| spellingShingle | Su-Zhen Bai Xin-Hua Lou Hong-Mei Li Hui Shi N-(9H-Fluoren-9-ylidene)-4-methylaniline Acta Crystallographica Section E |
| title | N-(9H-Fluoren-9-ylidene)-4-methylaniline |
| title_full | N-(9H-Fluoren-9-ylidene)-4-methylaniline |
| title_fullStr | N-(9H-Fluoren-9-ylidene)-4-methylaniline |
| title_full_unstemmed | N-(9H-Fluoren-9-ylidene)-4-methylaniline |
| title_short | N-(9H-Fluoren-9-ylidene)-4-methylaniline |
| title_sort | n 9h fluoren 9 ylidene 4 methylaniline |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809020765 |
| work_keys_str_mv | AT suzhenbai n9hfluoren9ylidene4methylaniline AT xinhualou n9hfluoren9ylidene4methylaniline AT hongmeili n9hfluoren9ylidene4methylaniline AT huishi n9hfluoren9ylidene4methylaniline |