Cathode materials for calcium‐ion batteries: Current status and prospects
Abstract In the post‐lithium‐ion battery era, calcium‐ion batteries (CIBs) have aroused extensive attention because of their strong cost competitiveness, low standard redox potentials, and high safety. However, the related research is progressing slowly due to the constraints of the development of e...
Main Authors: | , , , , , , , , , |
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Format: | Article |
Language: | English |
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Wiley
2023-09-01
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Series: | Carbon Neutralization |
Subjects: | |
Online Access: | https://doi.org/10.1002/cnl2.85 |
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author | Yuhan Wu Ziqi Zhao Xiaorui Hao Rui Xu Laishi Li Dan Lv Xianglong Huang Qing Zhao Yang Xu Yusheng Wu |
author_facet | Yuhan Wu Ziqi Zhao Xiaorui Hao Rui Xu Laishi Li Dan Lv Xianglong Huang Qing Zhao Yang Xu Yusheng Wu |
author_sort | Yuhan Wu |
collection | DOAJ |
description | Abstract In the post‐lithium‐ion battery era, calcium‐ion batteries (CIBs) have aroused extensive attention because of their strong cost competitiveness, low standard redox potentials, and high safety. However, the related research is progressing slowly due to the constraints of the development of electrode materials. The large ionic radius of Ca2+ especially increases the challenge to design cathode materials for reversible Ca2+ uptake/removal. Despite the inspiring achievements, various challenges still need to be further resolved. Here, this review systematically summarizes the recent advances in CIB cathode materials, including Prussian blue and its analogues, metal oxides, metal chalcogenides, polyanionic compounds, and organic materials. We first provide a brief introduction to CIBs and compare their advantages with other battery technologies. Then, preparation methods are introduced, and breakthrough investigations are highlighted. Finally, some possible research directions are discussed to promote the development of this emerging battery technology. |
first_indexed | 2024-03-11T21:33:23Z |
format | Article |
id | doaj.art-ecaede071e56480a902541fbb27d9661 |
institution | Directory Open Access Journal |
issn | 2769-3325 |
language | English |
last_indexed | 2024-03-11T21:33:23Z |
publishDate | 2023-09-01 |
publisher | Wiley |
record_format | Article |
series | Carbon Neutralization |
spelling | doaj.art-ecaede071e56480a902541fbb27d96612023-09-27T07:25:43ZengWileyCarbon Neutralization2769-33252023-09-012555157310.1002/cnl2.85Cathode materials for calcium‐ion batteries: Current status and prospectsYuhan Wu0Ziqi Zhao1Xiaorui Hao2Rui Xu3Laishi Li4Dan Lv5Xianglong Huang6Qing Zhao7Yang Xu8Yusheng Wu9School of Environmental and Chemical Engineering Shenyang University of Technology ShenyangChinaSchool of Environmental and Chemical Engineering Shenyang University of Technology ShenyangChinaCollege of Materials Science and Engineering Nanjing Tech University NanjingChinaHelmholtz‐Zentrum Dresden‐Rossendorf e.V. Institute of Ion Beam Physics and Materials Research DresdenGermanySchool of Materials Science and Engineering Shenyang University of Technology ShenyangChinaSchool of Environmental and Chemical Engineering Shenyang University of Technology ShenyangChinaInstitute of Fundamental and Frontier Sciences University of Electronic Science and Technology of China ChengduChinaKey Laboratory of Advanced Energy Materials Chemistry (Ministry of Education) Nankai University TianjinChinaDepartment of Chemistry University College London LondonUKSchool of Materials Science and Engineering Shenyang University of Technology ShenyangChinaAbstract In the post‐lithium‐ion battery era, calcium‐ion batteries (CIBs) have aroused extensive attention because of their strong cost competitiveness, low standard redox potentials, and high safety. However, the related research is progressing slowly due to the constraints of the development of electrode materials. The large ionic radius of Ca2+ especially increases the challenge to design cathode materials for reversible Ca2+ uptake/removal. Despite the inspiring achievements, various challenges still need to be further resolved. Here, this review systematically summarizes the recent advances in CIB cathode materials, including Prussian blue and its analogues, metal oxides, metal chalcogenides, polyanionic compounds, and organic materials. We first provide a brief introduction to CIBs and compare their advantages with other battery technologies. Then, preparation methods are introduced, and breakthrough investigations are highlighted. Finally, some possible research directions are discussed to promote the development of this emerging battery technology.https://doi.org/10.1002/cnl2.85calcium‐ion batteriescathode materialselectrochemical energy storageelectrochemical performance |
spellingShingle | Yuhan Wu Ziqi Zhao Xiaorui Hao Rui Xu Laishi Li Dan Lv Xianglong Huang Qing Zhao Yang Xu Yusheng Wu Cathode materials for calcium‐ion batteries: Current status and prospects Carbon Neutralization calcium‐ion batteries cathode materials electrochemical energy storage electrochemical performance |
title | Cathode materials for calcium‐ion batteries: Current status and prospects |
title_full | Cathode materials for calcium‐ion batteries: Current status and prospects |
title_fullStr | Cathode materials for calcium‐ion batteries: Current status and prospects |
title_full_unstemmed | Cathode materials for calcium‐ion batteries: Current status and prospects |
title_short | Cathode materials for calcium‐ion batteries: Current status and prospects |
title_sort | cathode materials for calcium ion batteries current status and prospects |
topic | calcium‐ion batteries cathode materials electrochemical energy storage electrochemical performance |
url | https://doi.org/10.1002/cnl2.85 |
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