Cathode materials for calcium‐ion batteries: Current status and prospects

Abstract In the post‐lithium‐ion battery era, calcium‐ion batteries (CIBs) have aroused extensive attention because of their strong cost competitiveness, low standard redox potentials, and high safety. However, the related research is progressing slowly due to the constraints of the development of e...

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Main Authors: Yuhan Wu, Ziqi Zhao, Xiaorui Hao, Rui Xu, Laishi Li, Dan Lv, Xianglong Huang, Qing Zhao, Yang Xu, Yusheng Wu
Format: Article
Language:English
Published: Wiley 2023-09-01
Series:Carbon Neutralization
Subjects:
Online Access:https://doi.org/10.1002/cnl2.85
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author Yuhan Wu
Ziqi Zhao
Xiaorui Hao
Rui Xu
Laishi Li
Dan Lv
Xianglong Huang
Qing Zhao
Yang Xu
Yusheng Wu
author_facet Yuhan Wu
Ziqi Zhao
Xiaorui Hao
Rui Xu
Laishi Li
Dan Lv
Xianglong Huang
Qing Zhao
Yang Xu
Yusheng Wu
author_sort Yuhan Wu
collection DOAJ
description Abstract In the post‐lithium‐ion battery era, calcium‐ion batteries (CIBs) have aroused extensive attention because of their strong cost competitiveness, low standard redox potentials, and high safety. However, the related research is progressing slowly due to the constraints of the development of electrode materials. The large ionic radius of Ca2+ especially increases the challenge to design cathode materials for reversible Ca2+ uptake/removal. Despite the inspiring achievements, various challenges still need to be further resolved. Here, this review systematically summarizes the recent advances in CIB cathode materials, including Prussian blue and its analogues, metal oxides, metal chalcogenides, polyanionic compounds, and organic materials. We first provide a brief introduction to CIBs and compare their advantages with other battery technologies. Then, preparation methods are introduced, and breakthrough investigations are highlighted. Finally, some possible research directions are discussed to promote the development of this emerging battery technology.
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spelling doaj.art-ecaede071e56480a902541fbb27d96612023-09-27T07:25:43ZengWileyCarbon Neutralization2769-33252023-09-012555157310.1002/cnl2.85Cathode materials for calcium‐ion batteries: Current status and prospectsYuhan Wu0Ziqi Zhao1Xiaorui Hao2Rui Xu3Laishi Li4Dan Lv5Xianglong Huang6Qing Zhao7Yang Xu8Yusheng Wu9School of Environmental and Chemical Engineering Shenyang University of Technology ShenyangChinaSchool of Environmental and Chemical Engineering Shenyang University of Technology ShenyangChinaCollege of Materials Science and Engineering Nanjing Tech University NanjingChinaHelmholtz‐Zentrum Dresden‐Rossendorf e.V. Institute of Ion Beam Physics and Materials Research DresdenGermanySchool of Materials Science and Engineering Shenyang University of Technology ShenyangChinaSchool of Environmental and Chemical Engineering Shenyang University of Technology ShenyangChinaInstitute of Fundamental and Frontier Sciences University of Electronic Science and Technology of China ChengduChinaKey Laboratory of Advanced Energy Materials Chemistry (Ministry of Education) Nankai University TianjinChinaDepartment of Chemistry University College London LondonUKSchool of Materials Science and Engineering Shenyang University of Technology ShenyangChinaAbstract In the post‐lithium‐ion battery era, calcium‐ion batteries (CIBs) have aroused extensive attention because of their strong cost competitiveness, low standard redox potentials, and high safety. However, the related research is progressing slowly due to the constraints of the development of electrode materials. The large ionic radius of Ca2+ especially increases the challenge to design cathode materials for reversible Ca2+ uptake/removal. Despite the inspiring achievements, various challenges still need to be further resolved. Here, this review systematically summarizes the recent advances in CIB cathode materials, including Prussian blue and its analogues, metal oxides, metal chalcogenides, polyanionic compounds, and organic materials. We first provide a brief introduction to CIBs and compare their advantages with other battery technologies. Then, preparation methods are introduced, and breakthrough investigations are highlighted. Finally, some possible research directions are discussed to promote the development of this emerging battery technology.https://doi.org/10.1002/cnl2.85calcium‐ion batteriescathode materialselectrochemical energy storageelectrochemical performance
spellingShingle Yuhan Wu
Ziqi Zhao
Xiaorui Hao
Rui Xu
Laishi Li
Dan Lv
Xianglong Huang
Qing Zhao
Yang Xu
Yusheng Wu
Cathode materials for calcium‐ion batteries: Current status and prospects
Carbon Neutralization
calcium‐ion batteries
cathode materials
electrochemical energy storage
electrochemical performance
title Cathode materials for calcium‐ion batteries: Current status and prospects
title_full Cathode materials for calcium‐ion batteries: Current status and prospects
title_fullStr Cathode materials for calcium‐ion batteries: Current status and prospects
title_full_unstemmed Cathode materials for calcium‐ion batteries: Current status and prospects
title_short Cathode materials for calcium‐ion batteries: Current status and prospects
title_sort cathode materials for calcium ion batteries current status and prospects
topic calcium‐ion batteries
cathode materials
electrochemical energy storage
electrochemical performance
url https://doi.org/10.1002/cnl2.85
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