Novel Approach for the Synthesis of Chlorophosphazene Cycles with a Defined Size via Controlled Cyclization of Linear Oligodichlorophosphazenes [Cl(PCl<sub>2</sub>=N)<sub>n</sub>–PCl<sub>3</sub>]<sup>+</sup>[PCl<sub>6</sub>]<sup>−</sup>

Novel Approach for the Synthesis of Chlorophosphazene Cycles with a Defined Size via Controlled Cyclization of Linear Oligodichlorophosphazenes [Cl(PCl<sub>2</sub>=N)<sub>n</sub>–PCl<sub>3</sub>]<sup>+</sup>[PCl<sub>6</sub>]<sup>−</sup>

Despite a significant number of investigations in the field of phosphazene chemistry, the formation mechanism of this class of cyclic compounds is still poorly studied. At the same time, a thorough understanding of this process is necessary, both for the direct production of phosphazene rings of a g...

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Bibliographic Details
Main Authors: Mikhail Gorlov, Nikolay Bredov, Andrey Esin, Igor Sirotin, Mikhail Soldatov, Volodymyr Oberemok, Vyacheslav V. Kireev
Format: Article
Language:English
Published: MDPI AG 2021-05-01
Series:International Journal of Molecular Sciences
Subjects:
phosphazenes
cyclization
controlled cycle size
living cationic polymerization
hexamethyldisilazane
Online Access:https://www.mdpi.com/1422-0067/22/11/5958

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