Effect of Magnetic Field on the Type and Amount of Monomers in Polyhydroxyalkanoate Copolymer

Many studies have been conducted on production of biodegradable polymers such as polyhydroxyalkanoates (PHAs) in overcoming the environmental problems due to the accumulation of synthetic plastics as waste materials and excessive activated sludge produced in municipal waste water treatment plants. I...

Full description

Bibliographic Details
Main Authors: Marzie Fatehi, Seyed Ahmad Ataei
Format: Article
Language:fas
Published: Iran Polymer and Petrochemical Institute 2014-10-01
Series:علوم و تکنولوژی پلیمر
Subjects:
Online Access:http://jips.ippi.ac.ir/article_1092_f34b940fee721be1f35a23e1af29088f.pdf
_version_ 1818729896058290176
author Marzie Fatehi
Seyed Ahmad Ataei
author_facet Marzie Fatehi
Seyed Ahmad Ataei
author_sort Marzie Fatehi
collection DOAJ
description Many studies have been conducted on production of biodegradable polymers such as polyhydroxyalkanoates (PHAs) in overcoming the environmental problems due to the accumulation of synthetic plastics as waste materials and excessive activated sludge produced in municipal waste water treatment plants. In this study; the effect of magnetic field intensity of 5, 10, 15, 20, 25 and 50 milliTesla (mT) was investigated on the type and amount of monomers produced in the copolymer and PHA production in activated sludge and the results were compared simultaneously with the results of PHA production without the magnetic field (0 mT). The experimental procedure included the transfer of the activated sludge into the batch reactor, addition of sodium acetate, magnetic field generation by magnets, aeration for 30 h, sampling at definite timing, measurement of PHA by gas chromatography. In summary, this research indicated that, the maximum PHA content was produced at 20 mT which was equal to 0.75 g/L, whereas the lowest PHA content was observed at 50 mT (0.55 g/L). In addition, the magnetic field was influenced by the type and amount of monomer produced in PHA. The highest amount of valerate was observed at 50 mT, while this magnetic field decreased the amount of PHA (8.33%) compared to the control sample. Also, the maximum amount of butyrate monomer in the copolymer was observed at 5 and 20 mT, which were equal to 81% and 74 %. According to the results obtained, the mass percentage of valerate in the control sample and those exposed to magnetic field with negative effects was more than the mass percentage of butyrate; an indication of better copolymers on the basis of their mechanical properties.
first_indexed 2024-12-17T22:53:10Z
format Article
id doaj.art-ecbb4179edcd4ddf803a9798121a2f94
institution Directory Open Access Journal
issn 1016-3255
2008-0883
language fas
last_indexed 2024-12-17T22:53:10Z
publishDate 2014-10-01
publisher Iran Polymer and Petrochemical Institute
record_format Article
series علوم و تکنولوژی پلیمر
spelling doaj.art-ecbb4179edcd4ddf803a9798121a2f942022-12-21T21:29:37ZfasIran Polymer and Petrochemical Instituteعلوم و تکنولوژی پلیمر1016-32552008-08832014-10-0127429829110.22063/jipst.2014.10921092Effect of Magnetic Field on the Type and Amount of Monomers in Polyhydroxyalkanoate CopolymerMarzie Fatehi0Seyed Ahmad Ataei1Department of Chemical Engineering, Shahid Bahonar University, P.O. Box: 7618891167, Kerman, IranDepartment of Chemical Engineering, Shahid Bahonar University, P.O. Box: 7618891167, Kerman, IranMany studies have been conducted on production of biodegradable polymers such as polyhydroxyalkanoates (PHAs) in overcoming the environmental problems due to the accumulation of synthetic plastics as waste materials and excessive activated sludge produced in municipal waste water treatment plants. In this study; the effect of magnetic field intensity of 5, 10, 15, 20, 25 and 50 milliTesla (mT) was investigated on the type and amount of monomers produced in the copolymer and PHA production in activated sludge and the results were compared simultaneously with the results of PHA production without the magnetic field (0 mT). The experimental procedure included the transfer of the activated sludge into the batch reactor, addition of sodium acetate, magnetic field generation by magnets, aeration for 30 h, sampling at definite timing, measurement of PHA by gas chromatography. In summary, this research indicated that, the maximum PHA content was produced at 20 mT which was equal to 0.75 g/L, whereas the lowest PHA content was observed at 50 mT (0.55 g/L). In addition, the magnetic field was influenced by the type and amount of monomer produced in PHA. The highest amount of valerate was observed at 50 mT, while this magnetic field decreased the amount of PHA (8.33%) compared to the control sample. Also, the maximum amount of butyrate monomer in the copolymer was observed at 5 and 20 mT, which were equal to 81% and 74 %. According to the results obtained, the mass percentage of valerate in the control sample and those exposed to magnetic field with negative effects was more than the mass percentage of butyrate; an indication of better copolymers on the basis of their mechanical properties.http://jips.ippi.ac.ir/article_1092_f34b940fee721be1f35a23e1af29088f.pdfmunicipal waste wateractivated sludgepolyhydroxyalkanoateaerationmagnetic field
spellingShingle Marzie Fatehi
Seyed Ahmad Ataei
Effect of Magnetic Field on the Type and Amount of Monomers in Polyhydroxyalkanoate Copolymer
علوم و تکنولوژی پلیمر
municipal waste water
activated sludge
polyhydroxyalkanoate
aeration
magnetic field
title Effect of Magnetic Field on the Type and Amount of Monomers in Polyhydroxyalkanoate Copolymer
title_full Effect of Magnetic Field on the Type and Amount of Monomers in Polyhydroxyalkanoate Copolymer
title_fullStr Effect of Magnetic Field on the Type and Amount of Monomers in Polyhydroxyalkanoate Copolymer
title_full_unstemmed Effect of Magnetic Field on the Type and Amount of Monomers in Polyhydroxyalkanoate Copolymer
title_short Effect of Magnetic Field on the Type and Amount of Monomers in Polyhydroxyalkanoate Copolymer
title_sort effect of magnetic field on the type and amount of monomers in polyhydroxyalkanoate copolymer
topic municipal waste water
activated sludge
polyhydroxyalkanoate
aeration
magnetic field
url http://jips.ippi.ac.ir/article_1092_f34b940fee721be1f35a23e1af29088f.pdf
work_keys_str_mv AT marziefatehi effectofmagneticfieldonthetypeandamountofmonomersinpolyhydroxyalkanoatecopolymer
AT seyedahmadataei effectofmagneticfieldonthetypeandamountofmonomersinpolyhydroxyalkanoatecopolymer