Poly[[μ4-4-(carboxylatomethyl)benzoato]zinc(II)]

In the title compound, [Zn(C9H6O4)]n, the ZnII cations are coordinated in a tetrahedral fashion by carboxylate O-atom donors belonging to four 4-(carboxymethyl) benzoate (4-cmb) ligands. Each 4-cmb ligand binds to four ZnII cations in an exotetradentate fashion to create a non-interpenetrated [Zn(4-...

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Main Authors: Jason Jia, Robert L. LaDuca
Format: Article
Language:English
Published: International Union of Crystallography 2019-07-01
Series:IUCrData
Subjects:
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314619010149
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author Jason Jia
Robert L. LaDuca
author_facet Jason Jia
Robert L. LaDuca
author_sort Jason Jia
collection DOAJ
description In the title compound, [Zn(C9H6O4)]n, the ZnII cations are coordinated in a tetrahedral fashion by carboxylate O-atom donors belonging to four 4-(carboxymethyl) benzoate (4-cmb) ligands. Each 4-cmb ligand binds to four ZnII cations in an exotetradentate fashion to create a non-interpenetrated [Zn(4-cmb)]n three-dimensional coordination polymer network with a new non-diamondoid 66 topology. The crystal studied was refined as an inversion twin.
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spelling doaj.art-ecbd5eeb3fec44ccadf080280a09bf582022-12-21T18:51:31ZengInternational Union of CrystallographyIUCrData2414-31462019-07-0147x19101410.1107/S2414314619010149lh4047Poly[[μ4-4-(carboxylatomethyl)benzoato]zinc(II)]Jason Jia0Robert L. LaDuca1E-35 Holmes Hall, Michigan State University, Lyman Briggs College, 919 E. Shaw Lane, East Lansing, MI 48825, USAE-35 Holmes Hall, Michigan State University, Lyman Briggs College, 919 E. Shaw Lane, East Lansing, MI 48825, USAIn the title compound, [Zn(C9H6O4)]n, the ZnII cations are coordinated in a tetrahedral fashion by carboxylate O-atom donors belonging to four 4-(carboxymethyl) benzoate (4-cmb) ligands. Each 4-cmb ligand binds to four ZnII cations in an exotetradentate fashion to create a non-interpenetrated [Zn(4-cmb)]n three-dimensional coordination polymer network with a new non-diamondoid 66 topology. The crystal studied was refined as an inversion twin.http://scripts.iucr.org/cgi-bin/paper?S2414314619010149crystal structurecoordination polymerzinc(II)
spellingShingle Jason Jia
Robert L. LaDuca
Poly[[μ4-4-(carboxylatomethyl)benzoato]zinc(II)]
IUCrData
crystal structure
coordination polymer
zinc(II)
title Poly[[μ4-4-(carboxylatomethyl)benzoato]zinc(II)]
title_full Poly[[μ4-4-(carboxylatomethyl)benzoato]zinc(II)]
title_fullStr Poly[[μ4-4-(carboxylatomethyl)benzoato]zinc(II)]
title_full_unstemmed Poly[[μ4-4-(carboxylatomethyl)benzoato]zinc(II)]
title_short Poly[[μ4-4-(carboxylatomethyl)benzoato]zinc(II)]
title_sort poly μ4 4 carboxylatomethyl benzoato zinc ii
topic crystal structure
coordination polymer
zinc(II)
url http://scripts.iucr.org/cgi-bin/paper?S2414314619010149
work_keys_str_mv AT jasonjia polym44carboxylatomethylbenzoatozincii
AT robertlladuca polym44carboxylatomethylbenzoatozincii