A superior P-H phosphonite: Asymmetric allylic substitutions with fenchol-based palladium catalysts

The fenchol-based P-H phosphonite BIFOP-H exeeds with 65% ee other monodentate ligands in the Pd-catalyzed substitution of 1-phenyl-2-propenyl acetate with dimethylmalonate.

Bibliographic Details
Main Authors: Bernd Goldfuss, Thomas Löschmann, Tina Kop-Weiershausen, Jörg Neudörfl, Frank Rominger
Format: Article
Language:English
Published: Beilstein-Institut 2006-03-01
Series:Beilstein Journal of Organic Chemistry
Online Access:https://doi.org/10.1186/1860-5397-2-7
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author Bernd Goldfuss
Thomas Löschmann
Tina Kop-Weiershausen
Jörg Neudörfl
Frank Rominger
author_facet Bernd Goldfuss
Thomas Löschmann
Tina Kop-Weiershausen
Jörg Neudörfl
Frank Rominger
author_sort Bernd Goldfuss
collection DOAJ
description The fenchol-based P-H phosphonite BIFOP-H exeeds with 65% ee other monodentate ligands in the Pd-catalyzed substitution of 1-phenyl-2-propenyl acetate with dimethylmalonate.
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spelling doaj.art-ecc71fb553ce491fbdb5cc34b8c78b102022-12-21T18:30:46ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972006-03-0121710.1186/1860-5397-2-71860-5397-2-7A superior P-H phosphonite: Asymmetric allylic substitutions with fenchol-based palladium catalystsBernd Goldfuss0Thomas Löschmann1Tina Kop-Weiershausen2Jörg Neudörfl3Frank Rominger4Institut für Organische Chemie, Universität zu Köln, Greinstraße 4, D-50939 Köln, GermanyDottikon Exclusive Synthesis, Hembrunnstrasse 17, CH-5605 Dottikon, SwitzerlandInstitut für Organische Chemie, Universität zu Köln, Greinstraße 4, D-50939 Köln, GermanyInstitut für Organische Chemie, Universität zu Köln, Greinstraße 4, D-50939 Köln, GermanyX-ray analysesThe fenchol-based P-H phosphonite BIFOP-H exeeds with 65% ee other monodentate ligands in the Pd-catalyzed substitution of 1-phenyl-2-propenyl acetate with dimethylmalonate.https://doi.org/10.1186/1860-5397-2-7
spellingShingle Bernd Goldfuss
Thomas Löschmann
Tina Kop-Weiershausen
Jörg Neudörfl
Frank Rominger
A superior P-H phosphonite: Asymmetric allylic substitutions with fenchol-based palladium catalysts
Beilstein Journal of Organic Chemistry
title A superior P-H phosphonite: Asymmetric allylic substitutions with fenchol-based palladium catalysts
title_full A superior P-H phosphonite: Asymmetric allylic substitutions with fenchol-based palladium catalysts
title_fullStr A superior P-H phosphonite: Asymmetric allylic substitutions with fenchol-based palladium catalysts
title_full_unstemmed A superior P-H phosphonite: Asymmetric allylic substitutions with fenchol-based palladium catalysts
title_short A superior P-H phosphonite: Asymmetric allylic substitutions with fenchol-based palladium catalysts
title_sort superior p h phosphonite asymmetric allylic substitutions with fenchol based palladium catalysts
url https://doi.org/10.1186/1860-5397-2-7
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