Universal Preparation Strategy for Ultradurable Antibacterial Fabrics through Coating an Adhesive Nanosilver Glue

Microbiological protection textile materials played an important role in the battle against the epidemic. However, the traditional active antimicrobial treatment of textiles suffers from narrow textile applicability, low chemical stability, and poor washability. Here, a high-strength adhesive nanosi...

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Main Authors: Jundan Feng, Lingling Feng, Sijun Xu, Chunhong Zhu, Gangwei Pan, Lirong Yao
Format: Article
Language:English
Published: MDPI AG 2022-07-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/12/14/2429
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author Jundan Feng
Lingling Feng
Sijun Xu
Chunhong Zhu
Gangwei Pan
Lirong Yao
author_facet Jundan Feng
Lingling Feng
Sijun Xu
Chunhong Zhu
Gangwei Pan
Lirong Yao
author_sort Jundan Feng
collection DOAJ
description Microbiological protection textile materials played an important role in the battle against the epidemic. However, the traditional active antimicrobial treatment of textiles suffers from narrow textile applicability, low chemical stability, and poor washability. Here, a high-strength adhesive nanosilver glue was synthesized by introducing nontoxic water-soluble polyurethane glue as a protectant. The as-prepared nanosilver glue could adhere firmly to the fiber surfaces by forming a flexible polymer film and could encapsulate nanosilver inside the glue. The as-prepared nanosilver had a torispherical structure with diameter of ~22 nm, zeta potential of −42.7 mV, and good dispersibility in water, and it could be stored for one year. Further studies indicated that the nanosilver glue had wide applicability to the main fabric species, such as cotton and polyester fabric, surgical mask, latex paint, and wood paint. The antimicrobial cotton and polyester fabrics were prepared by a simple impregnation–padding–baking process. The corresponding antimicrobial activity was positively correlated with nanosilver content. The treated fabrics (500 mg/kg) exhibited ultrahigh washing resistance (maintained over 99% antibacterial rates for 100 times of standard washing) and wear resistance (99% antibacterial rates for 8000 times of standard wearing), equivalent breathability to untreated fabric, improved mechanical properties, and good flexibility, demonstrating a potential in cleanable and reusable microbiological protection textiles.
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spelling doaj.art-ecd4c191819c464f98a9e4c8c90baa2c2023-11-30T21:35:59ZengMDPI AGNanomaterials2079-49912022-07-011214242910.3390/nano12142429Universal Preparation Strategy for Ultradurable Antibacterial Fabrics through Coating an Adhesive Nanosilver GlueJundan Feng0Lingling Feng1Sijun Xu2Chunhong Zhu3Gangwei Pan4Lirong Yao5National & Local Joint Engineering Research Center of Technical Fiber Composites for Safety and Protection, Nantong University, Nantong 226019, ChinaNational & Local Joint Engineering Research Center of Technical Fiber Composites for Safety and Protection, Nantong University, Nantong 226019, ChinaNational & Local Joint Engineering Research Center of Technical Fiber Composites for Safety and Protection, Nantong University, Nantong 226019, ChinaFaculty of Textile Science and Technology, Shinshu University, Nagano 386-8567, JapanNational & Local Joint Engineering Research Center of Technical Fiber Composites for Safety and Protection, Nantong University, Nantong 226019, ChinaNational & Local Joint Engineering Research Center of Technical Fiber Composites for Safety and Protection, Nantong University, Nantong 226019, ChinaMicrobiological protection textile materials played an important role in the battle against the epidemic. However, the traditional active antimicrobial treatment of textiles suffers from narrow textile applicability, low chemical stability, and poor washability. Here, a high-strength adhesive nanosilver glue was synthesized by introducing nontoxic water-soluble polyurethane glue as a protectant. The as-prepared nanosilver glue could adhere firmly to the fiber surfaces by forming a flexible polymer film and could encapsulate nanosilver inside the glue. The as-prepared nanosilver had a torispherical structure with diameter of ~22 nm, zeta potential of −42.7 mV, and good dispersibility in water, and it could be stored for one year. Further studies indicated that the nanosilver glue had wide applicability to the main fabric species, such as cotton and polyester fabric, surgical mask, latex paint, and wood paint. The antimicrobial cotton and polyester fabrics were prepared by a simple impregnation–padding–baking process. The corresponding antimicrobial activity was positively correlated with nanosilver content. The treated fabrics (500 mg/kg) exhibited ultrahigh washing resistance (maintained over 99% antibacterial rates for 100 times of standard washing) and wear resistance (99% antibacterial rates for 8000 times of standard wearing), equivalent breathability to untreated fabric, improved mechanical properties, and good flexibility, demonstrating a potential in cleanable and reusable microbiological protection textiles.https://www.mdpi.com/2079-4991/12/14/2429nanosilverfabricantimicrobialwashablereusable
spellingShingle Jundan Feng
Lingling Feng
Sijun Xu
Chunhong Zhu
Gangwei Pan
Lirong Yao
Universal Preparation Strategy for Ultradurable Antibacterial Fabrics through Coating an Adhesive Nanosilver Glue
Nanomaterials
nanosilver
fabric
antimicrobial
washable
reusable
title Universal Preparation Strategy for Ultradurable Antibacterial Fabrics through Coating an Adhesive Nanosilver Glue
title_full Universal Preparation Strategy for Ultradurable Antibacterial Fabrics through Coating an Adhesive Nanosilver Glue
title_fullStr Universal Preparation Strategy for Ultradurable Antibacterial Fabrics through Coating an Adhesive Nanosilver Glue
title_full_unstemmed Universal Preparation Strategy for Ultradurable Antibacterial Fabrics through Coating an Adhesive Nanosilver Glue
title_short Universal Preparation Strategy for Ultradurable Antibacterial Fabrics through Coating an Adhesive Nanosilver Glue
title_sort universal preparation strategy for ultradurable antibacterial fabrics through coating an adhesive nanosilver glue
topic nanosilver
fabric
antimicrobial
washable
reusable
url https://www.mdpi.com/2079-4991/12/14/2429
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