Bis(2,2′-diamino-4,4′-bi-1,3-thiazole-κ2N3,N3′)bis(nitrato-κO)lead(II) dihydrate
In the title compound, [Pb(NO3)2(C6H6N4S2)2]·2H2O, the PbII cation is N,N′-chelated by two 2,2′-diamino-4,4′-bi-1,3-thiazole (DABT) ligands and further is cis coordinated by two nitrate anions in a distorted PbN4O2 octahedral geometry. One of th...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809029638 |
| _version_ | 1819106181655822336 |
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| author | Bing-Xin Liu Duan-Jun Xu |
| author_facet | Bing-Xin Liu Duan-Jun Xu |
| author_sort | Bing-Xin Liu |
| collection | DOAJ |
| description | In the title compound, [Pb(NO3)2(C6H6N4S2)2]·2H2O, the PbII cation is N,N′-chelated by two 2,2′-diamino-4,4′-bi-1,3-thiazole (DABT) ligands and further is cis coordinated by two nitrate anions in a distorted PbN4O2 octahedral geometry. One of the uncoordinated water molecules is close to an inversion center and is disordered equally over two sites. Intramolecular N—H...N and N—H...O interactions are present. An extensive hydrogen-bonding network of types N—H...O, O—H...O, O—H...N and O—H...S consolidates the crystal structure. |
| first_indexed | 2024-12-22T02:34:04Z |
| format | Article |
| id | doaj.art-ecd5332459f5436ca4a747184af1eb35 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T02:34:04Z |
| publishDate | 2009-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-ecd5332459f5436ca4a747184af1eb352022-12-21T18:41:49ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-08-01658m1002m100310.1107/S1600536809029638Bis(2,2′-diamino-4,4′-bi-1,3-thiazole-κ2N3,N3′)bis(nitrato-κO)lead(II) dihydrateBing-Xin LiuDuan-Jun XuIn the title compound, [Pb(NO3)2(C6H6N4S2)2]·2H2O, the PbII cation is N,N′-chelated by two 2,2′-diamino-4,4′-bi-1,3-thiazole (DABT) ligands and further is cis coordinated by two nitrate anions in a distorted PbN4O2 octahedral geometry. One of the uncoordinated water molecules is close to an inversion center and is disordered equally over two sites. Intramolecular N—H...N and N—H...O interactions are present. An extensive hydrogen-bonding network of types N—H...O, O—H...O, O—H...N and O—H...S consolidates the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536809029638 |
| spellingShingle | Bing-Xin Liu Duan-Jun Xu Bis(2,2′-diamino-4,4′-bi-1,3-thiazole-κ2N3,N3′)bis(nitrato-κO)lead(II) dihydrate Acta Crystallographica Section E |
| title | Bis(2,2′-diamino-4,4′-bi-1,3-thiazole-κ2N3,N3′)bis(nitrato-κO)lead(II) dihydrate |
| title_full | Bis(2,2′-diamino-4,4′-bi-1,3-thiazole-κ2N3,N3′)bis(nitrato-κO)lead(II) dihydrate |
| title_fullStr | Bis(2,2′-diamino-4,4′-bi-1,3-thiazole-κ2N3,N3′)bis(nitrato-κO)lead(II) dihydrate |
| title_full_unstemmed | Bis(2,2′-diamino-4,4′-bi-1,3-thiazole-κ2N3,N3′)bis(nitrato-κO)lead(II) dihydrate |
| title_short | Bis(2,2′-diamino-4,4′-bi-1,3-thiazole-κ2N3,N3′)bis(nitrato-κO)lead(II) dihydrate |
| title_sort | bis 2 2 amp 8242 diamino 4 4 amp 8242 bi 1 3 thiazole amp 954 2n3 n3 amp 8242 bis nitrato amp 954 o lead ii dihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809029638 |
| work_keys_str_mv | AT bingxinliu bis22amp8242diamino44amp8242bi13thiazoleamp9542n3n3amp8242bisnitratoamp954oleadiidihydrate AT duanjunxu bis22amp8242diamino44amp8242bi13thiazoleamp9542n3n3amp8242bisnitratoamp954oleadiidihydrate |