Preparation and characterization of silver nanoparticles using aniline

UV–Vis spectroscopy, transmission electron microscopy (TEM) and selected area electron diffraction (SAED) have been employed to characterize silver nanoparticles (AgNPs) using aniline and silver nitrate as reductant and oxidant, respectively. A broad surface resonance plasmon (SRP) band appears at 4...

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Main Authors: Zaheer Khan, Javed Ijaz Hussain, Athar Adil Hashmi, Shaeel Ahmed AL-Thabaiti
Format: Article
Language:English
Published: Elsevier 2017-05-01
Series:Arabian Journal of Chemistry
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1878535213001214
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author Zaheer Khan
Javed Ijaz Hussain
Athar Adil Hashmi
Shaeel Ahmed AL-Thabaiti
author_facet Zaheer Khan
Javed Ijaz Hussain
Athar Adil Hashmi
Shaeel Ahmed AL-Thabaiti
author_sort Zaheer Khan
collection DOAJ
description UV–Vis spectroscopy, transmission electron microscopy (TEM) and selected area electron diffraction (SAED) have been employed to characterize silver nanoparticles (AgNPs) using aniline and silver nitrate as reductant and oxidant, respectively. A broad surface resonance plasmon (SRP) band appears at 400 nm, indicating that the AgNPs are spherical. The TEM images show that AgNPs aggregated in an unsymmetrical manner, leading to the formation of beautiful silver nanocrystals. Aniline adsorbed onto the surface of Ag-nanocrystals through electrostatic, van der Walls forces and hydrogen bonding. Cetyltrimethylammonium bromide (CTAB) acted as a stabilizer and/or capping agent.
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spelling doaj.art-ecedf56343e445a9b04bfb17940d92332022-12-21T18:12:56ZengElsevierArabian Journal of Chemistry1878-53522017-05-0110S2S1506S151110.1016/j.arabjc.2013.05.001Preparation and characterization of silver nanoparticles using anilineZaheer Khan0Javed Ijaz Hussain1Athar Adil Hashmi2Shaeel Ahmed AL-Thabaiti3Department of Chemistry, Jamia Millia Islamia (Central University), New Delhi 110 025, IndiaDepartment of Chemistry, Jamia Millia Islamia (Central University), New Delhi 110 025, IndiaDepartment of Chemistry, Jamia Millia Islamia (Central University), New Delhi 110 025, IndiaDepartment of Chemistry, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah 21413, Saudi ArabiaUV–Vis spectroscopy, transmission electron microscopy (TEM) and selected area electron diffraction (SAED) have been employed to characterize silver nanoparticles (AgNPs) using aniline and silver nitrate as reductant and oxidant, respectively. A broad surface resonance plasmon (SRP) band appears at 400 nm, indicating that the AgNPs are spherical. The TEM images show that AgNPs aggregated in an unsymmetrical manner, leading to the formation of beautiful silver nanocrystals. Aniline adsorbed onto the surface of Ag-nanocrystals through electrostatic, van der Walls forces and hydrogen bonding. Cetyltrimethylammonium bromide (CTAB) acted as a stabilizer and/or capping agent.http://www.sciencedirect.com/science/article/pii/S1878535213001214MorphologyAg-nanoparticlesOxidationAnilineCTAB
spellingShingle Zaheer Khan
Javed Ijaz Hussain
Athar Adil Hashmi
Shaeel Ahmed AL-Thabaiti
Preparation and characterization of silver nanoparticles using aniline
Arabian Journal of Chemistry
Morphology
Ag-nanoparticles
Oxidation
Aniline
CTAB
title Preparation and characterization of silver nanoparticles using aniline
title_full Preparation and characterization of silver nanoparticles using aniline
title_fullStr Preparation and characterization of silver nanoparticles using aniline
title_full_unstemmed Preparation and characterization of silver nanoparticles using aniline
title_short Preparation and characterization of silver nanoparticles using aniline
title_sort preparation and characterization of silver nanoparticles using aniline
topic Morphology
Ag-nanoparticles
Oxidation
Aniline
CTAB
url http://www.sciencedirect.com/science/article/pii/S1878535213001214
work_keys_str_mv AT zaheerkhan preparationandcharacterizationofsilvernanoparticlesusinganiline
AT javedijazhussain preparationandcharacterizationofsilvernanoparticlesusinganiline
AT atharadilhashmi preparationandcharacterizationofsilvernanoparticlesusinganiline
AT shaeelahmedalthabaiti preparationandcharacterizationofsilvernanoparticlesusinganiline