8,13-Dimethylicosa-9,11-diyne-8,13-diol
The protocol, 3-methyldec-1-yn-3-ol (<b>1a</b>) was chosen to perform the dimerization process. The optimal conditions for synthesis of 8,13-dimethylicosa-9,11-diyne-8,13 (<b>2a</b>) with high efficiency when using copper-catalyzed, N,N,N′N′-tetramethylethylenediamine as a li...
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| Format: | Article |
| Language: | English |
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MDPI AG
2022-11-01
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| Series: | Molbank |
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| Online Access: | https://www.mdpi.com/1422-8599/2022/4/M1484 |
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| author | Sarvinoz I. Tirkasheva Odiljon E. Ziyadullaev Vasiliy M. Muzalevskiy Askar B. Parmanov |
| author_facet | Sarvinoz I. Tirkasheva Odiljon E. Ziyadullaev Vasiliy M. Muzalevskiy Askar B. Parmanov |
| author_sort | Sarvinoz I. Tirkasheva |
| collection | DOAJ |
| description | The protocol, 3-methyldec-1-yn-3-ol (<b>1a</b>) was chosen to perform the dimerization process. The optimal conditions for synthesis of 8,13-dimethylicosa-9,11-diyne-8,13 (<b>2a</b>) with high efficiency when using copper-catalyzed, N,N,N′N′-tetramethylethylenediamine as a ligand and CCl<sub>4</sub> and methanol solvents in atmospheric pressure were determined. The structure of the obtained compound was proved by IR, <sup>1</sup>H-NMR and <sup>13</sup>C-NMR spectroscopy. |
| first_indexed | 2024-03-09T16:03:43Z |
| format | Article |
| id | doaj.art-ed0a392599254055a43f9fee043e948d |
| institution | Directory Open Access Journal |
| issn | 1422-8599 |
| language | English |
| last_indexed | 2024-03-09T16:03:43Z |
| publishDate | 2022-11-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molbank |
| spelling | doaj.art-ed0a392599254055a43f9fee043e948d2023-11-24T16:54:05ZengMDPI AGMolbank1422-85992022-11-0120224M148410.3390/M14848,13-Dimethylicosa-9,11-diyne-8,13-diolSarvinoz I. Tirkasheva0Odiljon E. Ziyadullaev1Vasiliy M. Muzalevskiy2Askar B. Parmanov3Department of Chemistry, Chirchik State Pedagogical University, A.Temur, 104, Chirchik 111700, UzbekistanDepartment of Chemistry, Chirchik State Pedagogical University, A.Temur, 104, Chirchik 111700, UzbekistanDepartment of Organic Chemistry, Moscow State University, Leninskiye Gory, 1, Moscow 119991, RussiaDepartment of General and Oil-Gas Chemistry, National University of Uzbekistan, University Street, 4, Almazar District, Tashkent 100174, UzbekistanThe protocol, 3-methyldec-1-yn-3-ol (<b>1a</b>) was chosen to perform the dimerization process. The optimal conditions for synthesis of 8,13-dimethylicosa-9,11-diyne-8,13 (<b>2a</b>) with high efficiency when using copper-catalyzed, N,N,N′N′-tetramethylethylenediamine as a ligand and CCl<sub>4</sub> and methanol solvents in atmospheric pressure were determined. The structure of the obtained compound was proved by IR, <sup>1</sup>H-NMR and <sup>13</sup>C-NMR spectroscopy.https://www.mdpi.com/1422-8599/2022/4/M1484terminal acetylene alcoholdiacetylene dioldimerizationoxidative homocoupling reactioncopper (I) chloride |
| spellingShingle | Sarvinoz I. Tirkasheva Odiljon E. Ziyadullaev Vasiliy M. Muzalevskiy Askar B. Parmanov 8,13-Dimethylicosa-9,11-diyne-8,13-diol Molbank terminal acetylene alcohol diacetylene diol dimerization oxidative homocoupling reaction copper (I) chloride |
| title | 8,13-Dimethylicosa-9,11-diyne-8,13-diol |
| title_full | 8,13-Dimethylicosa-9,11-diyne-8,13-diol |
| title_fullStr | 8,13-Dimethylicosa-9,11-diyne-8,13-diol |
| title_full_unstemmed | 8,13-Dimethylicosa-9,11-diyne-8,13-diol |
| title_short | 8,13-Dimethylicosa-9,11-diyne-8,13-diol |
| title_sort | 8 13 dimethylicosa 9 11 diyne 8 13 diol |
| topic | terminal acetylene alcohol diacetylene diol dimerization oxidative homocoupling reaction copper (I) chloride |
| url | https://www.mdpi.com/1422-8599/2022/4/M1484 |
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