Preparation of Chitosan-Composite-Film-Supported Copper Nanoparticles and Their Application in 1,6-Hydroboration Reactions of <em>p</em>-Quinone Methides
Here, we describe the preparation of copper nanoparticles that are stabilized on a chitosan composite film (CP@Cu). This material could catalyze the 1,6-hydroboration reactions of <i>p</i>-quinone methides with B<sub>2</sub>pin<sub>2</sub> as a boron source under...
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| Format: | Article |
| Language: | English |
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MDPI AG
2022-11-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/27/22/7962 |
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| author | Shuhan Chen Wei Wen Xue Zhao Zelang Zhang Weishuang Li Yaoyao Zhang Bojie Li Lei Zhu |
| author_facet | Shuhan Chen Wei Wen Xue Zhao Zelang Zhang Weishuang Li Yaoyao Zhang Bojie Li Lei Zhu |
| author_sort | Shuhan Chen |
| collection | DOAJ |
| description | Here, we describe the preparation of copper nanoparticles that are stabilized on a chitosan composite film (CP@Cu). This material could catalyze the 1,6-hydroboration reactions of <i>p</i>-quinone methides with B<sub>2</sub>pin<sub>2</sub> as a boron source under mild conditions. This reaction exhibited very good functional group compatibility, and the organoboron compounds that were formed could easily be converted into corresponding hydroxyl products with good to excellent yields. This newly developed methodology provides an efficient and sequential pathway for the synthesis of <i>gem</i>-disubstituted methanols. |
| first_indexed | 2024-03-09T18:07:28Z |
| format | Article |
| id | doaj.art-ed0abac6a2444264be48328d84b63f5b |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-09T18:07:28Z |
| publishDate | 2022-11-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-ed0abac6a2444264be48328d84b63f5b2023-11-24T09:24:08ZengMDPI AGMolecules1420-30492022-11-012722796210.3390/molecules27227962Preparation of Chitosan-Composite-Film-Supported Copper Nanoparticles and Their Application in 1,6-Hydroboration Reactions of <em>p</em>-Quinone MethidesShuhan Chen0Wei Wen1Xue Zhao2Zelang Zhang3Weishuang Li4Yaoyao Zhang5Bojie Li6Lei Zhu7School of Chemistry and Materials Science, Hubei Engineering University, Xiaogan 432000, ChinaSchool of Chemistry and Materials Science, Hubei Engineering University, Xiaogan 432000, ChinaSchool of Chemistry and Materials Science, Hubei Engineering University, Xiaogan 432000, ChinaSchool of Chemistry and Materials Science, Hubei Engineering University, Xiaogan 432000, ChinaSchool of Chemistry and Materials Science, Hubei Engineering University, Xiaogan 432000, ChinaSchool of Chemistry and Materials Science, Hubei Engineering University, Xiaogan 432000, ChinaSchool of Chemistry and Materials Science, Hubei Engineering University, Xiaogan 432000, ChinaSchool of Chemistry and Materials Science, Hubei Engineering University, Xiaogan 432000, ChinaHere, we describe the preparation of copper nanoparticles that are stabilized on a chitosan composite film (CP@Cu). This material could catalyze the 1,6-hydroboration reactions of <i>p</i>-quinone methides with B<sub>2</sub>pin<sub>2</sub> as a boron source under mild conditions. This reaction exhibited very good functional group compatibility, and the organoboron compounds that were formed could easily be converted into corresponding hydroxyl products with good to excellent yields. This newly developed methodology provides an efficient and sequential pathway for the synthesis of <i>gem</i>-disubstituted methanols.https://www.mdpi.com/1420-3049/27/22/7962copper nanoparticleschitosan composite filmhydroboration reactions<i>p</i>-quinone methidesorganoboron compounds |
| spellingShingle | Shuhan Chen Wei Wen Xue Zhao Zelang Zhang Weishuang Li Yaoyao Zhang Bojie Li Lei Zhu Preparation of Chitosan-Composite-Film-Supported Copper Nanoparticles and Their Application in 1,6-Hydroboration Reactions of <em>p</em>-Quinone Methides Molecules copper nanoparticles chitosan composite film hydroboration reactions <i>p</i>-quinone methides organoboron compounds |
| title | Preparation of Chitosan-Composite-Film-Supported Copper Nanoparticles and Their Application in 1,6-Hydroboration Reactions of <em>p</em>-Quinone Methides |
| title_full | Preparation of Chitosan-Composite-Film-Supported Copper Nanoparticles and Their Application in 1,6-Hydroboration Reactions of <em>p</em>-Quinone Methides |
| title_fullStr | Preparation of Chitosan-Composite-Film-Supported Copper Nanoparticles and Their Application in 1,6-Hydroboration Reactions of <em>p</em>-Quinone Methides |
| title_full_unstemmed | Preparation of Chitosan-Composite-Film-Supported Copper Nanoparticles and Their Application in 1,6-Hydroboration Reactions of <em>p</em>-Quinone Methides |
| title_short | Preparation of Chitosan-Composite-Film-Supported Copper Nanoparticles and Their Application in 1,6-Hydroboration Reactions of <em>p</em>-Quinone Methides |
| title_sort | preparation of chitosan composite film supported copper nanoparticles and their application in 1 6 hydroboration reactions of em p em quinone methides |
| topic | copper nanoparticles chitosan composite film hydroboration reactions <i>p</i>-quinone methides organoboron compounds |
| url | https://www.mdpi.com/1420-3049/27/22/7962 |
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